Quantum yield for the photochemical production of dissolved inorganic carbon in seawater

The direct photooxidation of coloured dissolved organic matter (CDOM) to dissolved inorganic carbon (DIC) may provide a significant sink for organic carbon in the ocean. To calculate the rate of this reaction on a global scale, it is essential to know its quantum yield, or photochemical efficiency. We have determined quantum yield spectra, φ(λ), (moles DIC/mole photons absorbed) for 14 samples of seawater from environments ranging from a turbid, eutrophic bay to the Gulf Stream. The spectra vary among locations, but can be represented quite well by three pooled spectra for zones defined by location and salinity: inshore φ(λ)=e^{−(6.66+0.0285(λ−290))}; coastal φ(λ)=e^{−(6.36+0.0140(λ−290))}; and open ocean φ(λ)=e^{−(5.53+0.00914(λ−290))}. Production efficiency increases offshore, which suggests that the most highly absorbing and quickly faded terrestrial chromophores are not those directly responsible for DIC photoproduction.     

无公害刺参稳产健康养殖新技术

本文针对目前刺参养殖中存在的问题,简单明了叙述刺参无公害健康养殖一系列新技术和新方法,对推动海参养殖业持续、稳定、健康发展,起到积极作用和效果。     

利用臭氧氧化实现复合生物反应器污泥减量

采用复合生物反应器,对应用臭氧氧化实现污泥减量进行了研究。2个相同的复合生物反应器平行运行,1个作为对照系统,1个作为氧化系统。反应器内装有半软性填料,投加量为10%。曝气池中悬浮污泥浓度为1 500 mg/L左右,生物膜浓度为2 000 mg/L左右。试验结果表明,随着臭氧氧化污泥比例的增加,污泥表观产率系数也随之降低,当臭氧投量为0.05 g O3/gSS,每天氧化的污泥分别为反应器内污泥的10%,20%,30%时,污泥表观产率系数分别减少28.2%,44.9%,75.8%。虽然随着污泥氧化比例的增大,氧化系统出水CODcr略有增加,但氧化系统仍能保持其生物处理能力,CODcr去除率在92%以上;2个系统之间氨氮的去除率相差不大,氧化系统的硝化能力基本没有受到臭氧氧化的影响。     

未来不同气候变化情景下我国玉米产量的初步预测

玉米是我国重要的粮食和饲料作物,研究气候变化对我国玉米产量的影响有重要意义。采用区域气候模式与CERES Maize模型相结合的方法,模拟了基准气候（BS,1961—1990年）和A2、B2两种温室气体排放方案下2011—2100年我国雨养和灌溉玉米产量,初步预测了未来不同气候情景下玉米产量的变化状况。结果表明,如果保持现有的玉米生产状况,气候变化将导致我国玉米主产区的玉米单产普遍降低,总产下降,给玉米生产带来一定经济损失。A2气候变化情景对我国玉米产量的负面影响要大于B2情景。CO2肥效作用可以在一定程度上缓解这种负面影响,其缓解作用对雨养玉米更明显。未来全国玉米主产区的雨养和灌溉玉米的稳产风险及低产出现的概率将会增大,总产的年际波动更剧烈。由于目前研究结果是未考虑农业生产的适应措施而得出的,可能会高估气候变化的负面影响。     

Simulation experiment on hydrocarbon generating potential of various source rocks on the northern margin of the Qaidam Basin,Qinghai, China

The northern margin of the Qaidam Basin is one of the main oil-gas exploration areas in western China, where source rocks are composed mostly of Middle and Lower Jurassic dark mud shale, carbargillite and coal. A large number of subsurface and outcrop samples differing in lithology with different types of organic matter were selected for resource evaluation, research and calculation. And among them, 13 samples were used for simulation experiment on hydrocarbon generating potential of various source rocks. At first, two kinds of heating modes were compared through simulation experiment, including single temperature-step heating and continual heating. Perhaps, the process of hydrocarbon generation and expulsion occurred naturally between a close system and an open system. In addition, the first heating mode was convenient, and all its reaction products were involved in the whole thermal evolution, and the final simulation experimental results were basically in consistency with the natural evolution trend Therefore, the first heating mode was adopted and the hydrocarbon yield of every sample was worked out. According to the type and lithology of organic matter and the hydrocarbon yield of samples for simulation experiment, hydrocarbon generation and expulsion mode with three kinds of lithology and five types of source rock has been established to provide the basis for hydrocarbon generation evaluation, research and resource calculation.     

