广西油麻坡钨钼矿床成岩成矿年代学研究及其地质意义

广西博白_岑溪断裂带位于钦杭成矿带南段,既是一条长期活动的地体边界断裂带,也是一条岩浆活动频繁的W_Mo_Sn_Pb_Zn_Sb_Au_Ag多金属成矿带。文章以该带中的广西博白县油麻坡矽卡岩型钨钼矿床为研究对象,在详细的岩性鉴别和划分的基础上,对矿区内花岗岩类进行了单颗粒锆石LA_ICP_MS锆石U_Pb测年,获得深灰色花岗斑岩的等时线年龄为(479.7±3.9)Ma,灰色黑云母花岗闪长岩为(109.7±1.1)Ma,浅灰色细粒白云母花岗岩为(103.3±1.2)Ma。辉钼矿Re_Os测年获得加权平均年龄为(97.4±1.9)Ma。由此可见,油麻坡岩体为一个复式岩体,由早奥陶世(加里东期)的花岗斑岩和早白垩世(燕山晚期)的黑云母花岗闪长岩和细粒白云母花岗岩组成,其中,黑云母花岗闪长岩构成油麻坡岩体的主体。钨钼矿形成于早白垩世晚期(即燕山晚期),与黑云母花岗闪长岩和白云母花岗岩密切相关。这些高精度测年数据的获得,进一步表明博白断裂带是一条长期活动的断裂,其在加里东期已经活动,并伴有岩浆岩的侵位。燕山晚期,该断裂重新复活,并导致大量的岩浆活动和一定强度的W_Mo_Sn_Pb_Zn_Sb_Au_Ag成矿作用,形成由多个大_中型矿床组成的多金属成矿带。博白_岑溪成矿带属于华南100~80 Ma大规模成矿的一部分,成矿背景与华南地区白垩纪的地壳伸展、钦杭成矿带的再次裂陷有关。     

赣北大湖塘地区昆山W-Mo-Cu矿床侵入岩锆石U-Pb、辉钼矿Re-Os年代学及地质意义

昆山W-Mo-Cu矿床地处赣北九岭矿集区南部,距大湖塘超大型钨矿床狮尾洞矿区仅3 km。矿床目前处于详查阶段,已探明钨达中型规模,同时伴生中型钼矿及小型铜矿,具有良好的找矿潜力。昆山矿床矿化样式较为单一,W-Mo-Cu矿体以石英脉形式产出,主要赋存在燕山期侵入岩顶部与新元古界双桥山群浅变质岩的外接触带,具有"上钨中钼下铜"的特点,明显区别于大湖塘矿床矿体主要产在燕山期侵入岩与晋宁期黑云母花岗闪长岩的内外接触带,具细脉浸染型白钨矿、热液爆破角砾岩型钨铜矿及石英脉型黑钨矿"三位一体"的矿化特征。本文在详细的野外地质调查基础上,对昆山W-Mo-Cu矿床的成岩成矿时代进行了详细研究,并探讨了其地质意义。利用LA-ICP-MS锆石U-Pb法获得矿区内呈岩株状产出的似斑状花岗岩的年龄为151.7±1.3 Ma,晚期花岗斑岩脉的年龄为136.6±2.5 Ma;利用辉钼矿Re-Os法,获得辉钼矿Re-Os等时线年龄和加权平均年龄分别为151.0±1.3 Ma和150.0±1.0 Ma,厘定矿床成矿时代为晚侏罗世,且与似斑状花岗岩有关。结合前人所得高精度成岩成矿年龄数据,认为赣北地区燕山期成岩成矿具多期性,可分为160~150 Ma(塔前、朱溪钨多金属矿床)、140 Ma(大湖塘钨多金属矿床)和125 Ma(香炉山钨矿),主要集中于150~140 Ma。晚侏罗世,华南地区全面进入岩石圈"伸展-减薄"的地球动力学背景,赣北地区燕山期成岩成矿可能与这一构造背景有关。昆山矿床具"上钨中钼下铜"的分带模式,其成因值得进一步研究。     

