Sample treatment with focused ultrasound and bath sonication as a powerful tool for the evaluation of cadmium pollution in estuarine waters

A new sample treatment was developed for the determination of dissolved cadmium in Tagus estuarine waters, based on focused ultrasound in conjunction with small volumes in the extraction steps for Cd pre-concentration. Cadmium was first pre-concentrated using a classical approach (APDC as the complexing agent and MIBK as the organic phase) and then back-extracted into HNO₃ with the aid of focused ultrasound, which reduced the acid concentration by more than one order of magnitude (from 4 to 0.1 mol L^− 3). This sample treatment was accomplished in less than 5 min, using low sample volume (20 mL), and low-volume, low-concentration reagents. The pre-concentration factor used in this work was 25, but different sample/organic volume ratios may be used in order to increase that value. The limit of detection and the limit of quantification in Tagus water samples were 0.03 nmol L^− 1 and 0.1 nmol L^− 3, respectively. Recoveries from spiked Tagus water were higher than 90%. The procedure was validated using the reference estuarine water NRC-SLEW-3. In the solubilization of Cd particulate, bath ultrasonication was used in conjunction with HNO₃ + HCl, followed by H₂O₂, which took about 2 instead of the usual 12 h (cooling included) when high-pressure microwave digestion is used.     

黄河口及其邻近海域大型底栖动物的初步研究——(二)生物与沉积环境的关系

1985年5—6月对黄河口及其邻近海域的27个站进行了大型底栖动物的首航次定量调查。分别对18种环境因子和68个优势种和习见种所做的聚类分析显示了黄河口水下三角洲与邻近海域的某些差异,并联系沉积环境将所研究海域划分为四个区:黄河口水下三角洲、莱州湾、渤海中部和渤海湾东部。对大型底栖动物与沉积速率的关系也做了初步探讨。     

基于BP人工神经网络的水体遥感测深方法研究

利用Landsat7ETM＋遥感图像反射率和实测水深值之间的相关性,建立了动量BP人工神经网络水深反演模型,并对长江口南港河段水深进行了反演.结果表明：具有较强非线性映射能力的动量BP神经网络模型能较好地反演出长江口南港河段的水深分布情况;由于受长江口水体高含沙量的影响,模型对小于5 m的水深值反演精度较高,而对大于10 m的水深值反演精度较低.     

珠江河口虎门的地貌动力学研究

以野外现场调查、数值模拟和前人研究成果综合分析虎门的地貌动力学特征。因峡口上、下游水域开阔,涨落潮过程中发育着强大的双向不对称射流系统;由于峡口区流速最大,发育着冲刷深槽,而峡口的上、下游因流速降低,泥沙有规律地沉积,形成了涨潮三角洲与落潮三角洲堆积体,出现纵向上“马鞍”形断面特征和横向上“槽-脊-滩”的地貌特征,与其动力特征相适应。     

长江口南支沉积物元素地球化学分区与环境指示意义

对采自长江口南支的130个表层底质沉积物样品采用X射线荧光光谱法进行了20种常、微量元素的地球化学分析。在此基础上,应用系统聚类法对该区域进行了元素地球化学分区。研究结果表明,研究区主要可以分为两大地球化学分区:Ⅰ区以相对富集SiO2,Sr,Zr元素为典型特征,主要涵盖5 m等深线以浅的长江三角洲前缘区;Ⅱ区以相对富集Al2O3,TFe2O3(全铁),MgO,Pb元素为典型特征,涵盖了前三角洲的广大区域。从地球化学分区的空间分布来分析,这两个分区元素之间的差异反映的是沉积水动力条件与沉积介质物化性质这两个环境要素空间分布的差异性,即在研究区内,表层沉积物元素地球化学空间分布的差异性实质上反映了沉积环境空间分布的差异性。     

黄河三角洲河口段海岸线动态及演变预测

黄河淤积造陆形成黄河三角洲,黄河三角洲地区表层均为第四系全新统松散沉积物,以细颗粒的粉砂为主,呈松散—稍密状态,孔隙度较高,稳定性较差,极易受到海洋动力侵蚀造成海岸蚀退。随着黄河断流天数逐年增多,使黄河来水来砂量逐年递减,在黄河淤积和海洋动力交互或共同影响下,现代黄河三角洲海岸线迅速地发生着淤进蚀退交替的演变。自1976年黄河人工改道走清水沟流路以来,黄河三角洲河口段海岸线总体处于淤进状态。对河口地区1986—2004年间遥感图像进行比较分析,发现有关岸线位置的原始数据间存在近似的二元一次线性相关关系,通过建立回归模型,对2005—2010年河口地区海岸线形态进行了演变预测。预测结果表明,2005—2010年间黄河三角洲原河口沙嘴前端处于蚀退状态,而北汊1流路附近有一直淤进扩张的趋势。     

Progress in Environmental Evolvement and Environmental Archaeology Study in the Yangtze Delta （China）

A review was conducted on the environmental evolvement and environmental archaeological research since the 1980s in the Yangtze Delta. Former environmental evolvement and environmental archaeological research results can be summed up into 4 aspects： 1） Formation and evolution of the Taihu Lake; 2） Transgression and sea-level changes in the Holocene epoch; 3） Reconstruction of the pre-historical environment; and 4） Impacts of environmental variations on the rise and fall of human civilization （formation of the cultural interruptions）. Based on this review, some limitations in the present research methods and possible outcomes are pointed out in this paper.     