Regional yield estimation for winter wheat with MODIS-NDVI data in Shandong, China

The significance of crop yield estimation is well known in agricultural management and policy development at regional and national levels. The primary objective of this study was to test the suitability of the method, depending on predicted crop production, to estimate crop yield with a MODIS-NDVI-based model on a regional scale. In this paper, MODIS-NDVI data, with a 250 m resolution, was used to estimate the winter wheat (Triticum aestivum L.) yield in one of the main winter-wheat-growing regions. Our study region is located in Jining, Shandong Province. In order to improve the quality of remote sensing data and the accuracy of yield prediction, especially to eliminate the cloud-contaminated data and abnormal data in the MODIS-NDVI series, the Savitzky–Golay filter was applied to smooth the 10-day NDVI data. The spatial accumulation of NDVI at the county level was used to test its relationship with winter wheat production in the study area. A linear regressive relationship between the spatial accumulation of NDVI and the production of winter wheat was established using a stepwise regression method. The average yield was derived from predicted production divided by the growing acreage of winter wheat on a county level. Finally, the results were validated by the ground survey data, and the errors were compared with the errors of agro-climate models. The results showed that the relative errors of the predicted yield using MODIS-NDVI are between −4.62% and 5.40% and that whole RMSE was 214.16 kg ha⁻¹ lower than the RMSE (233.35 kg ha⁻¹) of agro-climate models in this study region. A good predicted yield data of winter wheat could be got about 40 days ahead of harvest time, i.e. at the booting-heading stage of winter wheat. The method suggested in this paper was good for predicting regional winter wheat production and yield estimation.     

新密市白石沟井田二1煤层充水因素分析

白石沟井田是近年来探明的大巾型井田,位于五指岭-白寨背斜东端之南翼,新密-新郑复向斜之北翼．岗亚腰断层和梁山断层之间的地垒构造上,其基本构造形态为-向东倾伏的宽缓背斜。二叠系下统山西组二1煤为主要开采煤层,探明二1煤资源量7206×10^7t。分析了井田含水岩组及其富水性,对断层带及其富水特征进行了研究,从矿床（二1煤层）充水的水源、通道、机理三个方面分析了矿床充水因素,指出二1煤层的主要充水水源为该煤层底板的石炭系岩溶裂隙-承压水,充水通道为断层带和灰岩的岩溶裂隙发育带,充水机理为矿压及高水头压力冲破煤层底板阻水层阻力,形成底鼓,迅速突水。认为该井田水文地质勘查类型为三类二型,提出了排除与隔离地表水体,预留防水安全煤柱,灌浆辅助采掘的井田突水防范措施。     

Determination of specific yield using a water balance approach – case study of Torla Odha watershed in the Deccan Trap province, Maharastra State, India

Specific yield is an essential parameter for any groundwater management plan. Volumetric analysis in the domain of groundwater budgeting for the non-monsoon months has been undertaken for a typical watershed of the Deccan basalt province. The Torla Odha watershed covers an area of over 22 km² on a third-order tributary of the westerly flowing Bhima River. The watershed receives a normal annual rainfall of 643 mm. The entire water demand is supplied by dug wells, which penetrate a shallow aquifer. The specific yield was estimated by comparing the monthly net volume of water removed from the aquifer, with the volume of aquifer de-saturated, based on monthly water level data. The estimated specific yield ranges from 0.0019 in May to 0.0173 in November with an average value of 0.0093. A correlation of the groundwater levels with the detailed geology suggests that the higher specific yield value (0.017) corresponds to dewatering of the weathered zone within the shallow aquifer. The specific yield of the massive basalt immediately below the weathered zone varies from 0.0089 to 0.0103. The underlying vesicular basalt, which is dissected by sheet joints, has a relatively higher specific yield (0.0121). The massive basalt, which forms the base of the shallow aquifer system, has a lower specific yield from 0.0019 to 0.0022.

