Variscan ore formation and metamorphism at the Felbertal scheelite deposit (Austria): constraining tungsten mineralisation from Re–Os dating of molybdenite

The Felbertal scheelite deposit in the Eastern Alps has been regarded as the type locality for stratabound scheelite deposits. It is hosted by a Cambro-Ordovician metavolcanic arc sequence with minor Variscan granitoids (∼ 340 Ma) in the central Tauern Window. Re–Os model ages for molybdenite from the Felbertal tungsten deposit range between ∼ 358 and ∼ 336 Ma and record several pulses of magmatic-hydrothermal-metamorphic molybdenite formation. Molybdenite ages from the K2 orebody, a scheelite-rich quartz mylonite in the Western ore field, indicate that both mineralisation and mylonite are Variscan in age and suggest that the shear zone was active for ∼ 20 million years. Early stage tungsten mineralisation (Scheelite 1) in quartzitic ores in the Eastern ore field, which is free of molybdenite, yielded very low to near blank levels of Re and Os and thus could not be dated. However, molybdenite from scheelite–quartz stringers, previously interpreted as a feeder stockwork to quartzitic scheelite ore of presumed Cambrian age, yielded Variscan Re–Os ages of ∼ 342 and ∼ 337 Ma. Dating of molybdenite contained in scheelite ores thus far provides no indication of a Cambrian component to the tungsten mineralisation. Our data are consistent with a model of either granite intrusion-related ore formation and coeval metamorphic overprint during the Early Carboniferous or, alternatively, molybdenite formation may be exclusively attributed to Variscan metamorphism (see Stein 2006).     

Paleoproterozoic accretion in the Northeast Siberian craton: Isotopic dating of the Anabar collision system

Geochronological database considered in the work and characterizing the Anabar collision system in the Northeast Siberian craton includes coordinated results of Sm-Nd and Rb-Sr dating of samples from crustal xenoliths in kimberlites, deep drill holes, and bedrock outcrops. As is inferred, collision developed in three stages dated at 2200–2100, 1940–1760, and 1710–1630 Ma. The age of 2000–1960 Ma is established for substratum of mafic rocks, which probably originated during the lower crust interaction with asthenosphere due to the local collapse of the collision prism. Comparison of Sm-Nd and Rb-Sr isochron dates shows that the system cooling from ≈700 to ≈300°C lasted approximately 300 m.y. with a substantial lag relative to collision metamorphism and granite formation. It is assumed that accretion of the Siberian craton resulted in formation of a giant collision mountainous structure of the Himalayan type that was eroded by 1.65 Ga ago, when accumulation of gently dipping Meso-to Neoproterozoic (Riphean) platform cover commenced.     

青藏高原唐古拉山口第四纪冰碛层划分及其地质环境意义

在对唐古拉山口现代冰川和古冰川考察研究的基础上，结合定位观测资料和TL、^10B-^26Al-^21Ne及^14C测年数据，对区内第四纪冰川遗迹进行了深入讨论，划分出二次冰期(即中更新世晚期的倒数第二次冰期、晚更新世中一晚期的末次冰期)和二次全新世冰进(即新冰期和小冰期)。提出在早更新世时，由于山体未达到当时冰川发育的雪线高度，所以未发育冰川。但在唐古拉山口地区，截止目前还未找到中更新世早期的倒数第三次冰期的冰川遗迹，由于高原隆升的滞后性和冰川发育的延滞效应及“亚洲干极”的耦合，推测仍只发育局部冰川作用。进一步研究表明，古今雪线由高原边缘向腹地升高，唐古拉山地区高出边缘1500m左右，生动表现了“亚洲干极”的作用；广泛分布的湖群说明羌塘地区是一个大江大河尚未伸入的内流地区，意味着青藏高原是个年青的高原。由于青藏高原的隆升，对高原腹地引起的干旱化过程和水分严重不足，使唐古拉山地区的冰川自倒数第二次冰期以来，冰川规模一次比一次明显地减小。     

内蒙古中部苏尼特左旗富钾花岗岩锆石SHRIMP U-Pb年龄

精确的锆石SHRIMP U-Pb年龄测定表明,内蒙古苏尼特左旗富钾花岗岩的结晶年龄分别为423Ma±8Ma和424Ma±10Ma.综合区域资料,认为该年龄代表了内蒙古中部志留纪期间发生弧-陆碰撞事件的时限.     

