白云鄂博碳酸岩墙碳氧同位素地球化学

对内蒙古白云鄂博 REE- Fe- Nb矿床周围碳酸岩墙中共存的方解石和白云石进行了 C和 O同位素分析。结果表明，方解石和白云石的δ 13C值变化范围一致，均为－ 3.5‰～－ 7.3‰，落在正常地幔δ 13C值范围 (－ 5‰± 2‰ )内；而它们的δ 18O值可分为两组，第Ⅰ 组为 9.5‰～ 18.0‰，第Ⅱ 组为 20.6‰～ 22.6‰，均远大于正常地幔δ 18O值范围 (5.7‰± 1.0‰ )。第Ⅰ 组低δ 18O值样品中共存白云石与方解石之间的 C和 O同位素分馏均为负值，因此处于热力学不平衡状态，指示它们自形成后受到过后期热液蚀变，与先前的岩石学观察一致。相反，第Ⅱ 组高δ 18O值样品中白云石与方解石之间的 C和 O同位素分馏均为正值，处于热力学平衡状态，指示它们自形成后未受到后期热液蚀变，因此可能沉淀于晚期低温高δ 18O值流体。第Ⅰ 组碳酸岩墙中白云石的 C和 O同位素组成不呈线性分布，指示碳酸岩浆并非由幔源碳酸盐与沉积碳酸盐混合形成。应用水-岩交换模型计算得到，第Ⅰ 组碳酸岩在侵位后经历了碳酸岩浆期后热液的不均一蚀变，蚀变温度约在 220～ 800℃之间，蚀变流体的 CO2/H2O比值较小 (1/500)，但水 /岩比值变化较大 (10～ 400)。由于低温下方解石与热液之间的碳氧同位素交换速率大于白云石，导致这部分碳酸     

Fault-controlled dolomitization at Swan Hills Simonette oil field (Devonian), deep basin west-central Alberta, Canada

The partly dolomitized Swan Hills Formation (Middle‐Upper Devonian) in the Simonette oil field of west‐central Alberta underwent a complex diagenetic history, which occurred in environments ranging from near surface to deep (>2500 m) burial. Five petrographically and geochemically distinct dolomites that include both cementing and replacive varieties post‐date stylolites in limestones (depths >500 m). These include early planar varieties and later saddle dolomites. Fluid inclusion data from saddle dolomite cements (T_h=137–190 °C) suggest that some precipitated at burial temperatures higher than the temperatures indicated by reflectance data (T_peak=160 °C). Thus, at least some dolomitizing fluids were ‘hydrothermal’. Fluorescence microscopy identified three populations of primary hydrocarbon‐bearing fluid inclusions and confirms that saddle dolomitization overlapped with Upper Cretaceous oil migration. The source of early dolomitizing fluids probably was Devonian or Mississippian seawater that was mixed with a more ⁸⁷Sr‐rich fluid. Fabric‐destructive and fabric‐preserving dolostones are over 35 m thick in the Swan Hills buildup and basal platform adjacent to faults, thinning to less than 10 cm thick in the buildup between 5 and 8 km away from the faults. This ‘plume‐like’ geometry suggests that early and late dolomitization events were fault controlled. Late diagenetic fluids were, in part, derived from the crystalline basement or Palaeozoic siliciclastic aquifers, based on ⁸⁷Sr/⁸⁶Sr values up to 0·7370 from saddle dolomite, calcite and sphalerite cements, and ²⁰⁶Pb/²⁰⁴Pb of 22·86 from galena samples. Flow of dolomitizing and mineralizing fluids occurred during burial greater than 500 m, both vertically along reactivated faults and laterally in the buildup along units that retained primary and/or secondary porosity.     

