全新世初期气候的数值模拟研究

本文尝试用一个完全耦合的大气-海洋-植被模式(Atmosphere-Ocean-Vegetation General Circulation Model, AOVGCM)模拟全新世初期的地球气候.模拟结果表明，耦合模式成功地再现了全新世初期复杂气候条件下的基本特征，为研究这一时期的气候状况提供了重要的模型支持.就全球平均而言，11ka BP冬季地表气温比现代约低1.6 K,夏季比现代低约0.3 K；大气温度从低层到高层有不同的表现，高层反映了太阳辐射的重要作用，而低层气候对下垫面（如冰川、植被和海洋等）的影响比较敏感.从区域分布来看，11 ka BP冬季大部地区比现在偏干，但热带太平洋和南半球少部地区降水偏多；夏季大部地区比现在偏湿，亚洲和非洲季风偏强，主要的季风区降水偏多.     

GRACE和SLR观测的地球动力学扁率最大熵谱及小波相关分析

卫星重力测量技术的实现为测定地球动力学扁率提供了新的方式和途径，GRACE卫星是目前最新的重力测量卫星，据其恢复的低阶重力场较以往精度得到大大提高，然而其观测地球动力学扁率（二阶项）却与卫星激光测距（SLR）结果相差较大.本文采用最大熵谱和小波分析方法对GRACE和SLR观测的地球动力学扁率时间序列信号进行定量比较分析，结果表明：GRACE观测的地球动力学扁率年际周期变化振幅仅为SLR观测结果的25%，并且目前GRACE观测的地球动力学扁率数据中含有系统输入信息和相位差，但前者较后者包含有较强的短周期（2～6月）信息.造成这种差异的主要原因可能来自于GRACE与SLR全球观测数据时空分布不同.     

渤海湾西北部潮间带沉积物激光法与筛析沉降法结果的比较

对渤海湾西北部潮间带16个样品分别进行了激光法与综合法（筛析沉降法）粒度测量。两种方法所获结果的相关分析表明，激光法测得的〉63μm的砂的百分含量平均仅比综合法低5％，相关系数高达0.9，相关性显著。两种方法测得的粉砂和粘土含量相关系数分别为0.39和0.48。进一步将〈63μm部分分为6个粒级对比两种方法的异同，结果显示〈1μm、1～2μm、2～4μm、4～8μm、8～16μm和16～63μm部分的相关系数分别为0.24、0．7、0.7、0.61、0.61和0.37。据此认为，16个样品粒径〈1μm和16～63μm部分两种方法的结果不能对比，其余粒级的激光法结果，通过各自的回归方程，可谨慎地代替传统的综合法。     

Laser Scanning的基本原理及其应用前景

首先介绍了激光测距仪的发展历程,针对应用领域的不同,分别对3维激光成像仪和机载/星载激光测高仪的测量原理进行了阐述,并分别介绍了两种激光测距仪的工作流程以及数据处理流程,最后对两种激光测距仪的应用范围进行了阐述,并把两种激光测距技术和普通摄影测量进行了比较,指出了激光测距技术相对于普通摄影测量的优点,即高精度性、穿透性、实时性。     

