下辽河平原景观格局演变与预测分析

以下辽河平原为研究对象,选取1980年、2010年和2018年Landsat TM/ETM+OLI卫星图像进行解译,得到3期土地利用数据,定量分析下辽河平原近40年土地利用时空变化特征.结合地形、交通通达度及限制转化因子采用FLUS(Future Land Use Simulation)模型对流域未来土地利用变化情景及景观格局进行了预测.结果表明:1980-2018年水田、林地、草地、沼泽面积均减少,其中水田面积减少量最大,占比减少了8.59％,旱地、水域和城镇的面积均有所上升,旱地的增长面积最大,占比增加了6.19％;水田、林地、水域转入为旱地面积最大,旱地转出为建设用地面积最大;1980-2018年景观格局发生了较大变化,景观的破碎化程度降低,斑块之间的连通度、聚集程度升高,土地利用的集约化程度增大;2018-2040年,下辽河平原建设用地和水田的变化面积最大,城市化过程更加显著,景观的多样性及空间异质性降低,人类对环境的干扰能力变大.     

基于点云数据的不规则文物三维重建——以经幢为例

海量点云数据可以较好地构建文物的三维建模，针对文物复杂的表面结构，传统的算法很难达到精细建模，为了解决复杂模型表面的空间三角网构网问题，本文结合空间三角形的法向量构建三角网，以空间三角网表面的曲率为约束条件，构建物体表面的空间三角网，然后对构建的空间三角网进行精细建模。以昆明市文物——经幢为例进行三维重建试验，结果表明，新方法适合室内文物的三维建模，可以达到较好的效果。     

贵州夜郎湖表层水体地球化学昼夜变化及其影响因素

为探究岩溶水库水文地球化学行为过程,对贵州普定夜郎湖表层水体进行了为期3 d的高分辨率昼夜监测。结果表明：1）多变的天气和水文条件叠加导致水体离子指标昼夜变化不显著,规律性较差。而水温、DO、pH值、SpC、SIc、pCO₂等常规理化指标受水温变化和生物作用表现出明显的昼夜波动。2）利用亨利常数和主成分分析,得到温度变化、生物作用、人类活动、水库的蓄水与放水对夜郎湖水库水文地球化学特征变化的贡献率分别为21.66%、17.28%、14.08%和10.22%,说明作用于水库水文地球化学行为的因子具有多元性。3）δ ¹⁸O表现出与DO一致的波动趋势,即白天上升,晚上下降,反映在短时间尺度上,氢氧稳定同位素变化受控于生物过程（主要是呼吸作用过程）;而对比水库水体和大气降水的d-excess（d值）发现,水库水体的d值（8.21‰）显著偏低于当地大气降水的d值（9.64‰）,说明在长时间尺度上,主要受蒸发效应引起的不平衡分馏影响。     

Reducing uncertainty in stochastic streamflow generation and reservoir sizing by combining observed,reconstructed and projected streamflow

Reservoir sizing is one of the most important aspects of water resources engineering as the storage in a reservoir must be sufficient to supply water during extended droughts. Typically, observed streamflow is used to stochastically generate multiple realizations of streamflow to estimate the required storage based on the Sequent Peak Algorithm (SQP). The main limitation in this approach is that the parameters of the stochastic model are purely derived from the observed record (limited to less than 80 years of data) which does not have information related to prehistoric droughts. Further, reservoir sizing is typically estimated to meet future increase in water demand, and there is no guarantee that future streamflow over the planning period will be representative of past streamflow records. In this context, reconstructed streamflow records, usually estimated based on tree ring chronologies, provide better estimates of prehistoric droughts, and future streamflow records over the planning period could be obtained from general circulation models (GCMs) which provide 30 year near-term climate change projections. In this study, we developed paleo streamflow records and future streamflow records for 30 years are obtained by forcing the projected precipitation and temperature from the GCMs over a lumped watershed model. We propose combining observed, reconstructed and projected streamflows to generate synthetic streamflow records using a Bayesian framework that provides the posterior distribution of reservoir storage estimates. The performance of the Bayesian framework is compared to a traditional stochastic streamflow generation approach. Findings based on the split-sample validation show that the Bayesian approach yielded generated streamflow traces more representative of future streamflow conditions than the traditional stochastic approach thereby, reducing uncertainty on storage estimates corresponding to higher reliabilities. Potential strategies for improving future streamflow projections and its utility in reservoir sizing and capacity expansion projects are also discussed.     

山西省大同市新荣区石墨矿岩石矿物地球化学特征与成因

山西省大同市新荣区石墨矿带总体呈北东—南西向展布, 长约22 km, 赋矿层位为中下太古界右所堡组, 岩性为含石墨黑云斜长片麻岩。目前该矿带上已有7个勘查区, 累计查明晶质石墨矿物资源量约 5000万吨, 但对其矿床成因类型研究相对较少。本文收集整理和分析总结了区域内地质资料及化验分析结果, 采用变质岩原岩恢复的四种方法确定该矿带的成因: 从石墨矿带的矿体产状和岩石组合、岩相学和矿物学特征定性判断该矿带矿床为沉积岩区域深变质成矿类型; 矿体样品地球化学微量元素比值(Sr:Ba等)符合副变质岩特征; 稀土元素配分曲线及其研究表明矿体及围岩具有沉积岩变质特征; 以TiO2-F图解、[(al+fm)–(c+alk)]/Si图解以及(al-alk):c图解展示的岩石化学特征半定量地确认新荣区石墨矿带矿床为以黏土岩为主的区域变质成矿。新荣区石墨矿带成因类型的确定填补了该区域矿床成因类型研究的空白, 为下一步地质找矿及建模提供了重要依据; 三种图解相结合, 逐步缩小原岩范围, 锁定原岩类型, 为变质岩原岩恢复及矿床成因研究提供了新的思路和判别方法。     