Oxygen and Carbon Isotope Study of Calcite and Dolomite in the Disseminated Au-Ag Telluride Bulawan Deposit, Negros Island, Philippines

Abstract: The disseminated Au‐Ag telluride Bulawan deposit, Negros island, Philippines, is hosted by dacite porphyry breccia pipes which formed in a Middle Miocene dacite porphyry stock. Electrum and Au‐Ag tellurides occur mostly as grains intergrown with or filling voids between sphalerite, pyrite, chalcopyrite, galena and tennantite. Calcite, quartz and rare dolomite are the principal gangue minerals. Four types of alteration were recognized in the deposit, namely; propylitic, K‐feldspar‐sericitic, sericitic and carbonate alteration. Carbonate alteration is correlatable to the gold deposition stage and occurs mostly along fault zones. The δ¹⁸O and δ¹³C compositions of calcite and dolomite in propylite zone and ore‐stage dacite porphyry breccia were determined. The δ¹⁸O values of calcite in propylitized andesite range from +12.2 to +14.7%, and their δ¹³C values range from ‐6.1 to ‐1.0%. The δ¹⁸O values of calcite and dolomite in sericite‐ and carbonate‐altered, mineralized dacite porphyry breccia and dacite porphyry rocks range from +15.1 to +23.1%, and the δ¹³C values of calcite and dolomite range from ‐3.9 to +0.9%. The δ¹⁸O and δ¹³C values of the hydrothermal fluids were estimated from inferred temperatures of formation on the basis of fluid inclusion microthermometry. The δ¹⁸O values of hydrothermal fluid for the propylitic alteration were calculated to be +8.5 ‐ +9.5%, assuming 375°C. On the other hand, the δ¹⁸O values of ore solutions for base metal and Au mineralization were computed to be +13.6 ‐ +14.6%, assuming 270°C. The hydrothermal fluids that formed the Bulawan deposit are dilute and ¹⁸O‐enriched fluids which reacted with ¹⁸O‐ and ¹³C‐rich wallrocks such as limestone.     

新疆早寒武世玉尔吐斯小壳动物群再研究

新疆乌什—阿克苏地区下寒武统玉尔吐斯组的小壳化石丰富,已描述了近50属90种,包括1个新属,15个新种。计有软舌螺类、似软舌螺类、单板类、腹足类、骨针类及分类位置未定的化石,还有节肢动物门的高肌虫类。按小壳化石在地层纵向出现的次序及其代表性,可将玉尔吐斯组小壳动物群的比石划分为3个带,即1.Anabarites trisulcatus带;2.Cambroclavus-Aurisella带;3.Adyshevitheca-Xinjiangella带。其中1带可与梅树村阶I.Anabarites-Protohertzina带对比;2—3带大致可与梅树村阶Ⅱ.Paragloborilus-Siphogonuchites带—Ⅲ.Sinosachites-Lapworthella带对比。因Aanbarites trisulcatus的发现,证实玉尔吐斯组的下界可与梅树阶的底界对比;玉尔吐斯组顶部发现的高肌虫有别于筇竹寺阶的高肌虫。前者与大量梅树村期小壳动物共生,可以认为梅树村期已经出现高肌虫的先遣分子。     

Lower palaeozoic and precambrian petroleum source rocks and the coalification path of alginite