北半球高纬地区年际尺度循环过程中的气-海-冰相互作用关系

基于一个全球气-海-冰耦合模式数值模拟结果,对北半球高纬度地区年际尺度的气-海-冰相互作用进行了分析。在所使用的全球气-海-冰耦合模式中,大气环流模式和陆面过程模式来自国家气候中心,海洋环流模式和海冰模式来自中国科学院大气物理研究所大气科学和地球流体力学数值模拟国家重点实验室。采用一种逐日通量距平耦合方案实现次网格尺度海冰非均匀条件下大气环流模式和海洋环流模式在高纬地区的耦合。只对50 a模拟结果中的后30 a结果进行了分析。在分析中,首先对滤波后的北半球高纬度地区海平面气压、表面大气温度、海表面温度、海冰密集度及海表面感热通量的标准化距平做联合复经验正交函数分解,取第一模进行重建,然后讨论了在一个循环周期(约4 a)中北半球高纬度地区气-海-冰的作用关系。结果表明:(1)当北大西洋涛动处于正位相时,格陵兰海出现南风异常,使表面大气温度升高,海洋失去感热通量减少,海洋表面温度升高,海冰密集度减小;当北大西洋涛动处于负位相时,格陵兰海出现北风异常,使表面大气温度降低,海洋失去感热通量增多,海洋表面温度降低,海冰密集度增加。巴伦支海变化特点与格陵兰海相似,但在时间上并不完全一致。(2)多年平均而言,北冰洋内部靠近极点区域为冷中心。当北冰洋内部为低压异常时,因异常中心偏向太平洋一侧,使北冰洋内部靠近太平洋部分为暖平流异常,靠近大西洋一侧为冷平流异常。伴随着暖、冷平流异常,这两侧分别出现暖异常和冷异常,海表面给大气的感热通量分别偏少和偏多,上述海区海表面温度分别偏高和偏低,海冰密集度分别偏小和偏大。当北冰洋内部为高压异常时特点正好与上述相反。由上述分析结果可知,在海洋、大气年际循环中,大尺度大气环流变率起主导作用,海洋表面温度和海冰密集度变化主要是对大气环流变化的响应。     

Detection of iodine monoxide radicals in the marine boundary layer using laser induced fluorescence spectroscopy

A Laser Induced Fluorescence (LIF) instrument has been developed to detect iodine monoxide (IO) radicals in the atmosphere. An all solid-state Nd:YAG pumped Ti:Sapphire laser operating at approximately 445 nm was used to excite the (2,0) band of the IO A²Π_3/2 ← X²Π_3/2 electronic transition, with off-resonance fluorescence in the (2,5) band detected at 521 nm. The sensitivity of the instrument was determined by calibration. IO (between 10 and 150 pptV) was generated following the 184.9 nm photolysis of N₂O/CF₃I/N₂ mixtures with O₃ actinometry used to determine the photolysis flux. The detection limit was determined to be 0.3 pptV for a 300 s integration period, with an uncertainty of 23% (1σ). The instrument was deployed in August/September 2006 during the RHaMBLe (Reactive Halogens in the Marine Boundary Layer) campaign in Roscoff, France. Located on a small jetty, a few metres from the water’s edge at high tide, the instrument measured significant levels of IO on 11 days, with a maximum of 27.6 ± 3.2 pptV observed on one day (averaged over 10 s) representing the highest IO mixing ratio recorded in the marine boundary layer to date. IO displayed a clear diurnal profile with a maximum at low tide during the daytime. These results represent the first point measurements of IO in the atmosphere by LIF.     

GPS卫星的激光测距和应用研究

简述了SLR和GPS跟踪技术的发展概况。详细介绍了近几年来对GPS－35、36卫星的激光测距进展和应用研究的情况。给出了残差分析的初步结果,并指出了目前GPS卫星的稀少的激光测距资料对卫星精密定轨和站坐标的解算是有价值的。同时,也简单地评述了GPS卫星的微波和激光跟踪技术各自的优势和弱点．建议联合利用GPS-35、36卫星的SLR和GPS观测资料来开展有关的应用研究。最后,对今后的应用研究工作提出了建议．     

