Seasonal variation of volatile organic iodine compounds in the water column of Funka Bay,Hokkaido, Japan

Volatile organic iodine compounds (VOIs) emitted from the ocean surface to the air play an important role in atmospheric chemistry. Shipboard observations were conducted in Funka Bay, Hokkaido, Japan, bimonthly or monthly from March 2012 to December 2014, to elucidate the seasonal variations of VOI concentrations in seawater and their sea-to-air iodine fluxes. The bay water exchanges with the open ocean water of the North Pacific twice a year (early spring and autumn). Vertical profiles of CH₂I₂, CH₂ClI, CH₃I, and C₂H₅I concentrations in the bay water were measured bimonthly or monthly within an identified water mass. The VOI concentrations began to increase after early April at the end of the diatom spring bloom, and represented substantial peaks in June or July. The temporal variation of the C₂H₅I profile, which showed a distinct peak in the bottom layer from April to July, was similar to the PO₄ ^3? variation profile. Correlation between C₂H₅I and PO₄ ^3? concentrations (r = 0.93) suggests that C₂H₅I production was associated with degradation of organic matter deposited on the bottom after the spring bloom. CH₂I₂ and CH₂ClI concentrations increased substantially in the surface and subsurface layers (0–60 m) in June or July resulted in a clear seasonal variation of the sea-to-air iodine flux of the VOIs (high in summer or autumn and low in spring).     

Effects of forest harvesting on the occurrence of landslides and debris flows in steep terrain of central Japan

Landslides and debris flows associated with forest harvesting can cause much destruction and the influence of the timing of harvesting on these mass wasting processes therefore needs to be assessed in order to protect aquatic ecosystems and develop improved strategies for disaster prevention. We examined the effects of forest harvesting on the frequency of landslides and debris flows in the Sanko catchment (central Japan) using nine aerial photo periods covering 1964 to 2003. These photographs showed a mosaic of different forest ages attributable to the rotational management in this area since 1912. Geology and slope gradient are rather uniformly distributed in the Sanko catchment, facilitating assessment of forest harvesting effects on mass wasting without complication of other factors. Trends of new landslides and debris flows correspond to changes in slope stability explained by root strength decay and recovery; the direct impact of clearcutting on landslide occurrence was greatest in forest stands that were clearcut 1 to 10 yr earlier with progressively lesser impacts continuing up to 25 yr after harvesting. Sediment supply rate from landslides in forests clearcut 1 to 10 yr earlier was about 10‐fold higher than in control sites. Total landslide volume in forest stands clearcut 0 to 25 yr earlier was 5·8 × 10³ m³ km^?2 compared with 1·3 × 10³ m³ km^?2 in clearcuts >25 yr, indicating a fourfold increase compared with control sites during the period when harvesting affected slope stability. Because landslide scars continue to produce sediment after initial failure, sediment supply from landslides continues for 45 yr in the Sanko catchment. To estimate the effect of forest harvesting and subsequent regeneration on the occurrence of mass wasting in other regions, changes in root strength caused by decay and recovery of roots should be investigated for various species and environmental conditions. Copyright © 2007 John Wiley & Sons, Ltd.     

High-Mg diorites derived from sanukitic HMA magmas, Kyushu Island, southwest Japan arc: evidence from clinopyroxene and whole rock compositions

High-Mg diorites that have similar whole rock composition to high-Mg andesites (HMAs) should not be simply interpreted as rocks solidified from the HMA magmas, because the high-Mg diorites may be mafic cumulates derived from a different magma from the HMAs.

The HMAs contain unique clinopyroxenes with higher Mg# and Si than those of other sub-alkaline series igneous rocks. The Mg# and Si are controlled by the source magma composition rather than its crystallized conditions such as pressure and temperature. The chemical composition of clinopyroxenes would present important information for the investigation of the source of high-Mg diorites.

