单站GPS遥感水汽含量范围的确定及结果分析

随着GPS技术的日益成熟和研究的不断深入,GPS的定位精度得到了大幅度的提高,为其在测绘、交通、林业资源、石油勘探、精细农业等行业的应用提供了更广阔的空间。GPS气象学(GPS/Meteorology简称GPS/MET)的诞生改善了原有大气监测技术的局限性,极大的提高了气象监测的时空分辨率,但是在将这项技术由试验阶段向推广普及应用的过程中,单站地基GPS监测的有效范围以及水汽解的精度一直为广大气象学家们所忽略,本文在对以往GPS气象数据收集和整理的基础上,根据理论计算和实际验算,得出了一些有益的结论。     

Study on Ozone Change over the Tibetan Plateau

This paper reviewed the main results with respect to the discovery of low center of total column ozone (TCO) over the Tibetan Plateau (TP) in summer, and its formation mechanism. Some important advances are summarized as follows: The fact is discovered that there is a TCO low center over the TP in summer, and the features of the background circulation over the TP are analyzed; it is confirmed that the TP is a pathway of mass exchange between the troposphere and stratosphere, and it influences the TCO low center over the TP in summer; models reproduce the TCO low center over the TP in summer, and the formation mechanism is explored; in addition, the analyses and diagnoses of the observation data indicate that not only there is the TCO low center over the TP in summer, but also TCO decrease trend over the TP is one of the strong centers of TCO decrease trend in the same latitude; finally, the model predicts the future TCO change over the TP.     

北大西洋臭氧极小值和北太平洋极大值及其相互关系

利用1979～2002年TOMS卫星观测资料,采用臭氧总量纬向偏差和区域强迫的分析方法,研究北大西洋东北部大气臭氧低值与北太平洋西北部臭氧高值的季节变化过程和相互关系.研究表明,(1)北大西洋东北部存在一个大气臭氧极小值,年平均臭氧总量比纬向平均值低20 DU以上,冬季低50 DU以上; 北太平洋西北部存在一个大气臭氧极大值,年平均臭氧总量比纬向平均值高35 DU以上,冬季高70 DU以上.(2)上述两个地区大气臭氧的季节变化具有很强的区域特征,区域大气动力学输送和化学过程对上述两个地区大气臭氧季节变化的强迫分别为50.3%和42.6%.(3)上述两个地区大气臭氧纬向偏差的季节变化间存在很好的反相关,相关系数达到-0.98,说明其臭氧区域强迫之间存在良好的关系.     

大气臭氧总量的经验计算方法

依据臭氧生消与紫外辐射(UV)能量利用相互作用的观点,考虑与臭氧有关的主要因子UV、大气中物质在化学和光化学反应中对UV能量的吸收、气溶胶粒子的散射等,在分析1990—1992年臭氧总量、太阳辐射、气象资料的基础上,建立了计算臭氧总量的经验模式,其优点是所用资料均可由常规气象站获得。结果表明,计算值与观测值符合得比较好。利用该经验模式计算了北京地区1979年1月—1996年6月的臭氧总量,计算值与观测值同样比较一致,二者相对偏差的最大值、最小值、平均值分别为15.2%、0.05%和4.9%,相对偏差在±10%之内的比例为91.4%,因而该经验模式是合理、可行的。1991年之后北京地区臭氧的下降与Pinatubo火山气溶胶的影响有关。     

Long-term changes (1980–2003) in total ozone time series over Northern Hemisphere midlatitudes

Long-term changes in total ozone time series for Arosa, Belsk, Boulder and Sapporo stations are examined. For each station we analyze time series of the following statistical characteristics of the distribution of daily ozone data: seasonal mean, standard deviation, maximum and minimum of total daily ozone values for all seasons. The iterative statistical model is proposed to estimate trends and long-term changes in the statistical distribution of the daily total ozone data. The trends are calculated for the period 1980–2003. We observe lessening of negative trends in the seasonal means as compared to those calculated by WMO for 1980–2000. We discuss a possibility of a change of the distribution shape of ozone daily data using the Kolmogorov-Smirnov test and comparing trend values in the seasonal mean, standard deviation, maximum and minimum time series for the selected stations and seasons. The distribution shift toward lower values without a change in the distribution shape is suggested with the following exceptions: the spreading of the distribution toward lower values for Belsk during winter and no decisive result for Sapporo and Boulder in summer.     

