Marine Ecology - A Century of Changes

Abstract. The major changes within the concepts of marine ecology are investigated, with the aim to design this new journal's scientific format. Four phases of marine sciences are distinguished: the phase of seafarers, of oceanographic expeditions, of marine stations, and of field research. The changes in the latter two are discussed in detail. The changes are described as occurring along three axes. First, as a movement towards the object; accomplished by fieldwork, scientific diving, remote controlled equipment, and by underwater experimentation. Second, the cooperation between several disciplines that led towards bridging gaps. And lastly, how the discovery of unifying principles in ecology (the development of an ecological theory) led the approach in marine ecology towards increasing complexity.     

Trace element diagenesis in pyrite-rich sediments of the Achterwasser lagoon, SW Baltic Sea

The early diagenesis of trace elements (V, Cr, Co, Cu, Zn, As, Cd, Ba, U) in anoxic sediments of the Achterwasser, a shallow lagoon in the non-tidal Oder estuary in the Baltic Sea, was investigated in the context of pyrite formation. The dissolved major redox parameters show a two-tier distribution with transient signals in the occasionally re-suspended fluid mud layer (FM) and a permanently established diagenetic sequence in the sediment below. Intense microbial respiration leads to rapid depletion of O₂ within the uppermost mm of the FM. The reduction zones of Mn, Fe and sulfate overlap in the FM and in the permanently anoxic sediment section which appears to be a typical feature of estuarine sediments, under low-sulfate conditions. Degrees of pyritization (DOP) range from 50% in the FM to remarkably high values > 90% at 50 cm depth. Pyrite formation at the sediment surface is attributed to the reaction of Fe-monosulfides with intermediate sulfur species via the polysulfide pathway. By contrast, intense pyritization in the permanently anoxic sediment below is attributed to mineral growth via adsorption of aqueous Fe-sulfide complexes onto pyrite crystals which had originally formed in the surface layer.The studied trace elements show differential behavior patterns which are closely coupled to the diagenetic processes described above: (i) Zn, Cu and Cd are liberated from organic matter in the thin oxic layer of the sediment and diffuse both upwards across the sediment/water boundary and downwards to be trapped as monosulfides, (ii) V, Cr, Co and As are released during reductive dissolution of Mn- and Fe-oxyhydroxides, (iii) U removal from pore water occurs concomitantly to Fe reduction in the FM and is attributed to reduction of U(VI) to U(IV), (iv) the Ba distribution is controlled by reductive dissolution of authigenic barite in the sulfate reduction zone coupled with upward diffusion and re-precipitation. The incorporation of trace elements into pyrite is most intense for Co, Mn and As, intermediate for Cu and Cr and little to negligible for U, Zn, Cd, V and Ba. The observed trend is largely in agreement with previous studies and may be explained with differing rates for ligand exchange. Slow and fast ligand exchange and thus precipitation kinetics are also displayed by downcore increasing (Mn, Cr, Co and As) or constantly low (Zn, Cu, Cd) pore water concentrations. The downward increasing degrees of trace metal pyritization (DTMP) for Co, Cu, Zn and As are, in analogy to pyrite growth, assigned to adsorption of sulfide complexes or As oxyanions onto preexisting pyrite minerals.     

大别山地区石榴石橄榄岩的岩石学和地球化学

本文首次对我国石榴石橄榄岩类岩石进行系统的岩石学和地球化学研究。通过对大别山地区两个不同类型岩体中的石榴石橄榄岩的岩石学、岩石化学、矿物化学和稀土元素地球化学研究,表明这类岩石属钙碱性系列超基性岩;与地幔成分相比,富集易熔元素,亏损难熔元素;利用矿物地质温压计估算其形成压力为2×10~9pa,成岩温度为600～700℃具有正铕异常和轻稀土元素富集特征 推测为地壳下部的超基性岩经深成变质而成。     

柴达木盆地昆特依盐湖的地球化学演化与古气候变化

１９９０年用铀系年代学及古地磁对昆特依盐湖沉积物进行年代测定，探讨该湖区地球化学演化与古气候变化关系。结果表明，该区最老的盐层形成于早更新世晚期（大于７３０ｋａ），大量的盐类沉积则始于３００ｋａ左右；盐湖沉积物中元素含量变化主要受古盐度、矿物、类质同象和吸附控制；沉积物水溶Ｆ／Ｃｌ比值与古盐度成反比关系；该湖２０００ｋａ以来的古环境演变：盐层形成于干冷、偏酸性的氧化环境，泥岩层形成于湿暖、偏碱性的     

Relationship between biogeochemical features of biogenic elements and flocculation in the Changjiang Estuary

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Waveform Shaping of Sonar Transducers for Improving the Vertical Resolution in Sub-bottom Sediments Profiling

