Recommended Values of 239Pu, 240Pu and 239+240Pu Concentrations in Reference Material IAEA-315 (Marine Sediment) Estimated by Thermal Ionisation Mass Spectrometry, Inductively Coupled Plasma-Mass Spectrometry and Alpha Spectrometry

The recommended concentrations of ²³⁹Pu, ²⁴⁰Pu and ^239+240Pu in reference material IAEA‐315 (marine sediment) were estimated by three analytical methods: isotope dilution thermal ionisation mass spectrometry (TIMS), isotope dilution inductively coupled plasma‐mass spectrometry (ICP‐MS) and alpha spectrometry. The determination of ²³⁹Pu and ²⁴⁰Pu (^239+240Pu by alpha spectrometry) was carried out with samples from randomly selected bottles using each method. Plutonium‐238 was also measured by alpha spectrometry. A plutonium‐242 reference material was used as a spike for the quantitative analysis. The influence of ²⁴²Pu in the samples was therefore calculated; however, this contribution was less than the range of uncertainty and did not influence the final results. The obtained data were statistically analysed using variance component analysis and paired comparison. The combined standard uncertainties from “method/measurement”, “bottle” and “sub‐sample” were in the order of 3 to 6%. The main contributions to the uncertainty were from the material heterogeneity and from systematic differences between methods. Based on this study with twenty‐seven analyses using 10–14 g sample mass, concentrations of (38 ± 3) Bq kg^?1, (28 ± 3) Bq kg^?1 and (66 ± 4) Bq kg^?1 are proposed as recommended values for ²³⁹Pu, ²⁴⁰Pu and ^239+240Pu, respectively, and (9.5 ± 0.4) Bq kg^?1 for ²³⁸Pu as an information value in reference material IAEA‐315. In mass concentration units, these amount to (16.4 ± 1.2) ng kg^?1, (3.3 ± 0.4) ng kg^?1 and (0.015 ± 0.003) ng kg^?1 for ²³⁹Pu, ²⁴⁰Pu and ²³⁸Pu, respectively. The certified reference materials NIST 4350B and NIST 4354 were also analysed by TIMS for quality assurance of the method used in this study.     

Compositional variations in calciturbidites due to sea-level fluctuations,late Quaternary,Bahamas

Piston cores in Tongue of the Ocean, Bahamas, revealed an alternating sequence of periplatform ooze and bankderived turbidites of the past 5 glacial and interglacial periods. By using the point-count method we have analyzed the composition of the turbidite sediment. Variations in the bank-derived fraction are clearly linked to the glacial-interglacial cycles. Nonskeletal components (pellets; ooids; grapestones) are most abundant in interglacial turbidites, while skeletal components (calcareous algae; peneroplids and reef builders) dominate in glacial turbidites. We attribute this pattern to the exposure and flooding of the surrounding carbonate platforms during Late Quaternary sea-level cycles. Because nonskeletal sediment is produced in the interior of the platforms, its growth and subsequent export to the flanks are at a maximum when the banks are flooded, i.e. during interglacial periods. During glacials, skeletal grains dominate because the banks are exposed and carbonate production is limited to a narrow belt of skeletal sands and fringing reefs. The resulting compositional signal appeared to have a good correlation with aragonite variations in the periplatform ooze between the turbidites. Further, compositional variation parallels the change in turbidite frequency described earlier (»highstand bundling«). Frequency and composition of turbidites are both unaffected by diagenesis and therefore provide an excellent monitor of sealevel fluctuations.

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Zusammenfassung In Kolbenlotkernen aus der Tongue of the Ocean, Bahamas, bestehen die jüngsten fünf Glaziale und Interglaziale aus einer Wechselfolge von Periplattform-Schlamm und Turbiditen mit Flachwasser-Material. Die Zusammensetzung der neritischen Kornfraktion in den Turbiditen wurde durch Punktzählung ermittelt. Sie schwankt deutlich im Verlauf eines glazialen Zyklus. Abiogene Komponenten (Pellets, Ooide, Traubenklumpen) dominieren in den interglazialen Turbiditen, während Biogene (Kalkalgen, peneroplide Foraminiferen und Riffbildner) in glazialen Turbiditen vorherrschen. Wir erklären diese Schwankungen mit dem Auftauchen und Überfluten der Bahama Bänke während der jungquartären Schwankungen des Meeresspiegels. Die abiogenen Komponenten werden auf der Innenseite der Plattformen gebildet. Ihre Produktion und Export zu den Plattformflanken erreichen daher ein Maximum während der interglazialen Hochstände des Meeres. In den Glazialen dominieren biogene Komponenten, weil die Plattformen trocken liegen und die Karbonat-Produktion auf einen schmalen Streifen von Saumriffen und Biogensanden beschränkt ist.Die Zusammensetzung der Turbidite variiert im gleichen Rhythmus wie der Aragonitgehalt der zwischengeschalteten Periplattform-Schlamme. Überdies korreliert die Zusammensetzung gut mit der Häufigkeitsverteilung der Turbidite. Während der Interglaziale sind Turbidite häufiger als während der Glaziale (»Hochstand-Bündel«). Häufigkeitsverteilung und Zusammensetzung der Turbidite zusammen ergeben ein gutes, durch Diagenese nicht verwischbares Abbild der Schwankungen des Meeresspiegels.