新疆东准噶尔拉伊克勒克斑岩铜(钼)矿床成岩成矿年龄、地球化学特征及其意义

拉伊克勒克矿床是在第四系覆盖区新发现的隐伏斑岩铜(钼)矿床。采用LA-ICP-MS技术,对赋矿岩体英云闪长岩中的锆石和矿石中的辉钼矿分别进行锆石U-Pb同位素、Re-Os同位素和锆石Hf同位素测定及相应的研究。测得锆石U-Pb年龄为421.8±2.5Ma,辉钼矿Re-Os模式年龄为409.1±2.6Ma,表明拉伊克勒克斑岩铜(钼)矿床形成于晚志留世—早泥盆世,与琼河坝地区主要斑岩矿床大规模成矿时间一致。英云闪长岩属过铝质-钙碱性系列花岗岩类,岩体具有较高的铝钙含量,K_2O/Na_2O值普遍偏低,介于0.16~0.29之间;稀土元素配分曲线呈现右倾特征,稀土元素总量较低,轻稀土元素相对富集,负Eu异常不明显。在微量元素原始地幔标准化蛛网图上,高场强元素Th、Nb、Ta、P、Ti等相对亏损,大离子亲石元素Rb、Ba、U、K、Sr等相对富集。同时岩体具有高的正ε_(Hf)(t)值(10.98~15.01)和年轻的模式年龄(451~708Ma),暗示英云闪长岩体是大陆边缘弧环境下大洋板片熔融的产物,对进一步明确琼河坝地区斑岩型矿床的成矿环境和找矿方向具有重要意义。     

内蒙古丰镇市泉子沟斑岩钼矿床成岩成矿年代学及其地质意义

泉子沟斑岩钼矿床位于内蒙古丰镇市,地处华北克拉通北缘内蒙古台隆凉城断隆内。矿区出露一套燕山期花岗质杂岩体——红娘山杂岩体,主要由中粗粒花岗岩、似斑状花岗岩和石英斑岩组成,钼矿体主要赋存于似斑状花岗岩中。文章在详细的野外地质调查基础上,对泉子沟矿床的成岩成矿时代进行了详细研究,并探讨了地质意义。5件辉钼矿样品的Re-Os模式年龄介于(158.8±2.2)Ma~(161.5±2.2)Ma之间,其加权平均值为(159.8±1.0)Ma(MSWD=0.92),等时线年龄为(161.7±3.1)Ma(MSWD=1.40)。红娘山杂岩体LA-ICP-MS锆石U-Pb年龄分别为:中粗粒花岗岩结晶年龄为(173±1)Ma(MSWD=0.88),似斑状花岗岩侵位年龄为(162±1)Ma(MSWD=0.40),石英斑岩结晶年龄为(160±2)Ma(MSWD=1.90)。辉钼矿Re-Os和锆石U-Pb定年结果表明,泉子沟钼矿床形成于晚侏罗世早期,成矿与似斑状花岗岩关系密切。泉子沟钼矿床的辉钼矿w(Re)介于16.49×10~(-6)~32.87×10~(-6),暗示成矿物质主要来自下地壳。     

