多期构造演化盆地的复杂地温场对油气生成的影响——以塔里木盆地塔中地区为例

根据磷灰石裂变径迹分析（ＡＦＴＡ）及干酪根自由基浓度分析了塔里木盆地塔中地区单井的热历史，同时结合波动地质学分析的结果研究了其复杂的构造演化－沉积埋藏史，由此探讨了复杂构造运动对油气生成和油气藏形成的影响，表明多期构造运动一方面对油气藏会产生破坏作用，而另一方面却对延长生油层的生烃时间有利（即可以晚期生烃）。后期多次构造运动有利于烃源岩晚期、长期生烃     

塔里木盆地群4井原油吡咯类含氮化合物地球化学研究

在塔里木盆地群４井原油中成功地分离并检测出丰富的吡咯类含氮化合物-链基咔唑类，而链基苯并咔唑和链基二苯并咔唑则未被发现。链基咔唑中以二甲基咔唑、C₃-咔唑和C₄-咔唑为主。在甲基咔唑和二甲基咔唑中又鉴别出多个异构体。甲基咔唑中G2 G3含量相当，而二甲基咔唑中G3占优势。在我国，原油含氮化合物研究刚刚起步。实践证明，该类化合物是研究油气运移的可靠的、专属性强的标志化合物。通过本项研究，我们认为群４井原油已经历了长距离的运移。     

Geochemistry of Brines from Salt Ore Deposits in Western Tarim Basin

In the geological evolution of the Tarim Basin, many transgressions and relictions happened. So there have been plentiful sources of salt. Moreover, because of uttermost drought, a lot of salt has been deposited. It is possible to find potash salt in this area. In our fieldwork, we have found salt and brine in western Tarim Basin. Based on a geological survey and the characteristics of sedimentary facies and paleogeography, this paper deals with the geochemical parameters and discusses the possibility of formation of potash salt in terms of the chemical analyses of samples collected from western Tarim Basin. Results of brine analysis lead to some conclusions: most of these salt brines have eluviated from very thick halite beds, mainly chloridetype salt and this kind of halite does not reach the stage of potash deposition in all aspects; WKSL (Wukeshalu) occupies a noticeable place, and we should attach importance to this district because there have been some indicators of the occurrence of potash deposits as viewed from the contents of Br and K. Finally, low Br contents are recognized in the Tarim Basin as a result of salt aggradation, and this point of view has been proved by the results of this experiment and the data available. It cannot depend upon the index of Br to judge the evolution stage of halite. We must look for other facies of potash except marine facies.     

塔中地区油气运聚特征

塔中地区主要受塔中Ⅰ号、Ⅱ号及Ⅲ号三条大断层控制 ,形成巨型复式背斜 ,隆起高部位地层遭受了强烈的风化剥蚀。背斜之上 ,断裂和局部构造发育。可划分出两个主要成藏期 :第Ⅰ成藏期为寒武系—下奥陶统烃源岩成熟生烃运移期 ,生排烃高峰为志留纪 ;第Ⅱ成藏期为中—上奥陶统烃源岩在燕山期—喜马拉雅期成熟生烃运聚。第Ⅰ成藏期形成的油藏有两个特征 :在塔中Ⅰ号断裂带、北部斜坡带油气注入奥陶系及志留系圈闭中 ,形成原生油气藏 ;构造高部位 (如中央断垒带 )的油气藏在后期构造运动中遭受破坏。第Ⅱ成藏期形成的油藏可分为两类 :对早期油藏的再次充注 ;聚集形成新油藏。塔中地区的油气运移通道主要有断裂和不整合面 ,油气的分布也主要受断裂和不整合面所控制。塔中Ⅰ号构造带和北部斜坡带是较为有利的勘探区带     

塔里木盆地北缘库车盆地白垩系风成砂岩研究--以库车河剖面为例

库车盆地的早白垩世地层为一套干旱气候条件下的红层沉积，包括洪积扇砾岩、间歇性河流砂砾岩、风成细砂岩和粉砂岩、沙漠湖相紫红色泥岩等类型的沉积，组成一个较为典型的沙漠沉积体系。在库车河剖面，下白垩统红层中发育一些厚层至块状的“高能细砂岩和高能粉砂岩”，多为岩屑长石石英砂岩和长石岩屑石英砂岩。它们以良好的分选性和较高的结构成熟度、较细的粒度、较低的成分成熟度和大型交错层理的发育为特征，显示出较为明显的风成沉积特点。     

