西藏羌塘盆地侏罗系白云岩储层中油砂资源评价

西藏羌塘盆地是一个烃源岩发育厚度大、分布广的大型中生代海相沉积盆地,构造活动对早期形成的油气藏破坏和改造强烈,为油砂富集成矿提供了条件。通过对盆地中发现的隆鄂尼和昂达尔错两个矿点进行勘察。矿点油砂主要富集于中侏罗统布曲组,分析认为其形成和分布受燕山晚期形成的大型古隆起带的控制,早期形成的古油藏带在后期构造过程中遭受破坏和抬升,使顶部布曲组含油白云岩被抬升剥蚀风化形成现今的油砂矿。采用含油率法对油砂矿带进行了资源量的计算,结果表明两个矿带的油砂地质资源总量为93 099.76×104t。通过类比认为整个盆地油砂资源潜力巨大,可以成为油砂资源主要的勘探地区。     

白云鄂博碳酸岩墙碳氧同位素地球化学

对内蒙古白云鄂博 REE- Fe- Nb矿床周围碳酸岩墙中共存的方解石和白云石进行了 C和 O同位素分析。结果表明，方解石和白云石的δ 13C值变化范围一致，均为－ 3.5‰～－ 7.3‰，落在正常地幔δ 13C值范围 (－ 5‰± 2‰ )内；而它们的δ 18O值可分为两组，第Ⅰ 组为 9.5‰～ 18.0‰，第Ⅱ 组为 20.6‰～ 22.6‰，均远大于正常地幔δ 18O值范围 (5.7‰± 1.0‰ )。第Ⅰ 组低δ 18O值样品中共存白云石与方解石之间的 C和 O同位素分馏均为负值，因此处于热力学不平衡状态，指示它们自形成后受到过后期热液蚀变，与先前的岩石学观察一致。相反，第Ⅱ 组高δ 18O值样品中白云石与方解石之间的 C和 O同位素分馏均为正值，处于热力学平衡状态，指示它们自形成后未受到后期热液蚀变，因此可能沉淀于晚期低温高δ 18O值流体。第Ⅰ 组碳酸岩墙中白云石的 C和 O同位素组成不呈线性分布，指示碳酸岩浆并非由幔源碳酸盐与沉积碳酸盐混合形成。应用水-岩交换模型计算得到，第Ⅰ 组碳酸岩在侵位后经历了碳酸岩浆期后热液的不均一蚀变，蚀变温度约在 220～ 800℃之间，蚀变流体的 CO2/H2O比值较小 (1/500)，但水 /岩比值变化较大 (10～ 400)。由于低温下方解石与热液之间的碳氧同位素交换速率大于白云石，导致这部分碳酸     

Fault-controlled dolomitization at Swan Hills Simonette oil field (Devonian), deep basin west-central Alberta, Canada

The partly dolomitized Swan Hills Formation (Middle‐Upper Devonian) in the Simonette oil field of west‐central Alberta underwent a complex diagenetic history, which occurred in environments ranging from near surface to deep (>2500 m) burial. Five petrographically and geochemically distinct dolomites that include both cementing and replacive varieties post‐date stylolites in limestones (depths >500 m). These include early planar varieties and later saddle dolomites. Fluid inclusion data from saddle dolomite cements (T_h=137–190 °C) suggest that some precipitated at burial temperatures higher than the temperatures indicated by reflectance data (T_peak=160 °C). Thus, at least some dolomitizing fluids were ‘hydrothermal’. Fluorescence microscopy identified three populations of primary hydrocarbon‐bearing fluid inclusions and confirms that saddle dolomitization overlapped with Upper Cretaceous oil migration. The source of early dolomitizing fluids probably was Devonian or Mississippian seawater that was mixed with a more ⁸⁷Sr‐rich fluid. Fabric‐destructive and fabric‐preserving dolostones are over 35 m thick in the Swan Hills buildup and basal platform adjacent to faults, thinning to less than 10 cm thick in the buildup between 5 and 8 km away from the faults. This ‘plume‐like’ geometry suggests that early and late dolomitization events were fault controlled. Late diagenetic fluids were, in part, derived from the crystalline basement or Palaeozoic siliciclastic aquifers, based on ⁸⁷Sr/⁸⁶Sr values up to 0·7370 from saddle dolomite, calcite and sphalerite cements, and ²⁰⁶Pb/²⁰⁴Pb of 22·86 from galena samples. Flow of dolomitizing and mineralizing fluids occurred during burial greater than 500 m, both vertically along reactivated faults and laterally in the buildup along units that retained primary and/or secondary porosity.     