Os水吸收液ICP-MS测量信号强度衰减原因研究

蒸馏法能从样品中有效分离出OsO_4,吸收液直接用于ICP-MS测定,是辉钼矿Re-Os定年的关键技术环节。但实验发现,长时间放置的吸收液中Os信号强度显著降低。根据OsO_4化学性质推测原因在于一是挥发使吸收液Os含量减少,二是还原使+8价Os变成低价态,气态比例降低,若雾化效率不变,进入质谱仪的Os减少,两者都会导致信号降低,但具体影响情况不明,需深入研究。本文利用辉钼矿标准物质制备不同放置时间、酸度和温度的吸收液,对比上述条件对ICP-MS信号强度的影响。实验时将残余吸收液与稀释剂、氧化剂封入Carius管加热蒸馏,测定Os含量。结果表明:吸收液放置时间越长,酸度越低,温度越高,信号降幅越大,幅度达到3.2%~68.6%。室温下放置相同时间,低酸度吸收液的Os保存率高于高酸度吸收液,但Os信号强度低于后者,证明了挥发和还原共同导致信号衰减,且还原是主导原因。本文提出,冷冻(-18℃)可抑制OsO_4挥发,提高酸度(约3.5 mol/L)可减弱OsO_4还原,两者结合抑制信号衰减,提高了蒸馏法的灵活性和适用性。     

天山-兴蒙造山带主要钼矿床Re-Os定年和地质意义

天山-兴蒙钼矿带是中亚成矿域的重要组成部分,该成矿带主要呈近东西向分布;本文通过对天山-兴蒙钼矿带4个典型矿床Re-Os同位素精确定年,结合前人区域动力学背景的研究,揭示天山-兴蒙造山带钼矿床的成矿作用主要与岩浆侵入形成的花岗岩热液作用有关,并识别出兴蒙造山带3期岩浆活动、钼成矿作用和构造热事件;Re-Os定年结果揭示出晚古生代铜-钼矿床与俯冲-增生作用有关,三叠纪钼的成矿形成于西伯利亚板块与塔里木-华北克拉通碰撞背景下,而侏罗纪-早白垩世的钼成矿作用与古太平洋板块西向俯冲作用有关。     

Two Phases of Mineralization in the Dabaoshan Polymetallic Deposit,Guangdong Province: Constraints from Re-Os Geochronology of Black Carbonaceous Mudstone and MolybdeniteEI北大核心CSCD

The Dabaoshan polymetallic deposit is a polygenetic composite ore deposit located at south of the Qinhang (Qinzhou-Hangzhou) Metallogenic Belt, which is composed mainly of SEDEX type Cu-Pb-Zn and porphyry-skarn type W-Mo orebodies. Systematic field study shows that the W-Mo mineralization exhibits as quartz-vein type and skarn type orebodies around the granodioritic porphyry, or superimposes on the SEDEX type Cu-Pb-Zn orebody, while the Cu-Pb-Zn mineralization occurs mainly in the Qiziqiao Formation as stratiform-substratiform type and breccia type orebodies with typical SEDEX-type characteristics. Re-Os dating of five molybdenite separates from porphyry-skarn type W-Mo orebodies yielded isochron ages of 163.6±1.0 Ma (MSWD=0.58), which represents the age of W-Mo mineralization. Re-Os dating of seven black carbonaceous mudstone samples from a Cu-Pb-Zn orebody yielded isochron age of 387.6±9.9 Ma (MSWD=56), which is interpreted to be the age of SEDEX-type Cu-Pb-Zn mineralization. These ages indicate that there are at least two stages of ore mineralization in the Dabaoshan polymetallic deposit. The W-Mo mineralization is related to the Yanshanian intermediated-acidic intrusions, while the stratiform-substratiform SEDEX-type Cu-Pb-Zn mineralization is associated with the Hercynian seafloor hydrothermal activities. © 2018, Science Press. All right reserved.     

