Calculating Pollution Indices by Heavy Metals in Ecological Geochemistry Assessment and a Case Study in Parks of Beijing

Pollution index is a powerful tool for ecological geochemistry assessment. The commonly used pollution indices by heavy metals in soils and sediments were classified as two types of single index and integrated index in an algorithm point of view. Four single indices of contamination factor (or concentration factor), ecological risk factor, enrichment factor, and index of geo-accumulation were illustrated, and the reference values for calculating single indices were distinguished into background levels and threshold pollution values. Eight integrated indices were divided into two groups. One group is suitable for the normal distribution single indices including the sum, average, weighted average,vector modulus, and Nemerow pollution indices, and the other for log-normal distribution including the product, root of product, and weighted power product pollution indices. Using background levels as reference values, five contamination classes were divided, and the terminologies are suggested for the single and integrated indices to unify the assessment results. Software of EGAPI was developed in a single document interface to calculate the four single and eight integrated indices by heavy metals to assess the quality of soil and sediment ecological geochemistry. Pollution indices by heavy metals of Cu,Pb, and Zn in soils in parks of Beijing were calculated using EGAPI software, and these five contamination classes and terminologies suggested in this study were evaluated and used. Results ofintegrated indices of Cu, Pb, and Zn in soils indicated that the soil qualities are unpolluted as a whole and varied from low polluted to unpolluted status from the center to the outskirts of Beijing City.     

山西临汾盆地黄土剖面重金属分布特征及其影响因素

山西临汾盆地2条黄土剖面重金属分布特征及其影响因素研究表明,Pb、Cu和Zn的垂向变化特征非常相似,而As、Cd和Hg在剖面中的分布特征与前三者不同。各重金属元素在黄土剖面中的变化特征首先均受到黄土源区物质成分的控制,其次不同程度地受到古气候变化的影响。依据Pb、Cu、Zn与各古气候替代性指标(例如磁化率,w(SiO2)/w(Al2O3)等)均呈显著相关,As、Cd和Hg与古气候替代性指标的相关性较差,推断剖面中Cu、Pb、Zn的分布特征受古气候变化的影响,其原因可能主要是这3个金属元素易以类质同象形式赋存在磁性矿物中;而As、Cd和Hg在剖面中的分布特征与古气候无关。但各重金属元素与源区指示元素的相关性表明其在剖面中的分布特征均受黄土源区物质成分的影响和控制。     

国内外城市雨水径流水质的研究

综合国内外综合资料,对城市不同建筑材料屋面和不同路面的雨水径流水质特征进行了对比分析,阐明了影响城市雨水径流水质的三大因素,并论述了城市雨水收集利用的现实意义。     

Study on rain-runoff process in the peripheral mountainous area of the Sichuan Basin

Studies on rain-runoff process in the peripheral mountainous area of the Sichuan Basin, which is regarded as a key ecological shelter, will contribute to flood control and environmental protection for the Upper Yangtze River Basin. In two typical catchments--the Fujiang River Catchment and the Wujiang River Catchment, rainfall simulations have been conducted to study the rain-runoff processes of yellow soil and limestone soil in three types of land use--forestland, farmland and grassland. Results showed that （1） within the same rainfall process, overland flow occurs first on farmland, then on grassland, and finally on forestland; （2） soil surface coverage has a great impact on the occurrence and amount of overland flow. The runoff amount can increase 2-4 times after the coverage is removed; （3） the infiltration before the occurrence of overland flow will decrease because of higher gravel contents of soil, but it takes no effect on infiltration once overland flow becomes stable; （4） the runoff coefficient of the limestone soil forestland is greater than that of the yellow soil forest land, but less than that of the farmland; （5） three empirical infiltration models, including Horton＇ model, Kostiakov＇ model, and modified Kostiakov＇ model, were compared by using the observed results under rainfall simulation. The results showed that the Kostiakov＇ model performed better than both the Horton＇ model and modified Kostiakov model. According to the results of this research, the Kostiakov＇s model can be used to simulate rainfall infiltration when water erosion is modeled in the peripheral mountainous area of the Sichuan Basin.     

Study on the connectivity of heavy oil reservoirs by ultraviolet spectrum technique in the western part of the QHD32-6 oilfield

As a new method, the ultraviolet spectrum technique is applied to studying the connectivity of biode-gradable heavy oil reservoirs. The similarity of crude oils can be judged according to the extinction coefficient （E） because aromatic hydrocarbons and non-hydrocarbons have conjugated bonds and obvious absorption in the ultraviolet range, and different materials have different characteristics and additives. The relationship diagram is made in terms of the extinction coefficients （E） of the samples by taking E as the Y-axis and wavelength as the X-axis. The connectivity of oil reservoirs is estimated according to the curve positions and characteristic fingerprints of the sampies. The connectivity of part of the reservoirs in the western part of the QHD32-6 oilfield was studied with this method. The results showed that the connectivity of samples from wells F7 and F8 in the Nm-2 oil reservoir zone is good, that of samples from wells F17 and F20 in the Nm-1 oil reservoir zone also is good, and that of samples from wells F17, F19, and F20 is poor.     

