碳酸锰氧化实验和热力学分析

通过对碳酸锰氧化实验的结果分析和讨论，建立了一种适合于锰氧化过程的非平衡热力学模型，并利用此模型对硫酸锰氧化过程作了热力学可行性分析，研究结果表明，碳酸锰氧化过程是矿物组合的变化过程，也是锰自身价态的转为过程，整个过程既存在平衡状态，又存在非平衡状态，是一个不可逆的，多相的复杂反应。     

洋岛,海山碳酸盐岩的沉积特征及其古地理意义

高出水面的洋岛和潜伏水下的海山普遍存在于现代地球表面的各大洋中，地质历史中存在的古洋岛和古海山也逐渐为人们所认识。笔者从地形特征，沉积学特征，成岩作用和生物学特征几个方面对洋岛，海山进行了分析，洋岛，海山通常具有洋岛型火山岩基底和碳酸盐盖层的双层式地层结构，具有低分异度，探讨了古洋岛，古海山的鉴别对于再造古海洋，古地理格局的现实意义。     

催化褪色光度法测定痕量锰的研究及应用

本研究了在ＰＨ＝４．０醋酸－醋酸钠缓冲溶液中，锰催化ＫＩＯ４氧化５－Ｂｒ－ＰＡＤＡＰ的褪色反应及其动力学条件，建立了一个痕量锰的高灵敏度新方法，方法灵敏度为１．３２×１０＾－１０ｇ／ｍｌ，测定范围Ｍｎ＾２＋浓度为０￣１．５μｇ／ｍｌ，用于测定人发，自来水，茶叶中痕量锰，结果满意。     

断块开合说--中国大地构造研究的新思维

对板块说应持分析态度，既充分肯定它的创见，又要看到其不足。张文佑倡导的断块说强调地质演化中的陆洋地壳转化，即拉张造洋、挤压造陆。近年来提出的开合说，继承了板块说、断块说和新地槽-地台说的合理内核。笔者认为，断块-开合大地构造说是中国大地构造研究中有代表性的思潮。本文概括了其基本观点，强调了开合中的多模式、多旋回和非封闭性、不可逆性。     

Geochemistry of the subduction-related magmatic rocks in the Dahong Mountains, northern Hubei Province——Constraint on the existence and subduction of the eastern Mianle oceanic basin

Being a composite collisional orogen between North China and South China blocks, the Qinling orogenic belt is the key to understand the composite combination, prolonged evolutionary history and their continental dynamics. The main suture between north and south Qinling, called Shangdan suture zone (SDSZ), had been studied in detail for about twenty years. Recently, another suture zone, called Mianl黣 suture zone (MLSZ), has been identified in the Qinling Mountains. It is characterized b…     

Mafic Pegmatites Intruding Oceanic Plateau Gabbros and Ultramafic Cumulates from Bolivar, Colombia: Evidence for a 'Wet' Mantle Plume?

The fault-bounded Bolívar Ultramafic Complex (BUC) onthe eastern fringes of the Western Cordillera of Colombia wastectonically accreted onto the western coast of South Americain the late Cretaceous–early Tertiary, along with pillowbasalts of the Caribbean–Colombian Oceanic Plateau (CCOP).The complex consists of a lower sequence of ultramafic cumulates,successively overlain by layered and isotropic gabbroic rocks.The gabbros grade into, and are intruded by, mafic pegmatitesthat consist of large magnesiohornblende and plagioclase crystals.These pegmatites yield a weighted mean ⁴⁰Ar–³⁹Ar step-heatingage of 90·5 ± 0·9 Ma and thus coincidewith the timing of peak CCOP volcanism. The chemistry of theBUC is not consistent with a subduction-related origin. However,the similarity in Sr–Nd–Pb–Hf isotopes betweenthe CCOP and the BUC, in conjunction with their indistinguishableages, suggests that the BUC is an integral part of the plume-derivedCCOP. The parental magmas of the Bolívar complex wereprobably hydrous picrites that underwent 20–30% crystallization.The residual magmas from this fractionation contained     

The development of talus slopes around Lord Howe island and implications for the history of island planation

Lord Howe Island is a small eroded remnant of a Late Miocene shield volcano. A fringing coral reef dissipates wave energy along a portion of the shoreline, but the remainder of the coast is rugged with spectacular high basaltic sea cliffs. This paper investigates the evolution of talus slopes that occur beneath the loftiest cliffs, and places this analysis within the context of a longer history of island planation that has resulted in a wide truncated shelf around the island. During the Last Glacial, when the sea level was lower than at present, talus slopes accumulated around the extent of the island's cliffed coast because material eroded from cliffs by subaerial processes could not be removed by marine processes. The survival of these slopes during the Holocene has depended on a balance achieved between rates of subaerial and marine erosion. This balance is fundamentally influenced by cliff height, as cliffs higher than 200 m are plunging or veneered by talus slopes, whereas lower cliffs have erosional shore platforms. On comparison with published erosion rates from inland basalt scarps it appears that marine processes may account for over 90 per cent of the total cliff retreat that has occurred at Lord Howe Island, yet contemporary coastal morphology attests to the significance of subaerial processes in recent times. It is likely that marine cliffing was very rapid soon after volcanism ceased, but rates of erosion decreased through time as wave energy became increasingly attenuated across a widening planation surface, and as increasing cliff heights yielded greater quantities of talus that provided protection from rapid marine erosion.     

The influence of particle composition on thorium scavenging in the NE Atlantic ocean (POMME experiment)

²³⁰Th, ²³²Th and ²³⁴Th were analyzed in sinking particles collected by moored and drifting sediment traps in the NE Atlantic Ocean (POMME experiment) in order to constrain the phase(s) carrying Th isotopes in the water column. It reveals a contrasted behaviour between ²³⁴Th and ²³⁰Th. ²³⁴Th is correlated to the particulate organic carbon suggesting that it is primarily scavenged by organic compounds in the surface waters. ²³⁰Th_xs is correlated with Mn, Ba and the lithogenic fraction that are enriched in small suspended particles and incorporated in the sinking particulate flux throughout the water column. The lack of correlation between ²³⁰Th_xs and CaCO₃ or biogenic silica (bSi) indicates that CaCO₃ and bSi are not responsible for ²³⁰Th scavenging in the deep waters of this oceanic region. ²³⁰Th is generally correlated with the lithogenic content of the trapped material but this correlation disappears in winter during strong atmospheric dust inputs suggesting that lithogenic matter is not directly responsible for ²³⁰Th scavenging in the deep waters or that sufficient time is required to achieve particle–solution equilibration. MnO₂ could be the prevalent ²³⁰Th_xs-bearing phase. The narrow range of K_{d_MnO2}^Th obtained for very contrasted oceanic environments supports a global control of ²³⁰Th_xs scavenging by MnO₂ and raises the possibility that the ²³⁰Th–²³¹Pa fractionation is controlled by the amount of colloidal MnO₂ in seawater.