酸碱滴定法测定天然石膏中的碳酸盐(无水碳酸)

建立了用溴百里酚蓝—酚红作指示剂,酸碱滴定法测定天然石膏中碳酸盐的方法。在确定了试验条件的基础上,对石膏国家一级标准物质GBW03109a和GBE03110分析,相对标准偏差分别为0.08%、1.05%;分析3个天然石膏样品,相对标准偏差分别为1.47%、1.67%和0.25%;对试样进行加标回收,回收率在95.53%～97.02%之间;方法检出限为0.15%。表明用该方法测试,结果准确可靠。     

济阳坳陷奥陶系碳酸盐岩及缝洞充填方解石C、O同位素特征及其意义

对济阳坳陷奥陶系碳酸盐原岩及孔洞缝中充填方解石进行了C、O同位素测定,结果表明孔洞缝充填方解石的δ¹³C和δ¹⁸O值比原岩偏负。奥陶系三山子组和马家沟组孔缝中充填的方解石C、O同位素演化有很大区别,前者的δ¹³C和δ¹⁸O值均为负值,δ¹³C向较高负值偏移,δ¹⁸O值向较低负值偏移;马家沟组八陡段孔缝充填方解石的δ¹³C和δ¹⁸O值也多为负值,δ¹³C向较正值方向偏移,δ¹⁸O值向较高负值偏移。奥陶系碳酸盐岩孔缝充填方解石形成于大气淡水环境和埋藏成岩环境,次生孔洞可能主要形成于早期表生阶段,裂缝形成于中-新生代的构造运动,方解石主要充填于埋藏环境中。次生孔缝的主要形成时期早于油气大量运移期,对古潜山油藏的形成有利。     

中国海相碳酸盐岩的储层类型、勘探领域及勘探战略

中国海相碳酸盐岩有效储层成因类型主要包括古风化壳岩溶储层、礁滩储层及层状白云岩储层三大类。陆上中—古生界盆地三类储层均有分布,海上第三系盆地主要发育礁滩储层。针对我国海相油气地质特别是陆上中—古生界油气成藏的复杂性,提出应该加强对勘探及认识程度相对较低的礁滩储层形成的原生岩性-成岩圈闭油气藏的研究与勘探工作。石灰岩古风化壳岩溶储层具有强烈的非均质性,白云岩储层的含油气性比较依赖于有效储盖组合及构造圈闭。鉴于我国海相油气资源潜力巨大、勘探程度较低,故应该加强海相油气资源特别是陆上主要盆地海相油气资源及南海油气资源的研究与勘探开发,尤其要加强层序地层及岩相古地理编图等基础油气地质研究工作。     

塔河油田碳酸盐岩缝洞型油气藏的特征及缝洞单元划分

塔河油田奥陶系碳酸盐岩缝洞型油气藏的主要特征表现为油气藏高度远大于残丘圈闭幅度,油气分布受储集体发育程度控制,纵向上不连续,储集体主要为岩溶-构造作用所形成的缝洞,单个缝洞储集体为独立的油水系统等。运用油藏压力降落法、类干扰试井法和流体性质变化法等方法将塔河油田主体开发区划分出10个连通储渗单元和20个孤立或相对定容封闭体,对这些缝洞单元的特点作了描述。塔河油田整体上不具统一的底水;各油气藏流体性质变化较大。     

塔里木盆地牙哈—英买力地区寒武系—奥陶系碳酸盐岩储层成因类型、特征及油气勘探潜力

牙哈—英买力地区是塔北隆起上的主要油气富集区,古潜山风化壳型储层的观点一直主导着该地区寒武系—奥陶系碳酸盐岩油气勘探的思路。但储层精细描述揭示了牙哈—英买力地区除古潜山风化壳型储层外,还发育有暴露浅滩型、层间古岩溶型、白云岩型储层。其中位于古潜山面之下经风化作用改造的白云岩型储层是最有勘探价值的,勘探成功率高。其次是暴露浅滩型储层,油藏类型有早成藏残留型和晚成藏型。暴露浅滩型、层间古岩溶型和白云岩型储层也是很有勘探价值的储层类型。早成藏型原生油气藏,位于寒武系—奥陶系与志留系呈假整合接触的地区,与古潜山无关。古潜山风化壳型储层可以形成晚成藏型油气藏,但目前试油结果均为水层,值得进一步探索。     

Tidally dominated, rimmed-shelf facies of the Picún Leufú Formation (Jurassic/Cretaceous boundary) in southwest Gondwana, Neuquén Basin, Argentina

A palaeoenvironmental model for the Picún Leufú Formation (Jurassic/Cretaceous boundary), which crops out in the Neuquén Basin, Argentina, on the southwestern margin of Gondwana, is presented in this paper for the first time. Detailed stratigraphic sections exposed along National Road 40 where it crosses the Picún Leufú Creek (type locality) and in the Cerrito Caracoles area, were examined and sampled. Based on a combination of the sedimentological data obtained (facies/microfacies analysis) and the relationship between benthic macrofaunas and their taphonomic attributes, it is concluded that the formation reflects a tidally dominated, rimmed-shelf setting characterized by prograding bars dissected by channels and thick lagoonal facies with shoal developments. In the Cerrito Caracoles area, where only the basal part of the formation is exposed, it is interpreted to have been deposited in a shallow subtidal marine environment in which shelf margin facies with patch reefs have been recognized.     

