Granite is an Effective Helium Source Rock: Insights from the Helium Generation and Release Characteristics in Granites from the North Qinling Orogen,China

Global helium(He) shortage is a challenging problem; however, the types of helium source rock and the mechanisms of He generation and release therein remain still poorly understood. In this study, in order to evaluate the potential of granite as an effective helium source rock, we collected granitic samples from the North Qinling Orogen, Central China, in the south of the helium-rich Weihe Basin. The helium generation and release behaviors in granite were studied through analysis of U and Th concentrations, EMPA images, and He and Ar concentrations and isotopic ratios extracted by crushing and stepwise heating. The results indicate that Ar has a better retention and a lower mobility than He. 3 He/4 He ratios released by crushing and stepwise heating are 0.016–0.056 RA and 0.003–0.572 RA, respectively, where RA is the atmospheric 3 He/4 He of 1.4×10-6, reflecting a crustal and radiogenic source. Helium concentrations extracted by the two ways are 0.13–0.95 ucm3 STP/g and 7.82–115.62 ucm3 STP/g, respectively, suggesting that matrix-sited He accounts for more than 98% of total helium preserved in granite. In addition, the total generated He amounts in granites are calculated based on the measured U and Th concentrations in granitic samples. Dividing the preserved He quantities by the generated He amounts, it turned out that less than 10% of He produced since the formation of the granite is preserved in the rock over geological time, suggesting that more than 90% generated He can be transferred to the Weihe Basin. Temperature and fracture are the two critical factors controlling He release. Based on the relationship between He diffusivity of granites and temperature and the He closure temperatures of a variety of U-and Th-rich minerals(27–250°C), we estimate that He can be partially released out of granite at the depths 400 m and totally released at the depths 7800 m. Fractures provide effective transfer of free He from deep source rocks to shallow reservoirs. Finally, a model on granite as an effective helium source rock is established. We suggest exploring He resources in hydrocarbon basins with granitic basement(or adjacent to granite bodies), high geothermal field, and young active fractures.     

Coupled thermo-hydro-mechanical modelling of bentonite buffer material

Mechanistic model development and numerical analyses were carried out on coupled thermo-hydraulic-mechanical processes in bentonite-based buffer material for the geological disposal of high-level radioactive waste with small-scale laboratory experiments and a full-scale test. The mechanism of water movement in compacted bentonite was identified by applying theoretical equations to the experimental results. The application clearly explained the observed results of the temperature dependence of the hydraulic conductivity in the saturated state and the water diffusivity in the unsaturated state for the compacted bentonite and the dry density dependence of the diffusivity. The full-scale coupled test, BIG-BEN, was conducted at PNC (Power Reactor and Nuclear Fuel Development Corporation) Tokai Works. The results of the numerical analyses for the full-scale test which are based on the present knowledge of coupled processes and our small-scale experiments were in good agreement with the measured results except for mechanical phenomena. Copyright © 1999 John Wiley & Sons, Ltd.     

Nonlinear oscillations of semigeostrophic Eady waves in the presence of diffusivity

Analyses are performed to examine the physical processes involved in nonlinear oscillations of Eady baxoclinic waves obtained from viscous semigeostrophic models with two types of boundary conditions (free-slip and non-slip). By comparing with previous studies for the case of the free-slip boundary condition, it is shown that the nonlinear oscillations are produced mainly by the interaction between the baroclinic wave and zonal-mean state (total zonal-mean flow velocity and buoyancy stratification) but the timescale of the nonlinear oscillations is largely controlled by the diffusivity. When the boundary condition is non-slip, the nonlinear oscillations are further damped and slowed by the diffusive process. Since the free-slip (non-slip) boundary condition is the zero drag (infinite drag) limit of the more realistic drag boundary condition,the nonlinear oscillations obtained with the two types of boundary conditions are two extremes for more realistic nonlinear oscillations.     

Concentration profiles for fine and coarse sediments suspended by waves over ripples: An analytical study with the 1-DV gradient diffusion model

Field and laboratory measurements of suspended sediments over wave ripples show, for time-averaged concentration profiles in semi-log plots, a contrast between upward convex profiles for fine sand and upward concave profiles for coarse sand. Careful examination of experimental data for coarse sand shows a near-bed upward convex profile beneath the main upward concave profile. Available models fail to predict these two profiles for coarse sediments. The 1-DV gradient diffusion model predicts the main upward concave profile for coarse sediments thanks to a suitable β(y)$\beta (y)$-function (where β$\beta$ is the inverse of the turbulent Schmidt number and y   is the distance from the bed). In order to predict the near-bed upward convex profile, an additional parameter α$\alpha$ is needed. This parameter could be related to settling velocity (α$\alpha$ equal to inverse of dimensionless settling velocity) or to convective sediment entrainment process. The profiles are interpreted by a relation between second derivative of the logarithm of concentration and derivative of the product between sediment diffusivity and α$\alpha$.     

溶质类型与矿化度对土壤水分扩散率的影响

以甘肃省秦安县果园石灰性土壤为研究对象,采用水平土柱入渗法,探讨了不同矿化度下(lg/L、3g/L、5g/L、10g/L)的三种钠盐(Nacl、Na2SO4和Na2CO3)对石灰性土壤水分扩散率的影响.结果表明:在水盐复合迁移体系中盐分与水分迁移具有不同步性,影响不同步性的因子与盐分类型有很大关系.NaCl对水分移动速...     