河北涞源大湾锌钼矿床锆石U-Pb和辉钼矿Re-Os年龄及其地质意义

大湾斑岩-矽卡岩型锌钼矿床地处太行山北段成矿带中,是该段重要的金属矿床之一.五台群板峪口组和长城系高于庄组为主要赋矿围岩,锌钼矿体主要赋存在流纹斑岩体内及斑岩与围岩接触部位.文章对大湾矿床内2件赋矿流纹斑岩进行LA-ICP-MS锆石U-Pb年代测定,获得206Pb/238U年龄加权平均值分别为(137.1±0.9)Ma(MSWD=0.56,n=24)和(136.8±1.2)Ma(MSWD=0.40,n=22);对矿区4件辉钼矿样品进行Re-Os定年,得到加权平均年龄为(136.5±1.0)Ma,等时线年龄为(136.1±2.3)Ma,在误差范围内成岩成矿时代一致,显示大湾锌钼矿床形成于早白垩世.大湾矿床中辉钼矿的w(Re)为5.816～16.484μg/g,反映了矿床成矿物质来源具有壳幔混合特征.区内流纹斑岩和蚀变体系为进一步找矿勘查的有利标志.     

U-Pb Zircon and Re-Os Molybdenite Geochronology of theW-Mo Mineralized Region of South Qinling,China, andtheir Tectonic Implications

A W-Mo mineralized region is located along the northern margin of the South Qinling tectonic belt of China. WMo mineralization occurs mainly in Cambrian–Ordovician clastic and carbonate rocks, and the ore bodies are structurally controlled by NW–SE-and NNE–SSW-striking faults. Evidence for magmatism in the area is widespread and is dominated by intermediate–felsic intrusives or apophyses, such as the Dongjiangkou, Yanzhiba, Lanbandeng, and Sihaiping granitic bodies. Quartz-vein-type mineralization and fault-controlled skarn-type mineralization dominate the ore systems, with additional enrichment in residual deposits. At present, there are few or insufficient studies on(1) the age of mineralization,(2) the relationship between intermediate–felsic granite and W-Mo mineralization,(3) the source of ore-forming materials,and(4) the metallogenic and tectonic setting of the mineralized area. In this paper, we present geochronology results for numerous intrusive granitic bodies in the South Qinling tectonic belt. U-Pb zircon geochronology of the Lanbandeng monzogranite and Wangjiaping biotite monzogranite yields ages of 222.7 ± 2.3 and 201.9 ± 1.8 Ma, respectively. In contrast to the Late Triassic age of the Lanbandeng monzogranite, the age of the newly discovered Wangjiaping biotite monzogranite places it at the Triassic–Jurassic boundary. Re-Os molybdenite geochronology on the Qipangou W-Mo deposit yielded a model age of 199.7 ± 3.9 Ma, indicating the deposit formed in the early Yanshanian period of the Early Jurassic. Granitoid intrusions in the mineralized area are characterized by composite granite bodies that crystallized at ca.240–190 Ma. While there were multiple stages of intrusion, most occurred at 210–220 Ma, with waning magmatic activity at 200–190 Ma. The Re-Os age of molybdenite in the region is ca. 200–190 Ma, which may represent a newly discovered period of W-Mo metallogenesis that occurred during the final stages of magmatism. The heat associated with this magmatism drove ore formation and might have provided additional ore-forming components for metallogenesis(represented by the Wangjiaping biotite monzogranite). Ore materials in the mineralized area were derived from mixed crustal and mantle sources. Enrichment of the region occurred during intracontinental orogenesis in the late Indosinian–Yanshanian, subsequent to the main Indosinian collision. At this time, the tectonic environment was dominated by extension and strike-slip motion.     

辉钼矿铼－锇同位素年代学研究简介

辉钼矿铼－锇同位素年代学测定依据该矿物中含有由１８７Ｒｅ通过β－衰变而形成的放射性成因１８７Ｏｓ。这一同位素年代学方法由于８０年代以来微量铼、锇同位素质谱技术的成熟而逐渐应用于研究中，获得了具有地质意义的年龄值。对辉钼矿年龄测定的成功与否，选择适当的样品至关重要。一般而言，红外透光性（ｉｎｆｒａｒｅｄｔｒａｎｓｐａｒｅｎｃｙ）大于３．５的辉钼矿样品适合于铼－锇同位素年代学研究，其辉钼矿的铼－锇同位素年龄值十分接近于围岩的钾－氩或其它常规同位素方法的年龄值。