流动注射HG-AFS法同时测定化探样品中的砷和汞

建立了流动注射HG-AFS测定痕量砷和汞的分析方法。把砷和汞放入20%的王水介质中,它们被硫脲-抗坏血酸预还原,待测量溶液澄清之后,将溶液与硼氢化钾一起导入反应器,产生的氢化物载气导入原子化器中测定,测定结果符合国家标准。本法改进了流动注射HG-AFS法测定砷、汞的分析方法。     

滇黔桂地区汞锑金砷等低温矿床组合碳,氢,氧,硫同位素地球化学

滇黔桂地区分布着众多大中型Hg、Sb、Au矿床。通过对碳、氢、氧、硫等同位素的分析表明：大厂锑矿的硫来自地幔，木利、马雄锑矿的硫主要来自海水硫酸盐。各金矿的硫主要来自围岩，但碳大部分来自围岩。氢氧同位素数据表明，本区锑、金、汞等矿床的成矿流体来源相似，其主要来源为与围岩进行了氢氧同位素交换的大气降水。     

贵州及邻省区与蒸发岩和油气有关的汞矿成矿物理化学条件

对区域汞矿床中辰砂及其共生的脉石矿物的同位素组成和矿物包裹体成分的研究，讨论了所论汞矿成矿的物理化学条件。结合四川、重庆等地现代卤水（黄卤、黑卤）的对比研究和分析，认为黄卤和黑卤是具有成矿潜力的封存热卤水。     

成都地区隐伏构造元素的地球化学特征

通过对成都市多目标地球化学资料的研究，认为深层样的Hg,W,Au,Sc和浅层样的Hg,W,Au,B可以指示隐伏构造，而深层样的指示作用优于浅层样，在深层样反映好的隐伏构造可能与地热发育有关。低温热液、农业有毒元素和油气指示元素指标在隐伏构造上表明明显。在今后多目标地球化学测量中，必需进行深层样的采样。     

SnCl2还原冷原子吸收测定化探样品中的汞

样品经低温稀王水溶解 ,在选定的仪器条件下 ,用氯化亚锡还原 ,测定汞的吸收峰值。方法简便、快速、价廉 ,适用于大批化探样品的测定。     

呼和浩特地区隐伏断层土壤气氡、 汞地球化学特征

根据呼和浩特地区隐伏断层土壤气中氡、 汞的浓度, 探讨了断层的气体地球化学特征及其确定隐伏断层的方法。 在呼和浩特地区8条测线上进行了土壤气中氡、 汞浓度野外现场测量, 共2014个测点。 测量结果表明: 土壤气中氡浓度背景值为2238.7～3715.4 Bq/m³, 土壤气汞浓度背景值为21.1～79.4 ng/m³。 在8个地球化学剖面中有7个在断层带上发现了异常, 其土壤气氡、 汞异常强度一般是背景值的1.7～10.3倍。 根据断层带上土壤气氡、 汞异常特征确定了断层的具体位置。 土壤气氡、 汞测量是隐伏断层探测中非常有效的手段。     

Distribution and speciation of mercury in soil in the area of an ancient mercury ore roasting site,Frbejžene trate (Idrija area,Slovenia)

In the initial period of mining activities in the Idrija basin (the16^th and the first half of the17^th centuries), Hg ore processing was performed at various small-scale roasting sites in the woods surrounding Idrija, by roasting ore in earthen vessels. The recovery rate of this method was very low; about half of Hg was lost, causing soil contamination and considerable amounts of waste material that could potentially leach Hg into the surrounding environment. The main aims of present geochemical study were to determine the contents, vertical distribution and speciation of Hg in soils at the roasting site at Frbej?ene trate in order to verify the extreme pollution of ancient Hg ore roasting sites in the Idrija area and to establish their significance in the wider spatial contamination of soils and aquatic systems. Soil sampling was performed at the area of the former roasting site. The organic matter-rich surface soil layer (SOM) and underlying mineral soil were sampled at 63 sampling locations. Mercury speciation was performed using Hg thermo-desorption-AAS to distinguish cinnabar from potentially bioavailable forms. The results indicate extremely high Hg concentrations with a maximum of 37,000 mg/kg in SOM and 19,900 mg/kg in mineral soil. The established Hg median in soil was 370 mg/kg and in SOM 96.3 mg/kg. Spatial distributions of Hg in SOM and soil showed very high Hg contents in the central area and decreased rapidly with distance. The results of Hg thermo-desorption measurements indicated the presence of cinnabar (HgS) and Hg bound to organic or mineral soil matter. A significant portion (35–40%) of Hg in the investigated soil and SOM samples was comprised of non-cinnabar compounds, which are potentially bioavailable. It has been shown that soils contain high amounts of potentially transformable non-cinnabar Hg, which is available for surface leaching and runoff into the surrounding environment. Therefore, contaminated soils and roasted residues at the studied area are important for persistent Hg release into the aquatic ecosystem.     

云南富源—弥勒1∶5万化探异常的发现及意义

1∶5万水系沉积物测量表明,该区属浅成低温热液型金多金属成矿区,除受构造控制外,岩浆岩、地层亦有控矿作用。金矿主要分布在裂谷带中,成矿潜力巨大,测区西部杨梅山中部支壁找铜金、东南部大得克找铅锌有较好前景。     

基于偏最小二乘法的土壤汞含量高光谱反演

采集新疆准东煤田典型土壤样品44个,在实验室测定风干后的土样汞含量和光谱反射率,经预处理后分析两者的相关性,运用偏最小二乘法(PLSR)建立土壤汞含量高光谱估算模型,由均方根误差RMSE和决定系数R2检验模型的预测能力和稳定性,并比较不同预处理方法的适用性。结果表明:反射率一阶微分光谱是估算土壤汞含量较好的指标,估算R2为0.77、RMSE为0.032。通过各种光谱预处理方法可提高土壤汞含量的估算精度,为研究区生态环境的恢复和评价提供依据。     

微波消解-电感耦合等离子体质谱法测定铁矿石中铬砷镉汞铅

铁矿石中Cr、As、Cd、Hg和Pb不仅影响冶炼设备和产品性能,同时污染环境。文章以铁矿石标准物质为研究对象,对电感耦合等离子体质谱法(ICP-MS)测定铁矿石中Cd、As、Cr、Hg和Pb等5种元素进行了适用性探讨。结果表明,与常规的单元素原子吸收光谱法或多元素同步分析电感耦合等离子体发射光谱法相比,用微波消解方法处理铁矿石,具有样品消耗量少(0.1000±0.0200)g、消解用酸少(2.5 mL HCl+0.5 mL HF+1.0 mL HNO3)、排放降低、节约成本等优点,且无需配制铁底液,无需添加任何掩蔽剂,质谱干扰小,适用于分析Cr含量为5.5×10-10～2.5×10-4,As含量为7.6×10-10～1.9×10-4,Cd含量为4.5×10-11～5.5×10-6,Hg含量为1.88×10-9～1.9×10-7,Pb含量为1.2×10-10～3.2×10-5的铁矿石样品。优化后的前处理方法节约了能源、试剂和样品消耗,降低了二次污染和有效损失。