离子色谱法测定海水中氯离子和硫酸根离子

氯离子和硫酸根离子是海水中重要的无机阴离子，在研究海洋生态变化、海洋循环作用过程与海洋全球气候变化等领域具有重要的指示意义。其测定方法较多，但缺少相应的测试方法。本文对测定海水中Cl^-，SO₄^2-的离子色谱方法进行了优化，选用IonPacAS14碳酸盐选择性离子色谱柱，以3.5 mmol/L Na₂CO₃+1 mmol/L NaHCO₃为流动相，可消除海水样品中碳酸盐及其他阴离子的干扰。该方法对Cl^-检出限为0.29 mg/L，线性相关系数r²=0.999 2，对SO₄^2-检出限为0.42 mg/L，线性相关系数r²=0.997 9。样品的加标回收率在95%~102%，Cl^-和SO₄^2-的相对标准偏差分别为1.92%和4.18%。该方法简便、迅速、灵敏、准确度高，可满足批量海水样品中Cl^-与SO₄^2-的准确测试。     

粤港澳大湾区气溶胶对白天城市热岛强度的影响

以粤港澳大湾区为例,利用卫星遥感资料结合大气化学模式模拟,分析2003―2018年城市热岛强度、气溶胶光学厚度的变化规律,定性和定量研究气溶胶对白天城市热岛强度的影响。结果表明：2003―2018年粤港澳大湾区城市热岛强度呈波动上升趋势,夏季热岛强度最大,冬季热岛强度最小;气溶胶光学厚度呈波动下降趋势,春季气溶胶光学厚度最大,冬季气溶胶光学厚度最小。在年际和季节尺度,城市热岛强度与城区、郊区气溶胶光学厚度之差均呈弱的正相关。基于WRF-Chem的模拟实验表明,气溶胶的存在导致城区、郊区地表向下总辐射减少、地表温度降低,且城区地表向下总辐射减少多于郊区、降温幅度大于郊区,进而导致了热岛强度减弱。气溶胶对城市热岛强度的贡献率为?2.187%,冬季贡献率绝对值略高于夏季。     

塔克拉玛干沙漠腹地塔中地区大气气溶胶散射系数影响因子

利用2010年塔克拉玛干沙漠腹地塔克拉玛干沙漠大气环境观测试验站单波段(525nm)积分浊度计和PM10自动监测仪、能见度仪器观测资料,结合塔中地面气象观测资料,分析影响塔中气溶胶散射系数的各因子。结果表明:(1)散射系数和PM10质量浓度具有明显的正相关关系,相关程度秋季最大,达0.96;夏季次之,为0.94;冬季最小,为0.91。(2)质量散射系数3月最小,10月最大;四季中,春季最小,为0.60m2·g-1,秋季最大,为1.38m2·g-1。塔中站气溶胶质量散射系数小于河北张北站、甘肃民勤站、兰州西固区,大于内蒙古锡林浩特站、希腊克里特岛、以色列内盖夫沙漠。(3)能见度与散射系数呈显著负幂相关关系,相关系数为0.80,其中夏、秋、冬季的相关系数都超过了年相关系数,分别是0.913、0.908、和0.857,春季最低为0.723。(4)风速较大时,散射系数的值也比较大,两者呈现正相关关系,相关系数为0.45。散射系数小于500 Mm-1时,主要分布于ENE和NE;大于500Mm^-1以上则主要是在ENE、NE、E风向。在ESE风向时,散射系数的平均值最大,其次是SSE方向上,最小值是S风向。     

Improvement of a Snow Albedo Parameterization in the Snow–Atmosphere–Soil Transfer Model:Evaluation of Impacts of Aerosol on Seasonal Snow Cover