Analytical perspective on trace element species of interest in exploration

Analysis of soil and sediment samples, using selective extraction methods to distinguish different phases, is of particular interest in exploration geochemistry to locate deeply buried mineral deposits. There are various mechanisms of binding labile elements in the secondary environment, including physical and chemical sorption, precipitation, chelation and complexation. Phases present in soils and sediments which are likely to scavenge ‘free' elements include amorphous Mn and Fe oxides, the humic and fulvic components of humus, and clays. This paper reviews these forms of trace elements and the methods in current use to quantify them. Examples of precision data, both for control and survey samples, are given with respect to trace elements dissolved from the ‘soluble organic' component of humus, Mn oxides and amorphous Fe oxides. The high sensitivity of inductively coupled plasma mass spectrometry (ICP–MS) is required to measure accurately and precisely a large suite of trace elements, especially where only small fractions of elements are dissolved by such leaches as the commercially available Enzyme and MMI (Mobile Metal Ion) extractions. The relative standard deviations (RSD) obtained for 33 elements (e.g. Ag, Cd, In, I) in the standard reference sample (SRM), TILL-2, are in the range 0.5–8% for the hydroxylamine hydrochloride (NH₂OH·HCl) leach designed to extract hydrous Fe and Mn oxides. The corresponding RSDs for elements in the reactive Mn oxide phase extracted by the Enzyme leach are in the range 3–19% except for some trace elements at levels close to detection limit (e.g. Cd, Bi). The RSDs obtained for field duplicates are inferior to those for analytical replicates (i.e. sample splits), probably a reflection of different concentrations of the host phase. In one soil survey, the Fe extracted by a 0.25 M NH₂OH·HCl leach ranged conservatively from 0.2 to 1.7% whereas the Mn extracted by the Enzyme leach varied extensively, from 0.3 to >999 ppm. In contrast, precision, at 1–7% RSD, for field duplicates was found to be comparable with that for both analytical duplicates and the SRM, LKSD-4, for elements associated with the humic and fulvic component of humus samples sieved to <177 μm.     

Geological factors influencing the concentration of trace elements in the Philippi peatland, eastern Macedonia, Greece

Six peat samples obtained from the Holocene and the Weichselian of the Philippi peat deposit, eastern Macedonia, Greece, were analyzed for 48 trace elements by Inductively Coupled Plasma–Mass Spectrometry (ICP–MS). The ash contents of these samples were also determined. Most of the trace elements are associated with the minerals in the peat, while Ge, Mo, Pb, Se, Ta, Tl, U, and W display a greater affinity with the organic matter. Compared with crustal averages (Clarke concentrations), the Philippi peat is enriched in some elements (Ag, As, Au, Cd, Mo, Se, Te, U, and W) because of the respective mineralizations in the area. The Philippi peat is also enriched in Cr, Cu, Mo, Pb, Sc, Sn, T, V, Y, and Zn in comparison with typical fen peats, as well as in As, Cr, Mo, Se, and U in comparison with typical coals. Climatic and hydrogeological conditions strongly influenced the peat-forming environment resulting in a differentiation between Holocene and Weichselian peat. Generally, the Holocene peat contains lower concentrations of trace elements in the northern and southern part of the fen, than the Weichselian one. The opposite trend is observed in the fen area close to the western basin margins.     

A land surface model (IAP94) for climate studies Part II: Implementation and preliminary results of coupled model with IAP GCM

The Institute of Atmospheric Physics Land Surface Model (IAP94) has been incorporated into the IAP two-level atmospheric general circulation model (IAP GCM). Global and regional climatology averaged over the last 25 years of 100 year integrations from the IAP GCM with and without IAP94 (“bucket” scheme) is compared. The simulated results are also compared with the reanalysis data. Major findings are:(1) The IAP GCM simulation without IAP94 has extensive regions of warmer than observed surface air tempera?tures, while the simulation with IAP94 very much improves the surface air temperature.(2) The IAP GCM simulation with IAP94 gives improvement of the simulated precipitation pattern and intensity, especially the precipitation of East Asian summer monsoon and its intraseasonal migration of the rainbelts.(3) In five selected typical regions, for most of the surface variables such as surface air temperature, precipitation, precipitation minus evaporation, net radiation, latent heat flux and sensible heat flux, the IAP GCM with IAP94 pro?vides better simulations.