寒武系古流体地球化学特征及其对页岩气保存的指示意义 ——以中扬子地区寒武系页岩气发现井宜地2井为例

保存条件是中扬子地区页岩气富集的关键因素之一，宜地2井是中扬子寒武系页岩气发现井，通过对该井全井段岩芯裂缝古流体的地球化学分析，探讨了寒武系古流体成因和对水井沱组页岩气保存条件的指示意义。结果认为：① 覃家庙组膏岩层之上方解石脉缺少Fe2+、Mn2+，且δ13C和δ18O值较围岩偏负，指示其形成于氧化的环境，石牌组方解石脉δ13C偏负，黄铁矿脉δ34S值与膏盐相似，表明其成因与TSR密切相关；水井沱组脉体δ13C和δ18O与围岩相似，形成于封闭的环境。② 方解石脉包裹体群SO42-、Ca2+、Mg2+含量整体上由覃家庙组向上向下分别递减，钠氯系数以水井沱组最低，整体上向上升高，表明覃家庙组是高盐度卤水的主要来源，水井沱组受外来流体影响弱；包裹体水溶液δD和δ18O也指示娄山关组、石牌组方解石脉成因分别与大气水、TSR相关。③ 古流体地球化学研究表明宜昌地区页岩气保存条件整体较好，页岩气散失的主要通道是垂直裂缝，页岩气保存条件好与膏盐盖层发育、后期构造破坏弱、脉体对裂缝的及时封闭以及白垩系盖层等因素密切相关。     

EAR70、CLDAS和ERA Interim表层土壤温度在中国地区的评估

本文利用2010—2015年2400多国家气象站逐小时观测数据对覆盖中国的EAR70、CLDAS和ERA Interim 3种表层土壤温度进行了评估和对比。结果表明：空间上CLDAS表层土壤温度精度最高（平均误差为-0.5 ℃，均方根误差为3.0 ℃，相关系数为0.96），受益于CLDAS高精度的陆面初始场，EAR70平均误差得到了改善；时间上ERA Interim再分析表层土壤温度在6:00和夏、秋季精度会明显下降，再分析表层土壤温度在数值较高时段表现出冷偏差，原因是模拟的土壤温度数值上升速度慢，对应的参数化方案有待改进。再分析表层土壤温度在东北地区冬季存在冷偏差，可能和积雪覆盖有关，陆面参数化方案也有待提高。在地形复杂的青藏高原地区，融合地面观测的CLDAS提高了大气驱动的质量进而改进了土壤的模拟。ERA Interim分辨率较粗不适合在青藏高原或者沿海地区使用，结合了CLDAS的EAR70在青藏高原精度提高。土壤表层温度的精度随着高精度的土壤状态初始场进入模式中时间延长会显著下降。因此，CLDAS的实时同化方式，能够有效提高在分析数据的精度。     

A combined study of macroseismic data and focal mechanisms applied to the West-Bohemian earthquake,Czechoslovakia

The main shock of the West-Bohemian earthquake swarm, Czechoslovakia, (magnitudem=4.5, depthh=10 km) exhibits an irregular areal distribution of macroseismic intensities 6° to 7° MSK-64. Four lobes of the 6° isoseismal are found and the maximum observed intensity is located at a distance of 8 km from the instrumentally determined epicentre. This distribution can be explained by the energy flux of the directS wave generated by a circular source, the hypocentral location and focal mechanism of which are taken from independent instrumental studies. The theoretical intensity, which is assumed to be logarithmically proportional to the integrated squared ground-motion velocity (i.e.,I=const+log v ² (t)dt), fits the observed intensity with an overall root-mean-square error less than 0.5°. It is important that the present intensity data can also be equally well explained by the isotropic source. The fit was attained by means of a horizontally layered model though large fault zones and an extended sedimentary basin suggest a significant lateral heterogeneity of the epicentral region. The results encourage a broader application of the simple modelling technique used.     

Enhancement of radon signals in geophysical studies with the track technique

The existence of a suspected geological fault has been confirmed using Solid State Nuclear Track Detectors (SSNTDs) by measuring radon concentration variations in the upper soil above its inferred position. The results obtained prompted us to increase the natural radon signal in the soil, using an additional radon source; this enhancement technique, has been experimentally checked with SSNTD detectors.On leave from Faculté des Sciences, Laboratoire des D.S.T.N. Université de Dakar, Dakar-Fann, Sénégal     

Seasonal variation of atmospheric dimethylsulfide at Amsterdam Island in the southern Indian Ocean

Daily measurements of atmospheric concentrations of dimethylsulfide (DMS) were carried out for two years in a marine site at remote area: the Amsterdam Island (37°50S–77°31E) located in the southern Indian Ocean. DMS concentrations were also measured in seawater. A seasonal variation is observed for both DMS in the atmosphere and in the sea-surface. The monthly averages of DMS concentrations in the surface coastal seawater and in the atmosphere ranged, respectively, from 0.3 to 2.0 nmol l^-1 and from 1.4 to 11.3 nmol m^-3 (34 to 274 pptv), with the highest values in summer. The monthly variation of sea-to-air flux of DMS from the southern Indian Ocean ranges from 0.7 to 4.4 mol m^-2 d^-1. A factor of 2.3 is observed between summer and winter with mean DMS fluxes of 3.0 and 1.3 mol m^-2 d^-1, respectively.     