The presence of light-absorbing aerosols(LAA) in snow profoundly influence the surface energy balance and water budget.However,most snow-process schemes in land-surface and climate models currently do not take this into consideration.To better represent the snow process and to evaluate the impacts of LAA on snow,this study presents an improved snow albedo parameterization in the Snow–Atmosphere–Soil Transfer(SAST) model,which includes the impacts of LAA on snow.Specifically,the Snow,Ice and Aerosol Radiation(SNICAR) model is incorporated into the SAST model with an LAA mass stratigraphy scheme.The new coupled model is validated against in-situ measurements at the Swamp Angel Study Plot(SASP),Colorado,USA.Results show that the snow albedo and snow depth are better reproduced than those in the original SAST,particularly during the period of snow ablation.Furthermore,the impacts of LAA on snow are estimated in the coupled model through case comparisons of the snowpack,with or without LAA.The LAA particles directly absorb extra solar radiation,which accelerates the growth rate of the snow grain size.Meanwhile,these larger snow particles favor more radiative absorption.The average total radiative forcing of the LAA at the SASP is 47.5Wm~(-2).This extra radiative absorption enhances the snowmelt rate.As a result,the peak runoff time and "snow all gone" day have shifted 18 and 19.5 days earlier,respectively,which could further impose substantial impacts on the hydrologic cycle and atmospheric processes.     

Geochemistry of Flooded Underground Mine Workings Influenced by Bacterial Sulfate Reduction

Unlike the majority of the water in the flooded mine complex of Butte Montana, which includes the highly acidic Berkeley pit lake, groundwater in the flooded West Camp underground mine workings has a circum-neutral pH and contains at least 8 μM aqueous sulfide. This article examines the geochemistry and stable isotope composition of this unusual H₂S-rich mine water, and also discusses problems related to the colorimetric analysis of sulfide in waters that contain FeS_(aq) cluster compounds. The West Camp mine pool is maintained at a constant elevation by continuous pumping, with discharge water that contains elevated Mn (90 μM), Fe (16 μM), and As (1.3 μM) but otherwise low metal concentrations. Dissolved inorganic carbon in the mine water is in chemical and isotopic equilibrium with rhodochrosite in the mineralized veins. The mine water is under-saturated with mackinawite and amorphous FeS, but is supersaturated with Cu- and Zn-sulfides. However, voltammetry studies show that much of the dissolved sulfide and ferrous iron are present as FeS_(aq) cluster molecules: as a result, the free concentration of the West Camp water is poorly constrained. Concentrations of dissolved sulfide determined by colorimetry were lower than gravimetric assays obtained by AgNO₃ addition, implying that the FeS_(aq) clusters are not completely extracted by the Methylene Blue reagent. In contrast, the clusters are quantitatively extracted as Ag₂S after addition of AgNO₃. Isotopic analysis of co-existing aqueous sulfide and sulfate confirms that the sulfide was produced by sulfate-reducing bacteria (SRB). The H₂S-rich mine water is not confined to the immediate vicinity of the extraction well, but is also present in flooded mine shafts up to 3 km away, and in samples bailed from mine shafts at depths up to 300 m below static water level. This illustrates that SRB are well established throughout the southwestern portion of the extensive (>15 km³) Butte flooded mine complex.     

硫酸盐渍土含水率单次递减条件下的盐胀特性

为探究硫酸盐渍土在含水率递减下的盐胀特性,通过自主设计的试验装置,在室内开展了11组含水率单次递减下的盐胀试验,共历时2 868 h。结果表明：在含水率单次递减下硫酸盐渍土的起胀含盐量约为1.2%。含盐量<1.2%时,土体干缩,干缩量与含盐量近似呈下凸的二次抛物线规律,且干缩峰值含盐量约为0.5%;含盐量≥1.2%时,土体膨胀,且盐胀率与含盐量近似呈线性增大规律。盐胀敏感含水率区间受含盐量影响很小,含盐量从1.5%增至4.0%,盐胀敏感含水率区间基本稳定。此外,含水率递减速率与含盐量呈负相关规律,同一含盐量的硫酸盐渍土,其含水率的递减速率随含水率的降低亦减慢。基于以上试验结果,进一步开展了4组单次降温下的盐胀对比试验,结果表明：含盐量升高时,起胀温度区间逐渐升高,盐胀敏感温度区间的区间范围逐渐扩大。单次降温下的盐胀率均高于含水率单次递减下的盐胀率,且随着含盐量的升高两试验条件下的盐胀率差值趋于一常数。研究结果对西北地区高含盐量的残余型硫酸盐渍土地基的盐胀性评价具有重要指导意义。     

Diagenesis and Restructuring Mechanism of Oil and Gas Reservoir in the Marine Carbonate Formation,Northeastern Sichuan:A Case Study of the Puguang Gas Reservoir