河南焦作云台山早前寒武纪变质基底锆石SHRIMP U-Pb年龄

应用离子探针技术,对华北太行山南缘钾长石化长英质副片麻岩和钾长石化片麻状奥长花岗岩进行了锆石年龄测定。钾长石化长英质副片麻岩的变质原岩为泥砂质碎屑沉积岩,其形成时代很可能为新太古代。碎屑锆石普遍存在强烈铅丢失,靠近上交点的5个数据点207Pb/206Pb加权平均年龄为3399Ma±8Ma,代表了物源区组成的时代。钾长石化片麻状奥长花岗岩2组锆石207Pb/206Pb加权平均年龄分别为2511Ma±13Ma(岩体形成时代)和2735Ma±16Ma(残余锆石年龄),分别代表该岩体形成时代和残余锆石年龄。新的资料支持了华北克拉通中部造山带太古宙地质体与其东部陆块存在亲缘关系的认识。     

松潘-甘孜地体内花岗岩锆石SHRIMP U-Pb定年及其构造意义

松潘-甘孜地体总体上是一个三角状褶皱带,其北侧、东南侧及东侧分别与东昆仑-西秦岭构造带、金沙江构造带及龙门山构造带相邻。地体内几乎全部被三叠系浊积岩所覆盖,其中侵位了很多花岗岩体。显然,这些花岗岩的岩浆特征、来源与侵位时代,对研究松潘-甘孜地体基底性质、构造演化等问题具有重要意义。本文报道利用SHRIMP定年技术对一些花岗岩岩体锆石所进行的精确测年数据。测试结果表明:(1)松潘-甘孜地体内的花岗岩体主要形成于晚三叠世,但岩浆活动可延续到早侏罗世晚期;(2)早期花岗岩浆活动与三叠纪系褶皱变形大致同期,指示这一时期的花岗岩浆的形成可能与三叠系下部大型拆离滑脱构造相关;(3)花岗岩结晶锆石普遍具有浑圆状或不规则状较老的继承锆石核,这些核部继承锆石可能代表花岗岩浆在上升过程中从不同地层内捕获的碎屑锆石,或者是下地壳岩石深熔残留锆石。根据SHRING U-Pb定年,这些继承锆石的年龄分别为二叠纪、加里东期、晚元古代和早元古代。元古代碎屑锆石的存在也可能指示松潘-甘孜地体具前寒武系基底。     

同位素地质学定年方法评述

详细分析了当前同纱年代学的常用定年方法，如K-Ar法，U-Pb法，Rb-Sr法和Sm-Nd法等的适用性和局限性。讨论了地质事件定年过程中存在的一些问题，提出了准确定年的注意事项。     

铅锌矿床Rb-Sr定年研究综

本文在总结Rb-Sr等时线定年的基本前提和矿床Rb-Sr等时线定年存在的问题的基础上,综述了铅锌矿床流体包裹体和闪锌矿Rb-Sr等时线定年的研究进展,同时对该定年方法存在的问题进行了简要评述。综合分析表明,Rb-Sr等时线定年(尤其是闪锌矿Rb-Sr等时线定年)为铅锌矿床较理想的直接定年方法,但该定年方法还存在许多理论和技术问题,有待深入研究;铅锌矿床Rb-Sr等时线定年应以深入细致的地质、地球化学研究为基础,定年过程中必须严慎对待样品采集、样品挑选、流体包裹体溶液提取和质谱分析等各个环节。     

沐川太平砂岩型铼钼（饿）矿点的地质特征和矿化时代

四川沐川县民主-太平-带含钼砂岩为一新矿化类型——沉积砂岩型铼钼（锇）矿点。X-射线粉晶衍射分析结果表明其中微-细晶鳞片状含钼矿物为晶质辉钼矿；高精度质谱分析发现辉钼矿中分散元素Re和铂族元素Os含量很高，具有重要的综合利用价值；高精度Re-Os同位素测年证明辉钼矿形成年龄与含矿的中生代红物学和矿床学均具有重要的理论意义和应用价值。     

Rate of strike-slip motion on the Amanos Fault (Karasu Valley, southern Turkey) constrained by K–Ar dating and geochemical analysis of Quaternary basalts

The left-lateral Amanos Fault follows a 200-km-long and up to 2-km-high escarpment that bounds the eastern margin of the Amanos mountain range and the western margin of the Karasu Valley in southern Turkey, just east of the northeastern corner of the Mediterranean Sea. Regional kinematic models have reached diverse conclusions as to the role of this fault in accommodating relative motion between either the African and Arabian, Turkish and African, or Turkish and Arabian plates. Local studies have tried to estimate its slip rate by K–Ar dating Quaternary basalts that erupted within the Amanos Mountains, flowed across it into the Karasu Valley, and have since become offset. However, these studies have yielded a wide range of results, ranging from 0.3 to 15 mm a⁻¹, which do not allow the overall role and significance of this fault in accommodating crustal deformation to be determined. We have used the Cassignol K–Ar method to date nine Quaternary basalt samples from the vicinity of the southern part of the Amanos Fault. These basalts exhibit a diverse chemistry, which we interpret as a consequence varying degrees of partial melting of their source combined with variable crustal contamination. This dating allows us to constrain the Quaternary slip rate on the Amanos fault to 1.0 to 1.6 mm a⁻¹. The dramatic discrepancies between past estimates of this slip rate are partly due to technical difficulties in K–Ar dating of young basalts by isotope dilution. In addition, previous studies at the key locality of Hacılar have unwittingly dated different, chemically distinct, flow units of different ages that are juxtaposed. This low slip rate indicates that, at present, the Amanos Fault takes up a small proportion of the relative motion between the African and Arabian plates, which is transferred southward to the Dead Sea Fault Zone. It also provides strong evidence against the long-standing view that its slip continues offshore to the southwest along a hypothetical left-lateral fault zone located south of Cyprus.