大理州2005年初夏干旱成因探析

大理州2005年初夏出现了严重干旱气象事件.从500pHa高空环流特征、500pHa距平场特征、西太平洋副高特征量及北太平洋中低纬海温距平场、OLR距平场对这次干旱的成因进行了分析,分析结果表明：2005年初夏（4月1日～6月10日）降水异常偏少气温明显偏高是发生干旱的主要原因,高空大气环流异常、西太平洋副高持续偏强偏西、冷空气活动偏北是导致干旱的直接原因;孟加拉湾南部4月OLR场呈明显正距平,抑制低值系统的发展和东北移影响云南,是影响2005年大理初夏干旱重要原因;北太平洋中低纬海温特征与大理州初夏干旱有一定的遥相关性.     

论四川盆地三叠系地下水水文地质条件

四川盆地三叠系地下水可划分出碎屑岩孔隙裂隙和碳酸盐岩岩溶裂隙两大储集类型。按此处构造开启程度和埋深条件等的不同,下中三叠统地下水有沉积变质水和渗入淋滤水两种基本成因类型,水动力特征各异。沉积变质水处于深埋封闭条件,受地静压力驱动控制;渗入淋滤水分布于背斜露头区和浅部地区,受静水压力驱动控制。并由此控制了盆地三叠系盐类的保存条件。     

The petroleum generation potential and effective oil window of humic coals related to coal composition and age

A worldwide data set of more than 500 humic coals from the major coal-forming geological periods has been used to analyse the evolution in the remaining (Hydrogen Index, HI) and total (Quality Index, QI) generation potentials with increasing thermal maturity and the ‘effective oil window’ (‘oil expulsion window’). All samples describe HI and QI bands that are broad at low maturities and that gradually narrow with increasing maturity. The oil generation potential is completely exhausted at a vitrinite reflectance of 2.0–2.2%R_o or T_max of 500–510 °C. The initial large variation in the generation potential is related to the original depositional conditions, particularly the degree of marine influence and the formation of hydrogen-enriched vitrinite, as suggested by increased sulphur and hydrogen contents. During initial thermal maturation the HI increases to a maximum value, HI_max. Similarly, QI increases to a maximum value, QI_max. This increase in HI and QI is related to the formation of an additional generation potential in the coal structure. The decline in QI with further maturation is indicating onset of initial oil expulsion, which precedes efficient expulsion. Liquid petroleum generation from humic coals is thus a complex, three-phase process: (i) onset of petroleum generation, (ii) petroleum build-up in the coal, and (iii) initial oil expulsion followed by efficient oil expulsion (corresponding to the effective oil window). Efficient oil expulsion is indicated by a decline in the Bitumen Index (BI) when plotted against vitrinite reflectance or T_max. This means that in humic coals the vitrinite reflectance or T_max values at which onset of petroleum generation occurs cannot be used to establish the start of the effective oil window. The start of the effective oil window occurs within the vitrinite reflectance range 0.85–1.05%R_o or T_max range 440–455 °C and the oil window extends to 1.5–2.0%R_o or 470–510 °C. For general use, an effective oil window is proposed to occur from 0.85 to 1.7%R_o or from 440 to 490 °C. Specific ranges for HI_max and the effective oil window can be defined for Cenozoic, Jurassic, Permian, and Carboniferous coals. Cenozoic coals reach the highest HI_max values (220–370 mg HC/g TOC), and for the most oil-prone Cenozoic coals the effective oil window may possibly range from 0.65 to 2.0%R_o or 430 to 510 °C. In contrast, the most oil-prone Jurassic, Permian and Carboniferous coals reach the expulsion threshold at a vitrinite reflectance of 0.85–0.9%R_o or T_max of 440–445 °C.     

Fe and Mn in calcites cementing red beds: A record of oxidation–reduction conditions: Examples from the Catalan Coastal Ranges (NE Spain)

Fe and Mn occur in calcite cements depending on the oxidizing–reducing conditions of cementing waters, which may change according to depositional and diagenetic environments. In red beds, Mn and Fe are available from the ferruginous matrix. Thus, it is possible to know the oxidizing–reducing conditions of fluids that precipitated calcite as a function of Mn and Fe content in calcite cement. A detailed petrological (with special attention to cathodoluminescence) and geochemical analysis of these cements is a useful tool to constrain the diagenetic evolution of red beds and the history of the basin where they deposited.     

Rodent paleofaunas as indicators of climatic change in Europe during the last 125,000 years

This paper presents a quantitative reconstruction of the European late Pleistocene paleoclimate based on 72 rodent assemblages of five sequences from France, Germany and Bulgaria, covering the last interglacial-glacial cycle. They show a pattern of severe changes in temperature, with reduced precipitation during the coldest periods. A tentative correlation between the isotopic and palynological records and the paleotemperature changes is shown. These changes are consistent with variations in atmospheric circulation patterns in response to an expanding-retracting Fennoscandian ice-sheet. They can be attributed to the enhancement-weakening of the Scandinavian-Polar anticyclone and its associated dry winds, the south-north shifting of the North Atlantic Polar Front, and the varying supply of moist air from the Atlantic. Qualitative paleoenvironmental analysis shows broadleaved-deciduous forests in France and Bulgaria during most of the studied period. Taiga and tundra appeared in eastern France during the lower Würm. The German sequence indicates the presence of coniferous forests. These results are broadly consistent with other paleobiological records (mammalian, avian and insect faunas, isotopic record in dental tissue, palynology). The main discrepancies with the paleoclimate inferred from the palynological record are found during the coldest periods and are probably due to the interaction between vegetation, climate, and atmospheric CO₂ levels.