Dissolved organic matter in surface runoff in the Loess Plateau of China: The role of rainfall events and land-use

Exploring the chemical characterization of dissolved organic matter (DOM) is important for understanding the fate of laterally transported organic matter in watersheds. We hypothesized that differences in water-extractable organic matter (WEOM) in soils of varying land uses and rainfall events may significantly affect the quality and the quantity of stream DOM. To test our hypotheses, characteristics of rainfall-runoff DOM and WEOM of source materials (topsoil from different land uses and gullies, as well as typical vegetation) were investigated at two adjacent catchments in the Loess Plateau of China, using ultraviolet–visible absorbance and excitation emission matrix fluorescence with parallel factor analysis (PARAFAC). Results indicated that land-use types may significantly affect the chemical composition of soil WEOM, including its aromaticity, molecular weight, and degree of humification. The PARAFAC analysis demonstrated that the soils and stream water were dominated by terrestrial/allochthonous humic-like substances and microbial transformable humic-like fluorophores. Shifts in the fluorescence properties of stream DOM suggested a pronounced change in the relative proportion of allochthonous versus autochthonous material under different rainfall patterns and land uses. For example, high proportions of forestland could provide more allochthonous DOM input. This study highlights the relevance of soils and hydrological dynamics on the composition and fluxes of DOM issuing from watersheds. The composition of DOM in soils was influenced by land-use type. Precipitation patterns influenced the proportion of terrestrial versus microbial origins of DOM in surface runoff. Contributions of allochthonous, terrestrially derived DOM inputs were highest from forested landscapes.     

孤立金属尖端的电晕触发阈值

为了得到金属尖端在发生电晕放电时尖端处的电场强度,该文首先采用实验室实验得到不同高度、不同形状、不同材质的金属尖端发生电晕放电时的环境电场阈值;再采用有限元法计算二维泊松方程,得到尖端处电晕触发阈值,由此得出以下结论:环境电场阈值随金属尖端高度的增大基本呈线性减小趋势,随着尖端越来越尖,环境电场阈值呈先减小后增大的变化趋势;高度、形状对金属物尖端处电晕触发阈值无影响,尖端处电晕阈值为定值;给出尖端处电晕触发阈值为158.75 kV·m-1与空间分辨率的拟合公式,可为今后电晕放电数值模拟中判断电晕放电的起始时刻提供参考。     

In situ calcite U−Pb geochronology by high-sensitivity single-collector LA-SF-ICP-MS

Science China Earth Sciences - U?Pb geochronology of calcite using laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) is an emerging method, with potential applications...     

2001—2010年“新丝绸之路”经济带中国段城市经济时空演变

为探索"新丝绸之路"经济带的城市经济时空演变规律,采用主成分分析法对经济带内27个中国城市2001—2010年的经济数据进行研究,得出了各城市经济发展水平的综合得分。运用传统马尔科夫链和时间马尔科夫链方法,计算出城市经济发展水平的马尔科夫链转移概率矩阵和空间转移概率矩阵,探索了城市发展的时间和空间特征。结果表明:从时间上看,"新丝绸之路"沿线的城市经济发展在10年内保持着原来的状态。从空间上看,经济带的城市经济发展存在着明显的不平衡现象,东、中部和少数西部城市的发展居于前列,其余多数西部城市经济发展滞后,尤其是天水,定西、武威、张掖等城市出现"в趋同现象"。     

土地资源错配对中国城市工业绿色全要素生产率的影响

基于价格扭曲效应拓展资源错配模型,使用中国285个城市2004—2017年的工业投入产出数据,测算土地资源错配导致的城市工业绿色全要素生产率（GTFP）损失,并分析其时空变化。结果表明：① 土地资源错配对中国城市工业GTFP损失的年均贡献率为10.05%,已与能源错配并列成为继资本错配之后城市工业GTFP损失的重要贡献者。② 土地资源错配导致中国城市工业GTFP损失呈现“先小幅下降,再大幅上升,后较大幅度下降”的时序变化特征,但总体趋于上升,损失值介于1.10%~2.48%之间,纠正土地资源错配,中国现有城市的工业GTFP有望实现年均2%左右的再增加;东、中部地区土地资源错配导致的城市工业GTFP损失呈现出与全国层面类似的变化特征,西部地区的城市工业GTFP损失整体保持高位,总体稍有下降,东部地区是中国城市工业发展的主要阵地,其土地资源错配导致的城市工业GTFP损失主导着全国层面的城市工业GTFP损失变化。③ 土地资源错配导致中国城市工业GTFP损失的空间格局呈连片集聚化的发展特征,城市工业GTFP损失较高和高等级省份的数量有所增加,逐渐集中到以黄河流域为主的北方地区,损失低和中等等级省份的数量相应减少,逐渐集中到长江流域及东部沿海地区;土地资源错配导致中国城市工业GTFP损失的总差异呈缩小态势,三大地区内城市工业用地配置效率不均衡是土地资源错配导致中国城市工业GTFP损失差异的根本原因,其中西部地区内城市工业用地配置效率不均衡是主要原因,近年来的区域协同发展有利于三大地区间城市工业用地配置效率差距的缩小。     