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Résumé Dans le »Tongue of the Ocean« (Bahamas), des sondages à piston effectués dans les sédiments des cinq dernières périodes glaciaires et interglaciaires montrent une alternance de turbidites et de boues déposées en périphérie de plate-forme. La composition de la fraction néritique des turbidites, dé terminée par la méthode du compteur de points, montre une relation claire avec les cycles glaciaires. Les composants abiogènes (pellets, ooïdes, grapestones) dominent dans les turbidites interglaciaires, tandis que les composants biogènes (algues calcaires, foraminifères de type pénéroplide et organismes constructeurs) sont prépondérants dans les turbidites glaciaires. Nous attribuons cette répartition aux émersions et submersions successives du banc des Bahamas, consécutives aux variations du niveau de la mer au Quaternaire récent. Comme les composants abiogènes ont été formés sur la partie interne de la plate-forme, leur développement et leur transport vers les flancs étaient maximaux lorsque le banc était submergé, au cours des périodes interglaci aires. Par contre, les composants biogènes dominaient pendant les épisodes glaciaires, où la plate-forme était exondée et où la production de carbonate était restreinte à une zone étroite de récifs frangeants et de sables biogènes. Ces variations dans la composition des turbidites présentent une bonne corrélation avec la teneur en anhydrite des boues de périphérie de plate-forme intercalées entre les turbidites. Il existe également une bonne corrélation avec la fréquence des turbidites, plus élevée pendant les interglaciaires. La fréquence et la composition des turbidites ne sont pas affectées par la diagenèse et constituent donc un excellent témoin des fluctuations du niveau de la mer.

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Variability of Fram Strait sea ice export: causes, impacts and feedbacks in a coupled climate model

Analyses of a 500-year control integration of the global coupled atmosphere–sea ice–ocean model ECHAM5.0/MPI-OM show a high variability in the ice export through Fram Strait on interannual to decadal timescales. This variability is mainly determined by variations in the sea level pressure gradient across Fram Strait and thus geostrophic wind stress. Ice thickness anomalies, formed at the Siberian coast and in the Chukchi Sea, propagate across the Arctic to Fram Strait and contribute to the variability of the ice export on a timescale of about 9 years. Large anomalies of the ice export through Fram Strait cause fresh water signals, which reach the Labrador Sea after 1–2 years and lead to significant changes in the deep convection. The associated anomalies in ice cover and ocean heat release have a significant impact on air temperature in the Labrador Sea and on the large-scale atmospheric circulation. This affects the sea ice transport and distribution in the Arctic again. Sensitivity studies, simulating the effect of large ice exports through Fram Strait, show that the isolated effect of a prescribed ice/fresh water anomaly is very important for the climate variability in the Labrador Sea. Thus, the ice export through Fram Strait can be used for predictability of Labrador Sea climate up to 2 years in advance.     

Relations between electrical conductivity and petrological parameters of the crust and upper mantle

Laboratory data of the electrical conductivity of rocks and minerals pertinent to the deeper crust and upper mantle and summarized. They are discussed in the context of a theory to calculate effective conductivities of materials in the state of partial melt. Most published data have been obtained by too rapid measurements, i.e. without reaching an equilibrium state of the sample. Conductivity measurements on a material similar to the composition of pyrolite are not het known, their importance is outlined. A global conductivity distribution obtained by electromagnetic induction studies is represented by a few results covering oceanic and continental areas. Till today it seems to be a doubtful venture to deduce the temperature of the upper mantle or even the existence of a partial molten asthenosphere from a global conductivity distribution. On a more local scale the correlation of electrical conductivity with temperature and state of the material seems to be more realistic. This is tentatively shown by two petrological models of the Afar depression in Ethiopia and of the midoceanic rift.     