Product study of the reaction of OH radicals with isoprene in the atmosphere simulation chamber SAPHIR

Atmospheric oxidation of isoprene and its oxidation products methacrolein (MACR) and methyl vinyl ketone (MVK) have an important impact on the photochemical activity in the boundary layer, in particular in forested areas. The oxidation of isoprene by OH radicals was investigated in chamber experiments conducted under tropospheric conditions in the atmosphere simulation chamber SAPHIR at the Research Center Jülich. The aim was to determine the product yield of MVK and MACR in the OH-induced isoprene oxidation and the rate constant of their reaction with OH under real atmospheric conditions. The recently published updated degradation scheme for isoprene from Geiger et al. (2003) was used to determine rate constants and product yields. The fractional yields in the isoprene peroxy radical reaction with NO were found to be 0.41±0.03 for MVK and 0.27±0.03 for MACR. The rate coefficient for MACR with OH was found to be in very good agreement with the recommended value of IUPAC Atkinson (Atkinson et al., 2005). while the rate coefficient for MVK with OH was 27% lower.     

近10a西北太平洋海域登陆台风的环境场特征分析

对1995~2004年5~10月西北太平洋海域登陆台风的大尺度环境场的特征进行了分析。结果表明:海表温度(SST)在台风发生的区域要高于周围其它区域,而且都在26.5℃以上,即高的海表温度有利于台风的发展;在台风的发现点主要集中的区域范围,相对涡度几乎都为正值,正的相对涡度有利于台风的发展;对流层中层相对湿度大,有利于上升浮力和潜热释放的维持,使热带气旋得以发展;弱的环境风垂直切变有利于台风强度的增大,并且两者之间的影响存在着一定的时间滞后。     

云顶以下臭氧对TOMS反演臭氧总量的影响及反演方法的理论研究

目前紫外后向散射反演臭氧总量的所有算法，都将云考虑成不透明的Lambertian反射体，并假定云顶有效反照率不随波长的变化而变化.然而本文通过模拟计算发现，由于云散射、瑞利散射、臭氧吸收三种作用的综合结果，云顶的有效反照率是与波长相关的，即使光学厚度比较大的云，辐射也可由云顶继续向下传输，因而会受到云顶以下臭氧吸收的影响.用V7方法进行反演，模拟计算结果表明：云的出现使得云顶以下，特别是云内光程增强，导致紫外波段的臭氧吸收衰减增大，所以反演出的臭氧总量值比真实值偏大，本文称这种现象为“云吸收效应”，并讨论了该效应的影响因子.最后，在辐射传输模拟的基础上建立一套反演算法，大大减弱了“云吸收效应”的影响.     

长江三角洲地区对流层臭氧的变化趋势

Analysis of tropospheric ozone residual (TOR) data from satellite measurements indicates an increasing trend of tropospheric ozone over the Yangtze Delta region of China. The increasing trend can be derived both from the annual mean TOR and from the monthly mean TOR except for January and March. The increase rate of the decadal mean TOR was 0.82 DU during 1978-2000. The impact of this long-term trend on the climate and atmospheric oxidizing capacity over the region should be further studied. Data comparison shows a significant correlation between the TOR and surface ozone data collected at Lin'an background station in the Yangtze Delta region, suggesting an internal connection between both quantities.     

Retrieval of the Change of Precipitable Water Vapor by GPS Technique

The feasibility of GPS precipitable water vapor (PWV) is discussed based on the comparison of Radiosonde and GPS PWV where the correlation coefficient is 0.94 and the RMS is 4.0 mm. PWV change in the C...