Peroxymonosulfate Improves the Activity and Stability of Manganese Oxide for Oxidation of Arsenite to Arsenate

Manganese oxide has been widely investigated for oxidation of arsenite (As(III)) to arsenate (As(V)) due to its high redox potential; however, it becomes extremely unstable after reuse. Here, As(III) oxidation activity and stability of manganese oxide in the presence of peroxymonosulfate (PMS) is investigated. Batch experimental results reveal that manganese oxide/PMS exhibits high catalytic activity for As(III) oxidation compared to manganese oxide or PMS alone. Addition of PMS to manganese oxide not only reveals long‐term stability for As(III) oxidation, but also shows high As(III) oxidation activity in the presence of coexisting ions such as As(V) and phosphate. Quenching tests reveal that As(III) oxidation in the manganese oxide/PMS system is attributed to activation of PMS by manganese oxide at different oxidation states (Mn(III) and Mn(IV)), and the generation of sulfate radicals that are responsible for As(III) oxidation.     

内蒙古东珺铅锌银矿床成矿机制的热力学相图研究

大兴安岭广泛分布与岩浆热液作用有关的铅锌多金属矿床,对于该类型矿床中成矿物质的运移沉淀机制和矿物共生组合的研究是揭示成矿机制的关键。本文选取了大兴安岭成矿带东珺典型中高温岩浆热液型铅锌银矿床,通过对该矿床进行详细的野外地质调查和镜下矿物共生组合的研究,结合流体包裹体的显微测温研究,激光拉曼测试和H-O同位素测试,选择了方铅矿、闪锌矿和黄铁矿三种主要金属硫化物进行了热力学平衡的相关计算,依据包裹体显微测温结果选取了473K、513K、553K、593K四个温度截面绘制了热力学Eh-pH、lg[Pb~(2+)]-pH和lg[HS~-]-pH相图。结果显示随着热液成矿过程的不断演化,主要金属硫化物及其共生组合由Py(Ⅰ)→Py(Ⅱ)+Gn(Ⅰ)+Sp(Ⅰ)→Gn(Ⅰ)+Sp(Ⅰ)→Gn(Ⅰ)+Sp(Ⅱ)→Gn(Ⅱ)+Sp(Ⅱ)→Gn(Ⅱ)。流体沸腾、流体混合和水岩反应是东珺铅锌银矿床的主要成矿机制,由此引发的温度、离子活度、Eh和pH的变化对于成矿物质的运移沉淀和硫化物共生组合的形成具有重要的控制作用,东珺矿床热液成矿期主要金属硫化物及其共生组合的形成是多因素协同作用的结果。此研究对于解释大兴安岭典型热液型铅锌多金属矿床的运移沉淀机制和矿物共生组合特征具有重要的指导意义。     

长河坝—黄金坪水库区域地震台网监测能力分析

位于四川省甘孜藏族自治州康定市内大渡河干流的长河坝-黄金坪水电站，为大渡河流域开发中，以长河坝、大岗山、瀑布沟等形成主要梯级格局开发方案中，"三库22级"水电站中的第10和11级电站，其地震监测台网也采用梯级设计方式，长河坝-黄金坪上下游水库地震监测台网统一设计、建设及监测，共享同一地震监测能力。通过对监测设备的技术指标、台基地噪声水平和震级-频度对数关系的分析，结果表明，长河坝-黄金坪水库区域地震固定台站建成后，地震监测能力达到并优于设计的理论监测能力，地震监测震级达到下限为M_L 0.5的设计要求。     

藏南错那洞穹隆早渐新世含绿柱石花岗伟晶岩的成因机制及其地质意义

错那洞穹隆位于特提斯喜马拉雅东段,发育钨锡-铍稀有金属成矿作用。错那洞穹隆由上(边部)、中(幔部)、下(核部)3个构造层组成,分别以上、下拆离断层为分界线,其中在幔部强变形带中发育一套同构造变形的含绿柱石花岗伟晶岩。锆石U-Pb年代学表明,该套伟晶岩形成于33.7±0.4Ma(MSWD=1.12),为早渐新世岩浆活动的产物,明显早于穹隆中目前发现的淡色花岗岩(20～14Ma)。岩石地球化学和Sr-Nd-Hf同位素测试结果显示:(1)错那洞早渐新世花岗伟晶岩为过铝质高钾富钠花岗质岩石,具有较高SiO_2(69.74%)、高Al_2O_3(14.58%)及较低的CaO、MgO、MnO、TiO_2的特征;(2)高场强元素及大离子亲石元素均呈现高度变化特征,富集轻稀土元素,亏损重稀土元素;(3)Sr同位素初始值(0.696308～0.751604)与Nd同位素初始值(-11.48～-12.05)总体在角闪岩与泥质片麻岩之间,ε_(Hf)(t)值介于-5.4～0.1之间(主要集中在-5.4～-1.8)。综合研究表明,错那洞早渐新世含绿柱石伟晶岩是角闪岩与泥质片麻岩混熔的结果,其中泥质片麻岩的部分熔融起主导作用,其形成与藏南拆离系(STDS)的活动密切相关,表明错那洞地区新生代地壳深熔作用主要源岩在早渐新世已完成了从角闪岩向泥质片麻岩的转变。该同构造变形含绿柱石伟晶岩的发现,揭示错那洞穹隆的成穹作用至少在早渐新世便已开始。铍稀有金属可能在早渐新世已有了初始富集,而在中新世大规模岩浆活动中实现了巨量富集。     

A review of fully coupled atmosphere-hydrology simulations

Journal of Geographical Sciences - The terrestrial hydrological process is an essential but weak link in global/regional climate models. In this paper, the development status, research hotspots and...