GNSS���Թ۲�յ������о�

?????????????GNSS???????????????????????????λ???????????????????3????????????3??GNSS???????????????GNSS??????????????μ????????????????????????????????????￡??????????????????3????????????????????????????????????????????????????????????????????????????????????????????λ??????????????????????????????з???3.0?????????????????о??д????????????     

农村劳动力转移强度及其对农户发展的影响——基于河南省鄢陵县山岗村和刘圪垱村的调查

利用鄢陵县2个行政村1450份调查数据,定量分析了农村劳动力转移强度对农户发展的贡献度.结果表明:农村劳动力外出转移以短时间外出为主,外出时间在3～6个月的人数占总人数的72.55％,外出6～12个月的人数占总数的26.14％;农村劳动力外出转移地点主要分布在县内,其次为省内,农村劳动力外出转移的动力逐渐从区域差距转变为行业劳动效率差异;农村劳动力外出途径主要有亲戚朋友和同乡介绍,分别占到总数的46.41％和43.79％;2个村庄的劳动力转移强度分别为3915人·月和4685人·月,对农户收入的贡献率分为0.882和1.240.     

Erosion effects on soil properties of the unique red soil hilly region of the economic development zone in southern China

Erosion can have a significant impact on soil properties in areas characterized by undulating topography. The spatial trends of soil properties and the availability of soil nutrients change with land use conversion. Most studies on these changes in China, however, focus on the natural or agricultural ecosystems. Little attention has been paid to unique changes, such as the conversion of natural or agricultural land to economic development zones. To this end, it has been determined that the properties of the surface soil in an economic development zone with unique topography characterized by large mounds of earth and stones in the red soil hilly region in China. The aim of this study is to characterize the overall level and spatial patterns of the concentrations of topsoil selected soil properties, including pH, cation exchange capacity (CEC), bulk density, soil moisture, soil organic carbon (SOC), soil nitrogen (N), soil phosphorus (P), and soil potassium (K). Results show that the mean pH and CEC of soils is as low as 5.35 and 6.47?cmol?kg^?1, and the mean value of soil moisture is 0.30?g?g^?1, and the mean level of bulk density is 1.45?g?cm^?3. SOC and total P are as low as 5.89 and 0.35?g?kg^?1, while total N and total K have a high level of 8.44 and 25.2?g?kg^?1. The mean level of alkali-hydrolyzable N, Olsen P, and available K is 54.33, 6.35, and 120.33?mg?kg^?1, respectively, all at intermediate or low levels according to the Second National Soil Survey. All selected soil properties and nutrients have overall similar spatial patterns with the highest value on the lower slope positions except for alkali-hydrolyzable N. The results are most likely governed by the native properties of red soil, zonal climate, agricultural history for all the soils, and different degrees of soil erosion, and the probable impact of human activity like construction among different slope positions. Results indicate that (1) topography influences soil properties, as evidenced by the different spatial trends of the soil nutrients, and (2) human activity, especially construction, affects the soil properties of economic development zones. This study aims to provide valuable insights for the evaluation of soil quality as a prerequisite for land use planning in economic development zones.     

北京市GPS网解算时IGS站的选取实验

用实验的方法,讨论了北京市GPS台网在用GAMIT软件解算时,选取IGS基准站的空间分布(南北半球、网内网缘、均匀展布)、数量分布(0到8个IGS站)对解算结果精度的影响。由于受观测站数量和IGS站观测数据质量的影响,在保证精度的前提下,为了提高观测数据的利用率,需要增加IGS站数量。根据2004全年的解算结果,北京台网选择9到10个IGS站较为合适。     

地质样品中硫化物形式铁的分离和测定

提出一个利用次氯酸钠氧化铁硫化物碱性磺基水杨酸提取并直接测定碳酸盐相中铁硫化物的方法。结果表明,30%的NaClO溶液浸泡样品40h以上,可以完全释放铁硫化物并形成氢氧化铁胶体。0.1g/mL的碱性磺基水杨酸溶液则较容易地溶解新生成的氢氧化铁胶体,形成黄色的铁-磺基水杨酸络合物,可被分光光度法定量测定。该方法集选择性分离、富集和测定于一体,分析流程简单,结果可靠,适合地质样品中硫化物形式铁的测定。