Problems with the interpretation of the 220 nm interstellar feature

The bump in the ultraviolet part of the interstellar extinction curve provides a great challenge in the modelling of interstellar dust. Its shape can be well approximated by a classical dispersion profile with a total halfwidth of 48 nm centred at 217 nm. Apart from few slightly deviating cases the parameters of the band seem to be surprisingly constant in the solar neighbourhood.The equivalent widthW of the 217 nm band shows a very tight correlation with the colour excessE(B-V). Studies of correlations with the strength of diffuse interstellar bands gave no conclusive results as to the nature of the band.The most common interpretation of the 217 nm feature as originating from small graphite grians meets several difficulties. No final decision on the carrier can be made at present.Paper presented at a Workshop on The Role of Dust in Dense Regions of Interstellar Matter, held at Georgenthal, G.D.R., in March 1986.     

High resolution gravimetric geoid heights and gravimetric vertical deflections of Europe including marine areas

Gravimetric geoid heights and gravimetric vertical deflections have been detemined for Europe including the Mediterranean Sea, North Sea, Norwegian Sea, Baltic Sea and parts of the North Atlantic Ocean in a 12′×20′ grid. The computation has been carried out by least squares spectral combination using closed integral formulas, combining 104 000 mean free air gravity anomalies in 6′×10′ blocks, 12 000 mean free air gravity anomalies in 1⁰×1⁰ blocks and the sherical harmonic model GEM9. The precision of the computed geoid heights has been estimated to ±1 m, the precision of the computed vertical deflections has been estimated to ±2″. Comparisons of the gravimetric geoid heights and vertical deflections with a number of other solutions have been carried out, confirming the precision estimation.     

On the influence of adequate Weddell Sea characteristics in a large-scale global ocean circulation model

Global ocean circulation models usually lack an adequate consideration of high-latitude processes due to a limited model domain or insufficient resolution. Without the processes in key areas of the global thermohaline circulation, the characteristics and flow of deep and bottom waters cannot be modeled realistically. In this study, a high-resolution (~20 km) ocean model focused on the Weddell Sea sector of the Southern Ocean is combined with a low-resolution (2^° × 2^°) global ocean model applying the state estimation technique. Temperature, salinity, and velocity data on two Weddell Sea sections from the regional model are used as constraints for the large-scale model in addition to satellite altimetry and sea-surface temperatures. The differences between the model with additional constraints and without document that the Weddell Sea circulation exerts significant influence on the course of the Antarctic Circumpolar Current with consequences for Southern Ocean water mass characteristics and the spreading of deep and bottom waters in the South Atlantic. Furthermore, a warming trend in the period 1993–2001 was found in the Weddell Sea and adjacent basins in agreement with float measurements in the upper Southern Ocean. Teleconnections to the North Atlantic are suggested but need further studies to demonstrate their statistical significance.     

Integration of stress testing with graph theory to assess the resilience of urban road networks under seismic hazards

Transportation networks daily provide accessibility and crucial services to societies. However, they must also maintain an acceptable level of service to critical infrastructures in the case of disruptions, especially during natural disasters. We have developed a method for assessing the resilience of transportation network topology when exposed to environmental hazards. This approach integrates graph theory with stress testing methodology and involves five basic steps: (1) establishment of a scenario set that covers a range of seismic damage potential in the network, (2) assessment of resilience using various graph-based metrics, (3) topology-based simulations, (4) evaluation of changes in graph-based metrics, and (5) examination of resilience in terms of spatial distribution of critical nodes and the entire network topology. Our case study was from the city of Kathmandu in Nepal, where the earthquake on April 25, 2015, followed by a major aftershock on May 12, 2015, led to numerous casualties and caused significant damage. Therefore, it is a good example for demonstrating and validating the developed methodology. The results presented here indicate that the proposed approach is quite efficient and accurate in assisting stakeholders when evaluating the resilience of transportation networks based on their topology.     

The Black Forest Observatory, Schiltach

The purpose of the geoscientific Observatory at Schiltach in the Black Forest in SW-Germany is to measure and monitor motions and deformations of the earth in a frequency band as broad as possible. The spectrum of geodynamic signal contains

• - the short period waves (up to 40 Hz) of near earthquakes,

• - the longer period body and surface waves from teleseismic events,

• - the free oscillations of the earth excited by giant earthquakes,

• - the earth tide deformations caused by the gravitational forces of the moon and the sun having periods of 12 h and longer,

• - deformations of the earth in a wide period range from other sources (e.g. atmosphere).

Besides providing high quality data with some continuity using ‘standard’ sensors, the observatory must be considered as an experimental station and research facility where new instruments and techniques can be tested.     

A new solid state diffusion model applied to inverse zoning and diffusion rims in minerals

Any oxide and silicate mineral which is nominally anhydrous but crystallized in the presence of H₂O incorporates traces of H₂O in solid solution. In the case of MgO it can be shown that OH^? pairs convert into H₂+O ₂ ^2? . If the H₂ molecules are lost, the O ₂ ^2? remain in the lattice as excess oxygen stabilized by excess cation vacancies. When the O ₂ ^2? anions decay either thermally or by decompression unbound O^? states (positive holes) are generated which lead to surface charges and subsurface space charge layers. Calculated space charge profiles are presented. O^? concentrations as small as 10–20 ppm suffice to create electric surface fields of the order of 4·10⁷ V·m^?1. The diffusion mechanism which derives from these premises incorporates novel features: the cation diffusion is coupled to the counterdiffusion of unbound and vacancy-bound O^? states. The cation diffusion is predicted to be very fast because first, it is field-enhanced (electrochemically driven) and second, it is not rate-limited by the intrinsic cation vacancy concentration nor by the counter-diffusion of other cations. The model may apply to cases of inverse zoning and diffusion rim formation in minerals under certain P-T conditions.     