Benthic nutrient fluxes in the intertidal flat within the Changjiang （Yangtze River） Estuary

In an annual cycle from March 2005 to February 2006, benthic nutrient fluxes were measured monthly in the Dongtan intertidal flat within the Changjiang （Yangtze River） Estuary. Except for NH4^＋, there always showed high fluxes from overlying water into sediment for other four nutrients. Sediments in the high and middle marshes, covered with halophyte and consisting of macrofauna, demonstrated more capabilities of assimilating nutrients from overlying water than the low marsh. Sampling seasons and nutrient concentrations in the overlying water could both exert significant effects on these fluxes. Additionally, according to the model provided by previous study, denitrification rates, that utilizing NO3- transported from overlying water （Dw） in Dongtan sediments, were estimated to be from -16 to 193 μmol·h^-1·m^-2 with an average value of 63 μmol·h^-1·m^-2 （n=18）. These estimated values are still underestimates of the in-situ rates owing to the lack of consideration of DN, i.e., denitrification supported by the local NO3^- production via nitrification.     

Environmental Redox Changes of the Ancient Sea in the Yangtze Area during the Ordo-Silurian Transition

Extensive organic-matter （OM） rich facies （black shales） occur in the Ordo-Silurian boundary successions in the Yangtze area, South China. To investigate the redox changes of the Yangtze Sea during the Ordo-Silurian transition, two OM sections （Wangjiawan in Yichang, Hubei Province, and Sanjiaguan in Zhangjiajie, Hunan Province） straddling the Ordo-Silurian boundary are studied. The measurements finished in this study include contents of the total organic carbon （TOC）, pyrite sulphur, and different species of Fe, including dithionite-extractable Fe （FED）, pyrite Fe （FeP）, HCl-extractable Fe （FeH）, and total Fe （FeT）, in black shales, as well as other redox proxies, such as the SIC ratio, the ratio between highly reactive Fe （FeHR = FeD ＋ FeP） and FeT, and the FeP/（FeP ＋ FeH） ratio, known as the degree of pyritization （DOP）. In the Wangjiawan section, the Middle Ashgill sediments have high FeHR/FeT ratios （0.20-0.77; avg. 0.45）, high DOP values （0.21-0.72; avg. 0.54）, and a relatively constant sulfur content independent of the organic carbon content. By the contrast, the mid-early Hirnantian deposits generally have low FeHR/FeT ratios （0.10-0.35; avg. 0.21）, low DOP values （0.11- 0.40; avg. 0.28）, and SIC values are clustering on the normal marine value （SIC = 0.36）. The late Hirnantian and early Rhuddanian deposits, similar to those of the Middle Ashgill deposits, are characterized by high FeHR/FeT ratios （0.32-0.49; avg. 0.41）, high DOP values （0.46-0.68; avg. 0.53） and fairly constant sulfur contents. These data suggest the occurrences of marine anoxia on the Yangtze Sea shelf during intervals of the Mid Ashgill, Late Hirnantian and Early Rhuddanian, and ventilated and oxygenated marine conditions during the mid-early Hirnantian time. The mid-early Hirnantian ventilated event was concomitant with the global glacial period, likely resulted from the glacio-eustatic sea-level fall and subsequent circulation of cold, dense oxygenated waters     

石笋流体包裹体中的惰性气体及其在重建长江中游古温度变化中的作用

文中讨论了一种评估古气温变化的新方法。我们成功地利用石笋流体包裹体所捕获的Xe/Ar比值,重建了末次冰盛期以来盛行东亚季风的长江中游地区的气候演化。一种表达成ln(CXe/CAr)的对数式被证明与冷暖周期变化具有密切的关系。从研究的石笋中所提出的δ13C与Mg/Ca曲线一般随区域古气温波动而变化,但不能排除其中有另类气候信号的叠加。我们的工作则明确地指出,流体包裹体所记录的Xe/Ar在各种反映温度变化的替代指标中可能是最好的一种。整体而言,ln(CXe/CAr)曲线与那些基本随暖期和冷期振荡的曲线保持一致。将稀有气体曲线与δ13C和Mg/Ca信号整合对比之后,我们在研究区划分出末次冰盛期以来8组暖/冷旋回。整合后的气温变化模式合理地解释了过去20000年里的区域环境变化。