塔里木盆地西部古岩盐地质地球化学特征与成钾条件分析

塔里木盆地是我国重要的成盐盆地,为我国最有远景的找古钾矿地区之一。本文通过多年野外实地调查和大量岩盐样品的化学分析,特别是岩盐中可以指示沉积阶段的Br×103/Cl系数等区域分布特征,联系前人研究资料,分别从构造环境、地层和岩相古地理、地球化学特征等方面进行了成钾条件分析。结果表明,莎车盆地西部喀什坳陷和库车盆地中部拜城坳陷宏观地质特征均有利于钾盐沉积;岩盐地球化学组成相对于正常海相沉积表现出明显的贫Br特征,属海陆交互相或海源陆相沉积。相比之下,莎车盆地的喀什次级坳陷是目前最有前景的找钾远景区。     

Origin of Natural Gas in Kekeya Field, Tarim Basin, China

This paper is mainly concentrated on the geochemical characteristics and origin of gas of Kekeya field in the Tarim basin, NW China. This study shows that Permian mudstone is the main source rock of oil and gas. Based on the carbon isotopes of C1--C4, the carbon isotope of gas in Kekeya field is a little heavier than that in the typical marine-derived gas. The relationship between carbon isotopes of methane and ethane is coincident with Faber equation of gas derived from organic matter Ⅰ/Ⅱ. The majority of gas maturity is estimated, based on the formula, at 1.8%-2.2% besides K2 and K18 wells. In addition, the gas derived from 0.9%-1.2% Ro source rocks may also bemixture. ^40Ar/^36Ar and ^3He/^4He ratios from the gas samples also support the mixing process. Moreover, the gas in this region is mainly generated from more mature source rocks although the low mature gas exists.     

塔里木盆地南缘历史时期气候环境变化的过程与特征

根据塔里木盆地南缘具较高分辨率的湖沼相沉积物碳酸盐δ^13C和粒度等记录，恢复出2162-850BC期间为一相对稳定的温暖干旱时期，之后迅速转冷湿，湿润程度呈持续、阶段式增加，50 BC至500 AD期间呈现的显著冷湿特征于550 AD之后突变转暖干而结束。550 AD和1000 AD前后的具突变性质的气候事件在南疆地区近2．0ka的气候变化中具有重要意义，反映气候状况有过重大调整。850—1300AD期间(相当于中世纪温暖期)冷暖、干湿多变，但温暖特征并不明显。特别是1100—1200AD期间气候快速、频繁变化之后，奠定了本地区现代稳定干旱环境特征。区域对比表明，尼雅剖面记录的气候变化具有广泛的区域一致性。     

塔里木盆地构造-沉积波动过程

根据塔里木盆地环满加尔地区的不整合和构造形成时间研究, 以及对典型井沉积充填的“地质滤波”分析, 研究了塔里木盆地的构造-沉积波动演化过程. 典型井的“地质滤波”分析证明, 在时间上, 塔里木盆地演化受控于740±, 200±, 100±和 30±Ma的周期性波动过程. 沉积充填、盆地沉降和不整合分析证明盆地沉积相带的趋向呈周期性转换, 沉积中心和沉降中心逆时针迁移, 周期为200±Ma, 说明波动在空间上的传播. 塔里木盆地的这种波动演化过程对认识盆地的油气成藏规律具有重要意义.     

Ruthenium-ion-catalyzed oxidation of asphaltenes and oil-source correlation of heavy oils from the Lunnan and Tahe oilfields in the Tarim Basin, NW China

The identification of marine source rocks in the Tarim Basin is debated vigorously. The intention of this paper is to investigate the asphahenes in heavy oils from the Lunnan and Tabe oilfields and Well TD2 with ruthenium-ions-catalyzed oxidation technique (RICO), in order to explore its role in oil-oil and oil-source correlations, The RICO products included n-alkanoic acids, α,ω-di-n-alkanoic acids, branched alkanoic acids, tricyclic terpanoic acids, hopanoic acids, gammacerane carboxylic acid , regular sterane carboxylic acids and 4-methylsterane carboxylic acids. The n-alkyl chains and biomarkers bounded on the asphaltenes were of unsusceptibility to biodegradation. The distribution and absolute concentrations of n-alkanoic acids in the RICO products of heavy oils from the Lunnan and Tabe oilfields are different from those of Well TD2. The biomarkers bounded on the asphahenes, especially steranes, have a distribution trend similar to that of the counterparts in saturates. The sterane carboxylic acids and 4-methylsterane carboxylic acids in the RICO products of heavy oils from the Lunnan and Tahe oilfields, dominated by C30 sterane and C31 4-methylsterane carboxylic acids, respectively, are significantly different from those of the heavy oils of Well TD2, whose dominating sterane and 4-methylsterane carboxylic acids are C28 sterane and C29 4-methylsterane acids, respectively. The RICO products of the asphaltenes further indicate that the Middle-Upper Ordovician may be the main source rocks for heavy oils from the Lunnan and Tabe oilfields.