Abstract: Based on the technology of balanced cross-section and physical simulation experiments associated with natural gas geochemical characteristic analyses, core and thin section observations, it has been proven that the Puguang gas reservoir has experienced two periods of diagenesis and restructuring since the Late Indo-Chinese epoch. One is the fluid transfer controlled by the tectonic movement and the other is geochemical reconstruction controlled by thermochemical sulfate reduction (TSR). The middle Yanshan epoch was the main period that the Puguang gas reservoir experienced the geochemical reaction of TSR. TSR can recreate the fluid in the gas reservoir, which makes the gas drying index higher and carbon isotope heavier because C2+ (ethane and heavy hydrocarbon) and 12C (carbon 12 isotope) is first consumed relative to CH4 and 13C? (carbon 13 isotope). However, the reciprocity between fluid regarding TSR (hydrocarbon, sulfureted hydrogen (H2S)?, and water) and reservoir rock results in reservoir rock erosion and anhydrite alteration, which increases porosity in reservoir, thereby improving the petrophysical properties. Superimposed by later tectonic movement, the fluid in Puguang reservoir has twice experienced adjustment, one in the late Yanshan epoch to the early Himalayan epoch and the other time in late Himalayan epoch, after which Puguang gas reservoir is finally developed.     

东亚地区春季二氧化硫的输送与转化过程研究I.模式及其验证

结合新近评估的东亚地区污染源资料,作者利用一个耦合的区域化学输送模式系统以探讨东亚地区春季期间气象过程、气相与液相化学过程、非均相化学过程、气溶胶过程和干湿沉降过程对二氧化硫输送及转化过程的影响,并研究二氧化硫和硫酸盐气溶胶的空间分布及变化特征.模拟的二氧化硫和硫酸盐气溶胶的浓度值与2001年春季飞机和地面获取的观测值进行了比较.比较结果显示,模拟值与观测值具有很好的一致性,模式系统很好地反映了二氧化硫和硫酸盐气溶胶的分布特征和变化规律,再现了许多观测到的重要特征,为进一步分析模拟结果奠定了基础.     

复合体系有机气体氧化生成二次有机气溶胶研究进展

生物源与人为源有机气体氧化形成的二次有机气溶胶(SOA)对气候变化和人类健康具有重要影响。SOA的产生与其前体物研究已取得了一些进展,但由于有机气体之间存在复合相互作用以及SOA形成机制复杂,目前对不同有机气体混合体系中SOA的形成认知还比较匮乏。因此,深入了解有机气体多源、复杂的相互作用,摸清有机气体的大气氧化机制、SOA的形成及影响等对深入理解真实大气有机气体化学演变具有指导意义。本文旨在了解复合体系有机气体氧化生成SOA的相关研究进展。一方面总结了复合体系有机气体产生SOA质量浓度、产率、成分、挥发性、光学性质等的变化,侧重于实验室复合体系有机气体氧化对SOA形成的多重影响以及SOA组成元素、分子构成的变化特征,并总结了目前实验室基于模型对复合体系SOA生成的模拟研究和拟合情况;另一方面探究了环境因素,如相对湿度(RH)、温度(T)以及无机气体,如氮氧化物(NO_x)、二氧化硫(SO₂)、氨气(NH₃)等对复合体系有机气体形成SOA的影响。     

X射线荧光光谱法测定重晶石中的硫酸钡方法研究

应用XRF可快速测定重晶石中钡元素的总量,但当测定硫酸钡含量时,由于样品中的碳酸钡计入钡量造成硫酸钡的测定结果不准确,铜、铅、锌等有色金属元素对熔样坩埚会造成损害,需要进行酸处理除去碳酸钡、铅等干扰。而样品经酸处理后不同样品的剩余量不同,造成熔剂与样品的比例不确定,也不能准确测定硫酸钡的含量,因此保证熔剂与样品比例一致是解决该问题的关键。本文优化了样品前处理、熔片制样和仪器工作条件,将一定量样品以10%盐酸和10%硝酸溶解,过滤除去碳酸钡、硫酸钙及铜、铅、锌等有色金属元素,未溶解样品在700℃下灼烧后以氧化铝补充到原取样量,实现了熔剂与样品比例一致,再以硝酸铵作氧化剂,溴化锂和碘化铵作脱模剂,1075℃熔融制片,即可用XRF准确测定硫酸钡的含量。本方法的相对标准偏差(RSD)小于0.4%,检出限为72μg/g,较ICP-OES等方法的检测周期短、干扰元素少,提高了测试效率和分析质量。