We considered the source of Early Cretaceous high-Mg diorites on Kyushu Island, southwest Japan arc, based on their clinopyroxene and whole rock compositions. The clinopyroxenes have similar chemical characteristics to those in HMAs rather than those in other sub-alkaline rocks. Moreover, the whole rock compositions are equivalent to the sanukitic HMA and do not show features of mafic cumulates. This indicates that the high-Mg diorites solidified from sanukitic HMA magmas. It is generally believed that the sanukitic HMA magmas involve the subduction of a young and/or hot oceanic slab was situated in their genesis. Therefore, the occurrence of the high-Mg diorites suggests that Kyushu was situated in the tectonic setting of young and/or hot slab subduction in the Early Cretaceous.     

The Higo metamorphic complex in Kyushu, Japan as the fragment of Permo–Triassic metamorphic complexes in East Asia

The Higo terrane in west-central Kyushu Island, southwest Japan consists from north to south of the Manotani, Higo and Ryuhozan metamorphic complexes, which are intruded by the Higo plutonic complex (Miyanohara tonalite and Shiraishino granodiorite).The Higo and Manotani metamorphic complexes indicate an imbricate crustal section in which a sequence of metamorphic rocks with increasing metamorphic grade from high (northern part) to low (southern part) structural levels is exposed. The metamorphic rocks in these complexes can be divided into five metamorphic zones (zone A to zone E) from top to base (i.e., from north to south) on the basis of mineral parageneses of pelitic rocks. Greenschist-facies mineral assemblages in zone A (the Manotani metamorphic complex) give way to amphibolite-facies assemblages in zones B, C and D, which in turn are replaced by granulite-facies assemblages in zone E of the Higo metamorphic complex. The highest-grade part of the complex (zone E) indicates peak P–T conditions of ca. 720 MPa and ca. 870 °C. In addition highly aluminous Spr-bearing granulites and related high-temperature metamorphic rocks occur as blocks in peridotite intrusions and show UHT-metamorphic conditions of ca. 900 MPa and ca. 950 °C. The prograde and retrograde P–T evolution paths of the Higo and Manotani metamorphic complexes are estimated using reaction textures, mineral inclusion analyses and mineral chemistries, especially in zones A and D, which show a clockwise P–T path from Lws-including Pmp–Act field to Act–Chl–Epi field in zone A and St–Ky field to And field through Sil field in zone D.The Higo metamorphic complex has been traditionally considered to be the western-end of the Ryoke metamorphic belt in the Japanese Islands or part of the Kurosegawa–Paleo Ryoke terrane in south-west Japan. However, recent detailed studies including Permo–Triassic age (ca. 250 Ma) determinations from this complex indicate a close relationship with the high-grade metamorphic terranes in eastern-most Asia (e.g., north Dabie terrane) with similar metamorphic and igneous characteristics, protolith assembly, and metamorphic and igneous ages. The north Dabie high-grade terrane as a collisional metamorphic zone between the North China and the South China cratons could be extended to the N-NE along the transcurrent fault (Tan-Lu Fault) as the Sulu belt in Shandong Peninsula and the Imjingang belt in Korean Peninsula. The Higo and Manotani metamorphic complexes as well as the Hida–Oki terrane in Japan would also have belonged to this type of collisional terrane and then experienced a top-to-the-south displacement with forming a regional nappe structure before the intrusion of younger Shiraishino granodiorite (ca. 120 Ma).     

Isotopic equilibration ages for the Miyanohara tonalite from the Higo metamorphic belt in central Kyushu, Southwest Japan: Implications for the tectonic setting during the Triassic