Oxygen and Carbon Isotope Study of Calcite and Dolomite in the Disseminated Au-Ag Telluride Bulawan Deposit, Negros Island, Philippines

Abstract: The disseminated Au‐Ag telluride Bulawan deposit, Negros island, Philippines, is hosted by dacite porphyry breccia pipes which formed in a Middle Miocene dacite porphyry stock. Electrum and Au‐Ag tellurides occur mostly as grains intergrown with or filling voids between sphalerite, pyrite, chalcopyrite, galena and tennantite. Calcite, quartz and rare dolomite are the principal gangue minerals. Four types of alteration were recognized in the deposit, namely; propylitic, K‐feldspar‐sericitic, sericitic and carbonate alteration. Carbonate alteration is correlatable to the gold deposition stage and occurs mostly along fault zones. The δ¹⁸O and δ¹³C compositions of calcite and dolomite in propylite zone and ore‐stage dacite porphyry breccia were determined. The δ¹⁸O values of calcite in propylitized andesite range from +12.2 to +14.7%, and their δ¹³C values range from ‐6.1 to ‐1.0%. The δ¹⁸O values of calcite and dolomite in sericite‐ and carbonate‐altered, mineralized dacite porphyry breccia and dacite porphyry rocks range from +15.1 to +23.1%, and the δ¹³C values of calcite and dolomite range from ‐3.9 to +0.9%. The δ¹⁸O and δ¹³C values of the hydrothermal fluids were estimated from inferred temperatures of formation on the basis of fluid inclusion microthermometry. The δ¹⁸O values of hydrothermal fluid for the propylitic alteration were calculated to be +8.5 ‐ +9.5%, assuming 375°C. On the other hand, the δ¹⁸O values of ore solutions for base metal and Au mineralization were computed to be +13.6 ‐ +14.6%, assuming 270°C. The hydrothermal fluids that formed the Bulawan deposit are dilute and ¹⁸O‐enriched fluids which reacted with ¹⁸O‐ and ¹³C‐rich wallrocks such as limestone.     

地磁场模型和冠谐分析

地磁场是由内源场(地核场和地壳场)和外源场(电离层场和磁层场)组成的,地磁场模型是表示地磁场时空分布的数学表达式.本文简述了地磁场全球模型和区域模型的计算方法和应用;评述了冠谐分析方法及其在地磁学中的应用;介绍了地磁场模型误差的主要来源.     

陕西双王金矿床含铁白云石的某些标型特征

含铁白云石是双王金矿床矿体和围岩中的主要矿物,按其产状可分为四类:Ⅰ.产于层状钠质岩(矿体围岩)中的含铁白云石;Ⅱ.产于含金角砾岩体钠质岩角砾中的含铁白云石;Ⅲ.产于含金角砾岩胶结物中的含铁白云石,Ⅳ.产于近矿蚀变岩石中的含铁白云石。Ⅰ,Ⅱ类为热水沉积成因,Ⅲ和Ⅳ类为热液充填交代产物;它们在化学成分、有序度及碳氧同位素等方面有许多相似之处,但又有一定的差别。研究表明,含金角砾岩胶结物中的含铁白云石主要来自层状钠质岩,为矿床的热水沉积—改造成因提供了新的证据。     

新元古代晚期盖帽碳酸盐岩的成因与“雪球地球”的终结机制

新元古代晚期约635 Ma的地球发育了到达赤道附近的冰川作用，地质记录上表现为代表寒冷气候的冰期沉积杂砾岩，直接被代表温暖环境的碳酸盐岩层（常称盖帽碳酸盐岩）覆盖。由于盖帽碳酸盐岩奇特的岩石学和地球化学特征，引起了对其成因认识的巨大争论，提出了“雪球地球”和“甲烷渗漏”等假说。“雪球地球”假设可以解释一些令人困惑的地学现象，如低纬度和低海拔冰川沉积、盖帽碳酸盐岩、碳酸盐δ13C负漂移和条带状铁矿层等，但许多科学家对此提出了质疑。最近对盖帽碳酸盐岩的δ13C分析结果（最低达-41‰）、盖帽碳酸盐岩发育的类似现代冷泉碳酸盐岩沉积组构等似乎支持“甲烷渗漏”假说。     

新型白云岩珠核的研究

筛选天然白云岩为原料,采用机械磨削和表面处理等工艺,制成新型珠核。这种珠核物化性质与现有贝、蚌壳珠核相近,具有颜色白、光泽强、外形圆和价格低廉等特点。研制和开发新型白云岩珠核,既能保护生物资源和生态环境,又能满足今后珍珠产业发展的需求。     

Flotation Separation of Trace Elements from Alkaline-Earth Matrices by Co(III) Hexamethylenedithiocarbamate before ICP-AES Determination

A method for the selective separation of Ag, Cd, Cr, Cu, Ni, Pb and Zn in traces from solutions of calcite (CaCO₃), dolomite (CaMg(CO₃)₂) and gypsum (CaSO₄.2H₂O) before their determination by inductively coupled plasma-atomic emission spectrometry (ICP-AES) is presented. The expected interferences of Ca and Mg on intensities of trace analytes were removed by collecting the elements of interest with cobalt(III) hexamethylenedithiocar-bamate, Co(HMDTC)₃. The flotation of aqueous solutions (1 l) of calcite, dolomite and gypsum was performed at pH 6.0, by 1.5 mg l⁻¹ Co and 0.6 mmol l⁻¹ HMDTC⁻. To minimise the effect of the reaction between Ca/Mg, which restrains the function of the surfactant, careful selection of the most suitable foaming reagent was necessary. The accuracy of the method was established by analysing natural alkaline-earth minerals by the standard addition method as well as using the dolomite reference materials GBW 07114 and GSJ JDo-1. The ICP-AES limits of detection following flotation on different minerals were found to be 0.080 μg g⁻¹ for Cd, 0.105 μg g⁻¹ for Ag, 0.142 μg g⁻¹ for Cu, 0.195 μg g⁻¹ for Cr, 0.212 μg g⁻¹ for Ni, 0.235 μg g⁻¹ for Zn and 0.450 μg g⁻¹ for Pb.