A deuterium-hydrogen fractionation mechanism in magnesium oxide

Water dissolved in a nominally anhydrous oxide like MgO forms not only OH^? ions, as is usually assumed, but also molecular H₂ and peroxy anions O₂^2?. The specific lattice site where this reaction occurs has been identified for the model-type MgO structure: it is the fully OH^? compensated cation vacancy. In partially deuterated synthetic MgO, molecular D₂ forms preferentially to H₂, by a factor of the order of 4. Three methods have been used to study this very large D/H fractionation experimentally: mass spectrometry, electron spin resonance and infrared spectroscopy. All give consistent results and confirm that internal D/H fractionation occurs and is a function of the temperature. Theoretically the D/H fractionation is explained by the lower zeropoint energy of D₂ with respect to H₂, amplified by secondary processes through which the molecular hydrogen species become mobilized and eventually lost via diffusion. The possible consequences of such internal D/H fractionation processes are indicated for the interpretation of water and hydrogen release patterns, with varying D/H ratios, from terrestrial and extraterrestrial samples.     

Source parameters of intermediate-depth Vrancea (Romania) earthquakes from empirical Green's functions modeling

Several source parameters (source dimensions, slip, particle velocity, static and dynamic stress drop) are determined for the moderate-size October 27th, 2004 (M_W = 5.8), and the large August 30th, 1986 (M_W = 7.1) and March 4th, 1977 (M_W = 7.4) Vrancea (Romania) intermediate-depth earthquakes. For this purpose, the empirical Green's functions method of Irikura [e.g. Irikura, K. (1983). Semi-Empirical Estimation of Strong Ground Motions during Large Earthquakes. Bull. Dis. Prev. Res. Inst., Kyoto Univ., 33, Part 2, No. 298, 63–104., Irikura, K. (1986). Prediction of strong acceleration motions using empirical Green's function, in Proceedings of the 7th Japan earthquake engineering symposium, 151–156., Irikura, K. (1999). Techniques for the simulation of strong ground motion and deterministic seismic hazard analysis, in Proceedings of the advanced study course seismotectonic and microzonation techniques in earthquake engineering: integrated training in earthquake risk reduction practices, Kefallinia, 453–554.] is used to generate synthetic time series from recordings of smaller events (with 4 ≤ M_W ≤ 5) in order to estimate several parameters characterizing the so-called strong motion generation area, which is defined as an extended area with homogeneous slip and rise time and, for crustal earthquakes, corresponds to an asperity of about 100 bar stress release [Miyake, H., T. Iwata and K. Irikura (2003). Source characterization for broadband ground-motion simulation: Kinematic heterogeneous source model and strong motion generation area. Bull. Seism. Soc. Am., 93, 2531–2545.] The parameters are obtained by acceleration envelope and displacement waveform inversion for the 2004 and 1986 events and MSK intensity pattern inversion for the 1977 event using a genetic algorithm. The strong motion recordings of the analyzed Vrancea earthquakes as well as the MSK intensity pattern of the 1977 earthquake can be well reproduced using relatively small strong motion generation areas, which corresponds to small asperities with high stress drops (300–1200 bar) and high particle velocities (3–5 m/s). These results imply a very efficient high-frequency radiation, which has to be taken into account for strong ground motion prediction, and indicate that the intermediate-depth Vrancea earthquakes are inherently different from crustal events.     

Ein Algizidtest unter Laboratoriumsbedingungen

Vorgestellt wird cine Algizidtestvariante, die es erlaubt, unter laboratoriumsmäßig standardisierten Bedingungen ein repräsentatives Sortiment von Vertretern aus den Gruppen der Cyanophyceen, Diatomeen sowie monadaler, kokkaler und ulotrichaler Chlorophyceen zur Überprüfung der Wirksamkeit neu entwiekelter Substanzen einzusetzen. Die Testergebnisse liegen bereits nach 10 bzw. 24 h vor. Die elf Algenreinkulturstämme werden asynchron in Suspensionen bei 30 °C unter Dauerlicht kultiviert. Die Überprüfung der Wirksamkeit der Herbizide Amitrol, Paraquat, Atrazin, Fenuron und 2,4-D-Säure sowie der Algizide Quartolan, Cumasina ,,aktiv“ und Dimanin A zeigte, daß sich der als Bezugsorganismus eingesetzte Reinkulturstamm der Species Chlorella vulgaris (A 6) in seiner Empfindlichkeit gegenüber algiziden Substanzen als repräsentativ für einen großen Teil der übrigen Testorganismen erwies. Abweichungen in der Algizidempfindlichkeit einzelner Vertreter haben ihre Ursache vorwiegend in physiologischen und anatomisehen Besonderheiten bzw. im jeweiligen Volumen-Oberflächenverhältnis und der Bildung von Coenobien. Deshalb kann ein Test mit den ausgewählten Organismen in kurzer Zeit eine umfassende Aussage über den Wirkungsgrad algizider Substanzen ermöglichen.