Organic-rich samples derived from a Middle Cambrian Formation in the Georgina Basin, and from the Middle Proterozoic of the McArthur Basin in northern and central Australia, yielded alginite ranging from immature oil shale material to overmature residue. A maturation scale has been developed based on the thermal evolution of alginite as determined from reflectance and fluorescence. The coalification path of alginite is marked by jumps in contrast to the linear path of wood-derived vitrinite. Six zones have been recognised, ranging from undermature (zone I), through the mature (zones II/III), followed by a stable stage of no change (zone IV) to the overmature (zones V and VI). The onset of oil generation in alginite as evident from the present study is at 0.3% R_{o Alg.} and is expressed in a change of fluorescence from yellow to brown, and a coalification jump from 0.3 to 0.6% R_o of Alg. In many boreholes zone III can be distinguished between 0.6 and 0.8% R_o of Alg. where subsequent oil generation occurs. Zones II and III represent the oil window.A zone of little or no change designated zone IV, at of alginite follows zones II/III. A marked coalification jump characterises zone V, where a pronounced change in reflectance occurs to >1.0% R_{o Alg.}, signifying peak gas generation. The border of oil preservation lies at the transition of zone V and VI, at 1.6% R_{o Alg.} In zone VI gas generation only occurs.Comparison of reflectance results with experimental and geochemical pyrolysis data supports high activation energies for hydrocarbon generation from alginite, and therefore a later onset of oil generation than other liptinite macerals (i.e. cutinite, exinite, resinite) as well as a narrow oil window.Transmission electron microscopy (TEM) confirms that alginite does not go through a distinct intermediate stage but that the percentage of unreacted organic matter decreases as maturation proceeds. A clear distinction can be made in TEM between immature alginite, alginite after oil generation, and alginite residue following gas generation. Alginite beyond 1.6% R_o acquires very high densities and the appearance of inertinite in TEM.Bitumens/pyrobitumens make a pronounced contribution to the organic matter throughout the basins and have been shown to effect pyrolysis results by suppressing T_max. The bitumens/pyrobitumens have been divided into four groups, based on their reflectance and morphology, which in turn appears to be an expression of their genetic history. Their significance is in aiding the understanding of the basins' thermal history, and the timing of oil and gas generation.     

湘西北下寒武统黑色页岩伴生元素研究新进展

湖南大庸慈利的镍钼多金属矿床是湘西北下寒武统黑色页岩中伴生元素镍钼及铂族元素等富集最好地段。该矿床中的硅岩应属典型的喷气岩；特殊的筒状富矿体，以及Ｎｉ、Ｍｏ、Ｃｕ、Ｚｎ、Ｓｅ、Ａｓ、Ｂａ、Ａｕ、Ａｇ、Ｐｔ族元素特殊组合；矿石中金属硫化物呈胶状产出，显示快速堆积特征。     

我国早期生命进化研究的进展和展望

概述了中国在晚前寒武纪——寒武纪生物化石群研究多方面(尤其是大化石)的主要成就。其中,近年发现的震旦纪陡山沱期化石生物(包括庙河生物群和蓝田植物群),对植物界的进化说来是个重要阶段;早寒武世澄江生物群(包括软躯体生物和软部保存的带骨骼生物)早于国外著名的布吉斯页岩生物群,逼近了带骨骼动物最初的爆发式辐射期。这些珍稀化石的研究将促进对早期生物进化历程的重新认识。这个研究领域有无可限量的前景。     

陕西双王金矿床含铁白云石的某些标型特征

含铁白云石是双王金矿床矿体和围岩中的主要矿物,按其产状可分为四类:Ⅰ.产于层状钠质岩(矿体围岩)中的含铁白云石;Ⅱ.产于含金角砾岩体钠质岩角砾中的含铁白云石;Ⅲ.产于含金角砾岩胶结物中的含铁白云石,Ⅳ.产于近矿蚀变岩石中的含铁白云石。Ⅰ,Ⅱ类为热水沉积成因,Ⅲ和Ⅳ类为热液充填交代产物;它们在化学成分、有序度及碳氧同位素等方面有许多相似之处,但又有一定的差别。研究表明,含金角砾岩胶结物中的含铁白云石主要来自层状钠质岩,为矿床的热水沉积—改造成因提供了新的证据。     

基本层序和相分析是区调中组建立的基础

以赣西北地区中、上寒武统划分为例,阐述基本层序、相分析在岩石地层单位划分和对比中的作用、地位。划分岩石地层单位不能仅仅根据岩性特征,而必须进行基本层序和系统的相分析。在这样的基础上,划分的岩石地层单位才具有准确性、合理性和野外实用性。     

Diversification of skeletal microstructures of organisms through the interval from the latest Precambrian to the Early Cambrian

From the latest Precambrian to the Early Cambrian was the most important phase throughout the evolutionary history of life on the earth. The diversification of latest Precambrian multicellular organisms was obvious and some of them began to form primary s…