太湖流域土壤重金属元素污染历史的重建:以Pb、Cd为例

太湖是位于长江下游的一个大型浅水湖泊,通过对4个代表太湖不同沉积环境的湖底沉积剖面的137Cs和210Pb沉积定年,重建太湖湖底沉积物和太湖来水流域土壤Cd、Pb的污染历史。结果显示:1980年以前,太湖底积物中Cd、Pb含量与流域内的自然背景含量相当,1980年以后,湖底沉积物中的Cd、Pb含量显著增高,这与我国大规模工业化进程的起始时间基本一致,推测工业化进程是湖底沉积物中Cd、Pb含量增加的主要原因。1900年以来太湖湖底沉积物中累积含有Cd和Pb分别为146t和25980t,其中苕溪来水提供的Cd和Pb分别为40t、6777t,宜溧河来水提供的Cd、Pb分别为36t、6023t,其他来水(洮、滆、运河)提供的Cd、Pb分别为71t、13179t,其他来水是太湖Cd、Pd累积的主要输入途径。Cd、Pb累积的高峰期为20世纪80—90年代,1980年以来,运河来水Cd、Pb的输出通量为28.26t、3419t;苕溪流域Cd、Pb的输出总量分别为13.70t、1585t,其中人为源的Cd、Pb为8.90t、610t,人为源输出的Cd、Pb通量占总输出量的64.96%和38.47%;宜溧河流域Cd、Pb的输出总量分别为10.09t、1063t,人为源的Cd、Pb分别6.96t和500t,人为源输出的Cd、Pb通量占总输出量的68.68%和47.08%,表明太湖流域人类活动所导致的Cd已超过自然剥蚀过程,因此削减工业化进程中的Cd、Pb排放总量,控制太湖运河来水的输出通量是改善太湖底积物Cd、Pb环境质量的关键措施。     

黑色页岩与土壤重金属污染

本文利用ICP—MS等技术分析了湘中地区黑色页岩及其相应土壤的重金属含量,在对分析结果进行统计分析的基础上,探讨了黑色页岩与土壤重金属污染的关系。研究表明,黑色页岩是富集多种重金属元素的特殊岩石。以黑色页岩岩系为母岩的土壤,不仅明显富集Cu、Cd、Cr、Co、Pb、Zn、Mo、Ni、V、U、Sn、Sb、T1、Th等多种重金属元素,而且受到Mo、Sb、Cd、U、Tl、Cu、V、Sn、Th等重金属的污染,其中以Mo、Cd、Sb、U、Tl等的污染尤为严重。黑色页岩土壤重金属污染在一些地方已产生明显的负面环境效应,值得关注。     

重液材料多钨酸钠在青海湖沉积物重力分离中的应用

多钨酸钠是一种无毒、易配制、可循环使用、密度高的新型无机重液.本文利用多钨酸钠重液,用离心机重力分离的方法将青海湖沉积物分成低(≤1.9g/cm3)、中(1.2-2.8g/cm3)、高(≥2.8g/cm3)三个密度组分,平均回收率为96.5%.重力分离后的沉积物测试分析发现,有机质主要分布在富粘土矿物的中密度组,揭示了粘土矿物的表面吸附是青海湖底沉积物有机质的主要赋存形式.     

内蒙古敖包吐萤石矿床地质和地球化学特征

笔者总结了敖包吐萤石矿床的地质特征,并通过萤石的稀土元素的地球化学和Nd同位素研究,探讨了该矿床的成矿作用和成矿物质来源。敖包吐萤石矿床产出于下二叠统大石寨组火山—沉积岩与燕山中期花岗岩的接触带,为单一萤石矿床。萤石矿石的稀土元素的含量(∑REE)变化范围为(8.04～30.04)×10-6,平均为19.42×10-6;轻重稀土LREE/HREE值0.24～0.65,平均0.52;LaN/YbN为0.07～0.62,平均0.26;δEu为0.42～0.90,平均0.60,具Eu负异常和明显重稀土富集的特征。岩矿石的Nd同位素研究表明,萤石矿石的εNd(t)都表现为很大的负值,以成矿主期年龄138Ma计算的εNd(138Ma)为-7.30～-30.55,具有古陆壳的演化特征,暗示其成矿的物质来源主要是壳源物质。在Moller的Tb/La-Tb/Ca成因判别图解中,敖包吐矿床的萤石的结晶作用表现为重新活化的趋势,反映流体具有混源的特征,既有热液成因,又有沉积成因。二叠世的海相火山活动通过海底喷气和喷流的作用形成了初始矿源层,而燕山中期花岗岩浆的侵位与结晶分异,又对初始矿源层的活化和富集提供了流体和热能的来源。成矿流体在经历了长期的演化后在大石寨组的构造薄弱破碎的的部位沉淀析出,形成敖包吐萤石矿床。     

江西德兴矿集区水系沉积物重金属污染的时空对比

对比研究矿山开采一定时段内区域环境污染的时空变化特征,对于动态监测矿山开采对区域环境质量的影响情况、污染趋势等,具有重要的科学意义和实际价值。本文在利用2004年野外采集与测试分析的330个水系沉积物样品重金属含量数据基础上,充分利用矿山开采早期(1989)的1:20万乐平幅(As、Hg、Cd、Cr、Zn、Cu、Pb)水系沉积物地球化学图,通过数据预处理,分别对样品采集点重金属元素含量的统计分析和地质累积指数法评价的基础上,采用GIS的三维空间分析功能,对比研究德兴地区水系沉积物重金属污染时空变化。研究结果表明,十几年来,矿山开采对区域水系沉积物已造成了严重的污染,主要集中分布在是德兴铅锌和铜钼矿区德兴河与大坞河流域及其周边地区、乐安河下游沿岸局部地区、西北煤矿区以及乐安河下游乐平附近的煤矿区。