Methane-induced dolomite “chimneys” on the Kuroshima Knoll, Ryukyu islands, Japan

The Kuroshima Knoll is about 26 km south of Ishigaki Island in the southern part of the Ryukyu Arc. The area is considered to be the source area of “The 1771 Yaeyama Earthquake Tsunami”, which was due to the submarine landslide caused by an earthquake. It has been cleared from some investigations using “Dolphin 3K” and “Shinkai 2000” that there are large-scale dead Calyptogena colonies, many gravels of fallen dolomite chimneys and carbonates on the top of the Knoll [Matsumoto, T., Uechi, C., Kimura, M., 1997; Machiyama, H., Matsumoto, T., Matsumoto, R., Hattori, M., Okano, M., Iwase, R., Tomaru, H., 2001b.]. Carbonates of Kuroshima Knoll have various shapes and macroscopic textures. These have been classified into 4 types; shell crust (pavement), chimney, burrow, and nodule. It is clear that all chimney and burrow carbonates are composed of dolomite, while shell curst and nodule are composed of calcite, sometimes both calcite and dolomite. These carbonates are considered to have been formed by cold seep, because they are characterized by the light carbon isotopic ratio (semi-biogenic) and the heavy oxygen isotopic ratio. This suggests that methane hydrate layers develop under this survey area and the water that has the heavy oxygen and the light carbon isotopic ratio is derived from the dissociation of methane hydrate.     

Distinct sedimentary processes reflected in the isotopic signatures of dolomitic concretions in the Miocene Pohang Basin (southwestern East Sea)

Dolomitic concretions in diatomaceous hemipelagic sediments of the Miocene Pohang Basin in the southwestern East Sea (Sea of Japan) preserve distinct signals of two independent sedimentary processes, which controlled the extents of isotopic compositions. Variable δ¹⁸O (−9.1‰ to +0.7‰) and high δ¹³C (+3.1‰ to +17.9‰) values suggest that the concretions formed in the methanogenic zone with alteration of the residual mid-Miocene seawater by volcanogenic sediments. Remarkable δ¹⁸O and δ¹³C values show a strong linear relationship, indicating that distinctly independent depositional processes operated during the formation of the concretions. The degree of methanogenesis was enhanced during rapid hemipelagic sedimentation of organic-rich particles, resulting in higher δ¹³C values, and the effect of volcaniclastics was diluted, maintaining the original properties of ambient mid-Miocene seawater. In contrast, lower δ¹⁸O and ⁸⁷Sr/⁸⁶Sr values characterize the effect of volcaniclastic sediments that were transported by intermittent gravity flows and interacted with mid-Miocene seawater. The input of volcaniclastic sediment probably degraded the role of methanogenesis by lowering the contents of organic matter and thereby decreased the δ¹³C values within the concretions. Isotopic signals recorded within the concretions highlight understanding of the depositional environment and evolution of the pore-water chemistry.     

辽东半岛南部早古生代馒头组—冶里组沉积盆地演化

辽东半岛南部早古生代地层发育,其中馒头组—冶里组的沉积过程,具有完整的陆源碎屑岩—碳酸盐岩堆积特点。从层序划分、沉积环境演化、古气候变迁等方面分析,馒头组—冶里组反映了一个完整的碳酸盐岩台地的发展过程,可划分出准备阶段（形成碎屑岩垫板）、生长—发育阶段（形成碳酸盐岩缓坡）及衰亡阶段（发育白云岩盖层）。     

湘黔地区中奥陶世海平面上升的沉积响应

中奥陶世克拉道克阶(Caradocian)在全球范围内为海侵期,体现在全球范围广泛的黑色页岩沉积及笔石动物的大规模繁盛,湘黔地区这一时期地层发育完全,从碳酸盐台地-斜坡-外陆架盆地均有不同程度的响应。在台地区表现为碳酸盐台地的淹没,斜坡区表现为碳酸盐重力流及黑色页岩、粉砂岩沉积,形成碳酸盐与陆源碎屑的混合沉积,而在外陆架盆地区表现为黑色岩系大规模发育及笔石的大量繁盛。