Vertical resolution is of fundamental importance in sonar exploration and is directly related to the duration of the acoustic pulse generated by the transducer. The shorter the radiated pulse, the higher the vertical resolution. Many sub-bottom profiling sonar systems use piezoelectric transducers because they are reversible and well understood. Piezoelectric projectors are normally resonant transducers, which are intrinsically narrowband. A piezoelectric transducer is usually driven by a tone-burst. However, it is possible to use Fourier techniques to find a pre-compensated electrical driving function so that the transducer radiates a prescribed wider band acoustic waveform. This technique can be applied to synthesize zero-phase cosine-magnitude, Gaussian, and bionic pulses, with a conventional sandwich transducer. Zero-phase cosine-magnitude waveforms provide minimum length pulses (and therefore maximum resolution) within a prescribed frequency band.The aim of this paper is to illustrate the synthesis of wideband acoustic pulses using an underwater piezoelectric projector. The conventional acoustic waveform radiated when a Tonpiltz transducer is transiently excited using a “click” and allows its frequency response function to be measured. This function is used to design the electrical signal which then drives the transducer so that it radiates the shortest pulse compatible with its mechanical response. The significant resolution enhancement of the waveform shaping process is illustrated by its application to a sediment wedge model.     

热带气旋对黄、渤海影响的统计特征分析

本文统计分析了1949—2000年共52年影响黄、渤海的热带气旋时空分布特点及ENS0、西太平洋副热带高压与影响黄、渤海的热带气旋关系。结果表明，西太平洋热带气放以四种主要路径影响黄、渤海，其影响时间、频数及强度均有不同。ENSO和西太平洋副热带高压的强度、位置将影响热带气旋对黄、渤海影响的路径和频数。     

Reanalysis of the Atmospheric Flux of Nutrient Elements to the Southern Yellow Sea and the East China Sea

Based on the recent research results on dry and wet deposition of nutrient elements and sulphate,we estimate the atmospheric flux of nutrient elements and sulphate to the southern Yellow Sea and the East China Sea in each season.The results suggest that the concentrations of nutrient elements and sulphate in aerosol and precipitation show an apparent seasonal cycle with the maximum values in winter and the minimum values in summer.Depositions of nitrate and sulphate are dominated by wet deposition,while the deposition for phosphate is mainly dry deposition.Moreover,compared with the riverine inputs,the atmospheric deposition may be the main source of dissolved inorganic nutrients in the southern Yellow Sea and the East China Sea.     

Rifting to Spreading Process along the Northern Continental Margin of the South China Sea

Understanding the development from syn-rift to spreading in the South China Sea (SCS) is important in elucidating the western Pacific's tectonic evolution because the SCS is a major tectonic constituent of the many marginal seas in the region. This paper describes research examining the transition from rifting to spreading along the northern margin of the SCS, made possible by the amalgamation of newly acquired and existing geophysical data. The northernmost SCS was surveyed as part of a joint Japan-China cooperative project (JCCP) in two phases in 1993 and 1994. The purpose of the investigation was to reveal seismic and magnetic characteristics of the transitional zone between continental crust and the abyssal basin. Compilation of marine gravity and geomagnetic data of the South China Sea clarify structural characteristics of its rifted continental and convergent margins, both past and present. Total and three component magnetic data clearly indicate the magnetic lineations of the oceanic basin and the magnetic characteristics of its varied margins. The analyses of magnetic, gravity and seismic data and other geophysical and geological information from the SCS led up to the following results: (1) N-S direction seafloor spreading started from early Eocene. There were at least four separate evolutional stages. Directions and rates of the spreading are fluctuating and unstable and spreading continued from 32 to 17 Ma. (2) The apparent difference in the present tectonism of the eastern and western parts of Continent Ocean Boundary (COB) implies that in the east of the continental breakup is governed by a strike slip faulting. (3) The seismic high velocity layer in the lower crust seems to be underplated beneath the stretched continental crust. (4) Magnetic anomaly of the continental margin area seems to be rooted in the uppermost sediment and upper part of lower crust based on the tertiary volcanism. (5) Magnetic quiet zone (MQZ) anomaly in the continental margin area coincides with COB. (6) The non-magnetic or very weakly magnetized layer is probably responsible for MQZ. One of the causes of demagnetization of the layer is due to hydrothermal alteration while high temperature mantle materials being underplated. Another explanation is that horizontal sequences of basalt each with flip-flop magnetization polarity cancel out to the resultant magnetic field on the surface. We are currently developing a synthetic database system containing datasets of seismicity, potential field data, crustal and thermal structures, and other geophysical data to facilitate the study of past, contemporary and future changes in the deep sea environment around Japan; i.e. trench, trough, subduction zones, marginal basins and island arcs. Several special characteristics are an object-oriented approach to the collection and multi-faceted studies of global data from a variety of sources.