Perceptions of local community members towards foreign aid: A case study of Vava'u,Tonga

Foreign aid has arguably played a significant role in the economic development of the Pacific Island countries. Tonga is deemed to have succeeded in implementing the principles of the Paris Declaration of 2005, especially Ownership, Alignment and Harmonisation, by aid funding channelled through state institutions. Nevertheless, it is still unknown if the aid effect has reached civil society, and how community members perceive aid. This article examines the perceptions of community members towards foreign aid, using the case study of the archipelago of Vava'u, Tonga.     

Biogenic carbon flows through the planktonic food web of the Amundsen Gulf (Arctic Ocean): A synthesis of field measurements and inverse modeling analyses

Major pathways of biogenic carbon (C) flow are resolved for the planktonic food web of the flaw lead polynya system of the Amundsen Gulf (southeast Beaufort Sea, Arctic Ocean) in spring-summer 2008. This period was relevant to study the effect of climate change on Arctic marine ecosystems as it was characterized by unusually low ice cover and warm sea surface temperature. Our synthesis relied on a mass balance estimate of gross primary production (GPP) of 52.5 ± 12.5 g C m⁻² calculated using the drawdown of nitrate and dissolved inorganic C, and a seasonal f-ratio of 0.64. Based on chlorophyll a biomass, we estimated that GPP was dominated by phytoplankton (93.6%) over ice algae (6.4%) and by large cells (>5 μm, 67.6%) over small cells (<5 μm, 32.4%). Ancillary in situ data on bacterial production, zooplankton biomass and respiration, herbivory, bacterivory, vertical particle fluxes, pools of particulate and dissolved organic carbon (POC, DOC), net community production (NCP), as well as selected variables from the literature were used to evaluate the fate of size-fractionated GPP in the ecosystem. The structure and functioning of the planktonic food web was elucidated through inverse analysis using the mean GPP and the 95% confidence limits of every other field measurement as lower and upper constraints. The model computed a net primary production of 49.2 g C m⁻², which was directly channeled toward dominant calanoid copepods (i.e. Calanus hyperboreus 20%, Calanus glacialis 10%, and Metridia longa 10%), other mesozooplankton (12%), microzooplankton (14%), detrital POC (18%), and DOC (16%). Bacteria required 29.9 g C m⁻², a demand met entirely by the DOC derived from local biological activities. The ultimate C outflow comprised respiration fluxes (82% of the initial GPP), a small sedimentation (3%), and a modest residual C flow (15%) resulting from NCP, dilution and accumulation. The sinking C flux at the model limit depth (395 m) supplied 60% of the estimated benthic C demand (2.8 g C m⁻²), suggesting that the benthos relied partly on other C sources within the bottom boundary layer to fuel its activity. In summary, our results illustrate that the ongoing decline in Arctic sea ice promotes the growth of pelagic communities in the Amundsen Gulf, which benefited from a ∼80% increase in GPP in spring-summer 2008 when compared to 2004 – a year of average ice conditions and relatively low GPP. However, 53% of the secondary production was generated within the microbial food web, the net ecological efficiency of zooplankton populations was not particularly high (13.4%), and the quantity of biogenic C available for trophic export remained low (6.6 g C m⁻²). Hence it is unlikely that the increase in lower food web productivity, such as the one observed in our study, could support new harvestable fishery resources in the offshore Beaufort Sea domain.     

Über die Verteilung und Neubildung der nichtkarbonatischen Mineralkomponenten der Oberkreide aus der Umgebung von Hannover

Comparative investigations were made on the non-carbonate components of calcareous sediments of the upper chalk formation of the Hanover region.The mineral composition of the residues insoluble in 0.5 n HC1 has first been determined optically and by X-ray photographs and described. The quantitative analysis of the components contained was effected by microscopic counting using the phase contrast method up to the grain size of 2 u, and for the clay fractions proper by X-ray phase analyses.In addition to the minor components (feldspars, biotite, pyrite, marcasite, glauconite, heavy minerals and mikro-fossils) the residues contain quartz, muscovite, illite, montmorillonite and kaolinite.The calcareous sediments of the upper senon formation are specially characterized by the occurrence of authigenic heulandite crystals which could be analysed and described here for the first time. Moreover secondary crystallization of quartz, turmaline and albite could be observed in all the samples analysed.