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Résumé Le débit spécifique est un paramètre essentiel pour tout plan de gestion des eaux souterraines. Les analyses volumétriques, dans le cadre des bilans hydriques des eaux en dehors des mois de mousson, ont été entreprises pour un bassin-versant typique de la province basaltique du Deccan. Le bassin-versant du Torla Odha couvre une superficie de 22 km², et alimente l’affluent du troisième ordre de la rivière Bhima, qui coule vers l’Ouest. La pluviométrie annuelle atteint 643 mm. Toute la demande en eau es assurée par des puits foncés pénétrant dans l’aquifère phréatique. Le débit spécifique a été estimé en comparant le volume net mensuel d’eau captée dans l’aquifère, avec le volume de l’aquifère dé-saturé, basé sur les données des niveaux piézométriques mensuels. Le débit spécifique estimé s’étend entre 0,0019 en Mai et 0.173 en Novembre; la moyenne se situe à 0,0093. Une corrélation entre les niveaux des eaux souterraines et la géologie, suggère que les débits spécifiques les plus importants (0,017) correspondent aux zones altérées de l’aquifère phréatique. Le débit spécifique du massif basaltique, immédiatement sous la zone altérée, varie entre 0,0089 et 0,0103. Le basalte vésiculaire, situé juste en dessous et traversé par des diaclases parallèles, possède un débit spécifique sensiblement plus élevé (0,0121). Le basalte massif, qui forme la base de l’aquifère phréatique, possède un débit spécifique moins important, compris entre 0,0019 et 0,0022.

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Resumen El rendimiento específico es un parámetro esencial para cualquier plan de manejo de aguas subterráneas. Se ha llevado a cabo el análisis volumétrico, en el entorno de balance de aguas subterráneas, para los meses sin monzón de una cuenca típica de la provincia de basaltos Deccan. La cuenca Rorla Odha cubre un área de 22 km² en un tributario de tercer orden del Río Bhima que fluye al oeste. La cuenca capta una lluvia anual normal de 643 mm. La totalidad de la demanda de agua es abastecida por pozos manuales que penetran un acuífero somero. Se estimó el rendimiento específico al comparar el volumen neto mensual de agua removido del acuífero con el volumen de agua de-saturado estimado a partir de datos de niveles de agua mensuales. Los valores estimados de rendimiento específico varían de 0.0019 en mayo a 0.0173 en noviembre con un valor promedio de 0.0093. La correlación de niveles de agua subterránea con la geología de detalle sugieren que el valor más alto (0.017) de rendimiento específico corresponden con el desaguado de la zona de intemperismo dentro del acuífero somero. El rendimiento específico del basalto masivo que se encuentra inmediatamente debajo de la zona de intemperismo varía de 0.0089 a 0.0103. El basalto vesicular subyacente, el cual está disectado por fracturas laminares, tiene un rendimiento específico relativamente más alto (0.0121). El basalto masivo, que forma la base del sistema de acuífero somero, tiene un rendimiento específico más bajo el cual varía de 0.0019 a 0.0022. Palabras clave: basalto Deccan. India. Rendimiento específico. Recarga de agua subterránea. Balance hídrico.

     

宁夏自治区生态农业地质研究及其前景

论述了宁夏回族自治区土壤元素含量和农作物优质高产与土壤环境中化学元素N、P、K、S、Fe、Mn、Cu、Zn、B、Mo、V、Sr、Ti、Mg、La、Ce、Pr、Nd、Sm、Eu、Y、Gd、Tb、Dy、Ho、Er、Tm、Yb、Lu、Ca、Co、Ni、F、Tl、Si、Na、Cr、Pb、Cd、Hg、Se、Ba、Te、Ta有密切的关系.提出了生态农业地质研究的目的、内容、方法、管理及其前景。     

原油在储层介质中的加水裂解生气模拟实验

采用高温高压热模拟实验方法,开展了原油在砂岩和火成岩储层介质中的加水裂解生气模拟实验研究.结果表明,原油开始大量裂解的温度是400℃,随模拟温度增加,甲烷相对含量增大,乙烷以上重烃气尤其是丙烷相对含量减小.其中砂岩的油水混合物裂解生气主要发生在450～500℃之间,生气窗范围小,对应的烃气产率高,火成岩的油水混合物裂解生气主要发生在450～600℃之间,生气窗范围大,对应的烃气产率小.模拟烃气的组分碳同位素分馏显著,随模拟温度增加呈变重趋势.在裂解生气过程中,水解加氢和催化作用对烃气的组成、产率和碳同位素分布有重要影响。