Pressures on an intensive irrigated cash-crop system in coastal Ghana

This paper outlines the results of recent interdisciplinary fieldwork in Anloga on Keta Lagoon, Ghana. Vegetable production has been undertaken at Anloga since the nineteenth century and is now highly intensive and carefully regulated. Farmers produce shallots and other crops utilising irrigation water, mostly from wells which tap a shallow fresh-water perched aquifer. However, farmers have been expanding their cultivation activities from the lagoon-side, encouraged by a World Bank supported programme which provides for well-sinking and some electric pumps. The project has environmental and socio-economic implications which give cause for concern. The research employs field investigation to explore both the physical and political economy context and implications of recent change and considers the opportunities for community-based water and crop regulation.     

Journeys to the street: the complex migration geographies of Ugandan street children

Children have generally been afforded little attention in migration research or unsatisfactorily included within family migration. Although they are an important consideration in family decisions to move, children also engage in autonomous, independent migration. Further, researchers now argue for the need to situate migration within political, economic and social conditions to obtain a full understanding of why people migrate. Through the use of children-centred research methods, and in-depth interviews with key informants, this paper considers children's journeys to the street in Uganda. By integrating an analysis of Ugandan street children's spatial origins with the familial and societal contexts of their migration decisions, this research highlights the complexity of their migration. In addition, an exploration of the impact of changing social, spatial and temporal conditions on street children's movements illustrates that their journeys are far more than just single processes.     

Tidal Stress/Strain and the b-values of Acoustic Emissions at the Underground Research Laboratory, Canada

The correlation between the b-values of acoustic emissions (AEs) and the phase of the moon was investigated at the Underground Research Laboratory (URL) in Canada. The same data as those used in Iwata (2002) were examined, which showed that the occurrence of AEs is correlated with the phase of the moon. It was expected, therefore, that the b-value of the AEs would also be sensitive to tidal stress/strain fluctuations. We investigated the variation of the b-values as a function of the phase of the moon. Results show that b-values immediately following the times of full/new moon are higher than those at other times. Using AIC (Akaike Information Criterion) and random (Monte Carlo) simulations, it was confirmed that this feature is statistically significant. We also investigated whether or not there was a change in the b-values immediately before the times of full/new moon, but no statistically significant change was observed. The results suggest that the effect of stress/strain fluctuations on AE occurrences at the URL is asymmetric to the times of full/new moon.All authors are members of the Academic Robotics Group. In listing The Academic Robotics Group, the authors are endeavoring to place each of the participant institutions on an equal footing in terms of effort and authorship. M. A. Talamini is serving as presenter.     

Cu(II) adsorption at the calcite-water interface in the presence of natural organic matter: Kinetic studies and molecular-scale characterization

We have characterized the adsorption of Suwannee River humic acid (SRHA) and Cu(II) on calcite from preequilibrated solutions at pH 8.25. Sorption isotherms of SRHA on calcite follow Langmuir-type behavior at SRHA concentrations less than 15 mg C L⁻¹, whereas non-Langmuirian uptake becomes evident at concentrations greater than 15 mg C L⁻¹. The adsorption of SRHA on calcite is rapid and mostly irreversible, with corresponding changes in electrostatic properties. At pH 8.25, Cu(II) uptake by calcite in the presence of dissolved SRHA decreases with increasing dissolved SRHA concentration, suggesting that formation of Cu-SRHA aqueous complexes is the primary factor controlling Cu(II) sorption at the calcite surface under the conditions of our experiments. We also observed that surface-bound SRHA has little influence on Cu(II) uptake by calcite, suggesting that Cu(II) coordinates to calcite surface sites rather than to surface-bound SRHA.Cu K-edge X-ray absorption near edge structure (XANES) and extended X-ray absorption fine-structure (EXAFS) spectroscopic results show that the local coordination of Cu adsorbed at the calcite surface is very similar in the presence and absence of SRHA. Ca backscatterers at ∼3.90 Å indicate that Cu(II) forms tetragonally distorted inner-sphere adsorption complexes in both binary and ternary systems. Subtle differences in the XANES and EXAFS between binary sorption samples and ternary sorption samples, however, prevent us from ruling out the formation of ternary Cu-SRHA surface complexes. Our findings demonstrate that SRHA plays an important role in controlling the fate and transport of Cu(II) in calcite-bearing systems.     

Planetesimal sulfate and aqueous alteration in CM and CI carbonaceous chondrites

Water-soluble sulfate salts extracted from six CM chondrites have oxygen isotope compositions that are consistent with an extraterrestrial origin. The Δ¹⁷O of sulfate are correlated with previously reported whole rock δ¹⁸O and with an index of meteorite alteration, and may display a correlation with the date of the fall. The enrichments and depletions for Δ¹⁷O of water-soluble sulfate from the CM chondrites relative to the terrestrial mass dependent fractionation line are consistent with sulfate formation in a rock dominated asteroidal environment, and from aqueous fluids that had undergone relatively low amounts of oxygen isotope exchange and little reaction with anhydrous components of the meteorites. It is unresolved how the oxidation of sulfide to sulfate can be reconciled with the inferred low oxidation state during the extraterrestrial alteration process. Oxygen isotope data for two CI chondrites, Orgueil and Ivuna, as well as the ungrouped C2 chondrite Essebi are indistinguishable from sulfate of terrestrial origin and may be terrestrial weathering products, consistent with previous assertions. Our oxygen isotope data, however, can not rule out a preterrestrial origin either.     

Why chromatic imaging matters

During the last two decades, the first generation of beam combiners at the Very Large Telescope Interferometer has proved the importance of optical interferometry for high-angular resolution astrophysical studies in the near- and mid-infrared. With the advent of 4-beam combiners at the VLTI, the u ? v coverage per pointing increases significantly, providing an opportunity to use reconstructed images as powerful scientific tools. Therefore, interferometric imaging is already a key feature of the new generation of VLTI instruments, as well as for other interferometric facilities like CHARA and JWST. It is thus imperative to account for the current image reconstruction capabilities and their expected evolutions in the coming years. Here, we present a general overview of the current situation of optical interferometric image reconstruction with a focus on new wavelength-dependent information, highlighting its main advantages and limitations. As an Appendix we include several cookbooks describing the usage and installation of several state-of-the art image reconstruction packages. To illustrate the current capabilities of the software available to the community, we recovered chromatic images, from simulated MATISSE data, using the MCMC software SQUEEZE. With these images, we aim at showing the importance of selecting good regularization functions and their impact on the reconstruction.