Synchrotron IR study of hydrous ringwoodite (γ-Mg2SiO4) up to 30 GPa

High-pressure synchrotron infrared (IR) absorption spectra were collected between 650 and 4,000 cm⁻¹ at ambient temperature for hydrous Mg-ringwoodite (γ-Mg₂SiO₄) up to 30 GPa. The main feature in the OH⁻ stretching region is an extremely broad band centred at 3,150 cm⁻¹. The hydrogen bond is strong for most protons and the most probable site for protonation is the tetrahedral edge. With increasing pressure, this band shifts downward while decreasing its integrated intensity until disappearance at a pressure of 25 GPa. Only one band at 2,450 cm⁻¹ and an absorption plateau persist with a maximum wavenumber of 3,800 cm⁻¹. This behaviour is reversible upon pressure release. We interpret this as a second-order phase transition occurring in hydrated Mg-ringwoodite at high pressure (beyond ∼ 25 GPa). This result is compatible with the observation by Kleppe et al. (Phys Chem Miner 29:473–476, 2002a) who suggested the presence of Si–O–Si linkages and/or partial increase in the coordination of Si. Beyond the phase transition, the protons are delocalized and their environment on the ringwoodite structure is probably quite different from that at low pressure. Data obtained in situ at high pressures and temperatures are needed to better understand the effect of protonation on the structure and to better constrain this phase transition.     

2003年 8月 21-22日辐合气流暴雨天气过程总结

本文综合应用天气图、静止卫星云图、物理量诊断场,分析了 2003年 8月 21～ 22日黑龙江省大范围强降水过程.分析了乌拉尔山阻高、副热带高压和冷暖空气在暴雨天气过程中的作用.得出有预报指示意义的特征.并对日本传真图的降水预报能力进行了检验分析.在暴雨预报中也具有一定的预报意义.     

新疆冰雹天气过程的基本特征

通过对新疆39a冰雹天气资料的普查，得到76次系统性冰雹天气过程和1279次局地冰雹天气过程，局地冰雹天气的发生远远多于系统性雹天气。冰雹天气过程与地形密切相关，主要发生在山区，冰雹天气以1天为主，多发生于夏季，系统性冰雹天气均由中尺度高压造成。     

多年冻土地区L型挡土墙土压力(冻胀力)的分析与试验

为适应多年冻土区土体冻胀过程所产生的较大变形的特性, 缩短施工进程, 减少扰动时间, 在青藏铁路格拉段选择了一个试验工点进行了L型悬臂挡墙的初步验证性试验研究. 通过对L型挡墙的受力模式分析, 确定了对粗颗粒填料不考虑冻胀力的土压力设计控制值. 通过与现场实测土压力分布规律的对比, 探讨了土压力与冻胀力的关系.     

裂隙型单斜介质中弹性系数的计算及波的传播特性研究

根据Hudson等关于裂隙介质弹性系数计算的扰动理论及Bond变换矩阵原理，给出了各向同性介质中含多组垂直裂隙时等效弹性系数的计算方法。计算了含两组斜交的垂直裂隙形成的单斜各向异性介质中的等效弹性系数，并根据Christoffel方程推导、得出水平面内平面波传播的相速度和群速度随方位变化的特性。     

H2O-CH4-H2-CO2-CO-O2在高温、高压和高密度条件下的状态方程

为了计算高温，高压和高密度流体的热力学性质，提出了一个具有19个参数的维里型状态方程，其中参数与温度间的函数关系采用由Sutherland位能函数导出的维里系数近似式。除临界点附近以外，在已报道的pVT数据所覆盖的大部分超临界区域内，该方程均可适用。用该方程对H2O，CH4，H2，CO2，CO和O2等流体pVT关系的计算结果令人满意，其中pVT上限分别为：91-610GPa,1.6-11.0cm^3/mol,4000-5000K。计算体积的平均偏 小于0．8％，最大偏差小于5．4％。     

高温高压下电解质溶液热力学性质的研究进展

高温高压下电解质溶液热力学性质的研究不仅对探讨地球内部流体的作用具有重要意义，而且在很多实际工业过程中也都有广泛应用。本综述了近10年来高温高压下电解质溶液热力学参数的实验测量和理论计算的进展，实验设备还有待进一步的改进和完善，以获得更高温度和压力下的数据，理论计算不仅有待于实验的发展，也与溶液的结构理论密切相关。     

Evaluation of the Reduction in Uncertainty Obtained by Conditioning a 3D Stochastic Channel to Multiwell Pressure Data

A stochastic channel embedded in a background facies is conditioned to data observed at wells. The background facies is a fixed rectangular box. The model parameters consist of geometric parameters that describe the shape, size, and location of the channel, and permeability and porosity in the channel and nonchannel facies. We extend methodology previously developed to condition a stochastic channel to well-test pressure data, and well observations of the channel thickness and the depth of the top of the channel. The main objective of this work is to characterize the reduction in uncertainty in channel model parameters and predicted reservoir performance that can be achieved by conditioning to well-test pressure data at one or more wells. Multiple conditional realizations of the geometric parameters and rock properties are generated to evaluate the uncertainty in model parameters. The ensemble of predictions of reservoir performance generated from the suite of realizations provides a Monte Carlo estimate of the uncertainty in future performance predictions. In addition, we provide some insight on how prior variances, data measurement errors, and sensitivity coefficients interact to determine the reduction in model parameters obtained by conditioning to pressure data and examine the value of active and observation well data in resolving model parameters.     

Numerical Calculation of Equivalent Cell Permeability Tensors for General Quadrilateral Control Volumes

A new method for upscaling fine scale permeability fields to general quadrilateral-shaped coarse cells is presented. The procedure, referred to as the conforming scale up method, applies a triangle-based finite element technique, capable of accurately resolving both the coarse cell geometry and the subgrid heterogeneity, to the solution of the local fine scale problem. An appropriate averaging of this solution provides the equivalent permeability tensor for the coarse scale quadrilateral cell. The general level of accuracy of the technique is demonstrated through application to a number of flow problems. The real strength of the conforming scale up method is demonstrated when the method is applied in conjunction with a flow-based gridding technique. In this case, the approach is shown to provide results that are significantly more accurate than those obtained using standard techniques.     

Spectroscopic evidence for pressure-induced phase transitions in diopside

 Raman spectra of diopside were collected from atmospheric pressure to 71 GPa. The pressure dependences of 22 modes were determined. Changes occurred in the spectra at three different pressures. First, at approximately 10 GPa, the two Raman modes at 356 and 875 cm⁻¹ disappeared, while the mode at 324 cm⁻¹ split into two modes, diverging at this pressure with significantly different pressure shifts; second, at approximately 15 GPa, a small (1 to 2 cm⁻¹) drop in several of the frequencies was observed accompanied by changes in the pressure dependency of some of the modes; and third, above 55 GPa, the modes characteristic of chains of tetrahedrally coordinated silicon disappeared, while those for octahedrally coordinated silicon appeared. The first change at 10 GPa appears to be a C2/c to C2/c transition involving a change in the Ca coordination. The third change above 55 GPa appears to be a change in the silicon coordination. At 15 GPa, it is suggested that a change in compressional mechanism takes place. Received: 14 November 2000 / Accepted: 9 January 2002