Abstract Miyanohara tonalite occurs in the middle part of the Higo metamorphic belt in the central Kyushu, Southwest Japan. This tonalite intrudes into early Permian Ryuhozan metamorphic rocks in the south and is intruded by Cretaceous Shiraishino granodiorite in the north. The Miyanohara tonalite yielded three mineral ages: (i) 110–100 Ma for Sm–Nd and Rb–Sr internal isochrons and for K–Ar hornblende; (ii) 183 Ma for Sm–Nd internal isochron; and (iii) 211 Ma for Sm–Nd internal isochron. The ages of 110–100 Ma may indicate cooling age due to the thermal effect of the Shiraishino granodiorite intrusion. The ages of 183 Ma and 211 Ma are consistent with timing of intrusion of the Miyanohara tonalite based on geologic constraints. The hornblende in the sample which gave 183 Ma shows discontinuous zoning under microscope, whereas the one which gave 211 Ma does not show zonal structure. These mineralogical features suggest that the 183 Ma sample has suffered severely from later tectonothermal effect compared with the 211 Ma sample. Therefore, the age of 211 Ma is regarded as near crystallization age for the Miyanohara tonalite. The magmatic process, geochronology and initial Sr and Nd isotope ratios for the Miyanohara tonalite are similar to those of early Jurassic granites from the Outer Plutonic Zone of the Hida belt that constitutes a marginal part of east Asia before the opening of the Japan Sea. Intrusion of the Miyanohara tonalite is considered to have taken place in the active continental margin during the late Triassic.     

The optical reflector system for the CANGAROO-II imaging atmospheric Cherenkov telescope

A new imaging atmospheric Cherenkov telescope with a light-weight reflector has been constructed. Light, robust, and durable mirror facets of containing carbon fiber reinforced plastic laminates were developed for the telescope. The reflector has a parabolic shape (f/1.1) with a 30 m² surface area, which consists of 60 spherical mirror facets. The image size of each mirror facet is 0°.08 (FWHM) on average. The attitude of each facet can be adjusted by stepping motors. After the first in situ adjustment, a point image of about 0°.14 (FWHM) over 3° field of view was obtained. The effect of gravitational load on the optical system was confirmed to be negligible at the focal plane. The telescope has been in operation with an energy threshold for γ-rays of 300 GeV since May 1999.     

Differential Fractionation of Rare Earth Elements in Oxidized and Reduced Granitic Rocks: Implication for Heavy Rare Earth Enriched Ion Adsorption Mineralization

Ion adsorption rare earth element (REE) deposits in southern China are the exclusive source of heavy REEs (HREEs) in the world, and this HREE‐enriched character of the deposits is inherited from the REE compositions of the underlying granitic rocks. Such HREE‐enriched rocks form from heavy fractionation of reduced granitic magmas. We explore why reduced granitic magmas are enriched in HREEs during the fractionation, based on the REE geochemistry of granitic rocks and abundance of REEs in their constituent minerals in the southwestern Japan arc of Cretaceous to Paleogene age. The compilation of the whole rock geochemistry and REE compositions of the granitic rocks of the Sanin (oxidized), Sanyo (reduced) and Ryoke (reduced) belts in the southwestern Japan arc indicates that: (i) light REEs (LREEs) decease with fractionation of the granitoids in the Sanin belt but this trend is not clear in the granitoids in the Sanyo belt and LREEs rather increase in the Ryoke granitoids; (ii) Eu decreases with fractionation in all the belts; and (iii) HREEs slightly, but steadily decrease in the Sanin belt but enrich significantly in the Sanyo and Ryoke belts with fractionation. Analytical results of REE concentrations by scanning electron microscope with energy dispersive X‐ray spectroscope and laser ablation‐inductively coupled plasma mass spectrometer in the constituent minerals in a granodiorite sample from the Sanin belt show a moderate concentration of REEs in hornblende (577 ppm) in addition to high concentrations in allanite (~20 %), britholite (~30 %), primary titanite (8922 ppm), apatite (4062 ppm), and zircon (1693 ppm). Because primary titanite and allanite are commonly present in the oxidized granitoids but not in the reduced ones, the REE depletion in the fractionated, oxidized granites is attributed to the crystallization of these minerals. In contrast, scarcity of these minerals in the reduced granitoids enriches REEs, in particular HREEs in the fractionated magmas, which finally precipitate REEs in the granites and pegmatites. Both positive, but different correlation ratios between the Nb and Dy concentrations in the granitoids of the Sanin and Sanyo‐Ryoke belts suggest that columbite–pyrochlore‐group and fergusonite‐group minerals are the major HREE host in the oxidized and reduced granites, respectively.