阿拉尔绿洲灌区棉田土壤水分扩散率的测定

土壤水分扩散率是研究土壤水盐运动的重要参数之一。在室内用非稳定流水平土柱法对塔里木河流域阿拉尔绿洲灌区棉田土壤水分扩散率进行了测定。建立了Boltzmann变换参数、土壤水分扩散率与土壤含水率之间的定量关系。结果表明:土壤水分扩散率与土壤含水率呈单调递增关系。当土壤含水率趋近饱和含水率时,土壤水分扩散率趋近于无穷大。因此,用指数函数或幂函数不能很好地刻画土壤水分扩散系数与土壤的体积含水量之间的定量关系。本文建立的土壤水分扩散率与土壤含水率之间的函数关系较好地反映了土壤水分扩散系数与土壤的体积含水量之间的客观规律。     

Diurnal variability of upper ocean temperature and heat budget in the southern Bay of Bengal during October–November, 1998 (BOBMEX-Pilot)

Time-series data on upper-ocean temperature, Vessel-Mounted Acoustic Doppler Current Profiler (VM-ADCP) measured currents and surface meteorological parameters have been obtained for the first time in the southern Bay of Bengal at 7‡N, 10‡N, and 13‡N locations along 87‡E during October–November, 1998 under BOBMEX-Pilot programme. These data have been analysed to examine the diurnal variability of upper oceanic heat budget and to estimate the eddy diffusivity coefficient of heat in the upper layer. Diurnal variation of near-surface temperature is typical at northern location (13‡N) with a range of 0.5‡C while the diurnal range of temperature is enhanced to 0.8‡C at the central location (10‡N) due to intense solar radiation (1050 W/m²), clear skies and low wind speeds. At the southern location (7‡N), the diurnal variation of temperature is atypical with the minimum temperature occurring at 2000 hrs instead of at early morning hours. In general, the diurnal curve of temperature penetrated up to 15 to 20 m with decreasing diurnal range with depth. The VM-ADCP measured horizontal currents in the upper ocean were predominantly easterly/northeasterly at southern location, north/northerly at central location and northwesterly at northern location, thus describing a large-scale cyclonic gyre with the northward meridional flow along 87‡E. The magnitudes of heat loss at the surface due to air-sea heat exchanges and in the upper 50 m layer due to vertical diffusion of heat are highest at the southern location where intense convective activity followed by overcast skies and synoptic disturbance prevailed in the lower atmosphere. This and the estimated higher value (0.0235 m²/s) of eddy diffusivity coefficient of heat in the upper ocean (0–50 m depth) suggest that 1-D processes controlled the upper layer heat budget at the southern location. On the other hand, during the fair weather conditions, at the central and northern locations, the upper layer gained heat energy, while the sea surface lost (gained) heat energy at northern (central) location. This and lower values of eddy diffusivity coefficient of heat (0.0045 and 0.0150 m²/s) and the northward intensification of horizontal currents at these locations suggest the greater role of horizontal heat advection over the 1-D processes in the upper ocean heat budget at these two locations.     

Thermal fronts and cross-frontal heat flux in the southern Huanghai Sea and the East China Sea

Synoptic features in/around thermal fronts and cross-frontal heat fluxes in the southern Huanghai./Yellow Sea and East China Sea （HES） were examined using the data collected from four airborne expendable bathythermograph surveys with horizontal approxmately 35 km and vertical 1 m（from the surface to 400 m deep） spacings. Since the fronts are strongly affected by HES current system, the synoptic thermal features in/around them represent the interaction of currents with surrounding water masses. These features can not be obtained from climatological data. The identified thermal features are listed as follows ： （ 1 ） multiple boundaries of cold water, asymmetric thermocline intrusion, locally-split front by homogeneous water of approxmately 18 ℃, and mergence of the front by the Taiwan Warm Current in/around summertime southern Cheju - Changjiang/Yangtze front and Tsushima front; （2） springtime frontal eddy-like feature around Tsushima front; （3） year-round cyclonic meandering and summertime temperature-inversion at the bottom of the surface mixed layer in Cheju - Tsushima front; and （4） multistructure of Kuroshio front. In the Kuroshio front the mean variance of vertical temperature gradient is an order of degree smaller than that in other HES fronts. The southern Cheju- Changjiang front and Cheju -Tsushima front are connected with each other in the summer with comparable cross-frontal temperature gradient. However, cross-frontal heat flux and lateral eddy diffusivity are stronger in the southern Cheju - Changjiang front. The cross-frontal heat exchange is the largest in the mixing zone between the modified Huanghai Sea bottom cold water and the Tsushima Warm Current, which is attributable to enhanced thermocline intrusions.     

Tide-induced head fluctuations in coastal aquifers of variable thickness

In this work, a new analytical solution to describe tide-induced head fluctuations in aquifers of variable thickness is presented. The proposed model assumes a finite and confined aquifer with a thickness that increases or decreases quadratically with the distance to the coast. A closed-form analytical solution is obtained by solving a boundary-value problem with both a separation of variables method and a change of variables method. This solution is a generalization of the solution obtained by Cuello et al., Hydrogeological Journal, 2017, 25, 1509–1515. The analytical solution is expressed in terms of the wedging parameter, a parameter that depends on the length and thicknesses at the coast and at the inland edge of the aquifer. Positive values of the wedging parameter describe aquifers with increasing thickness towards land and negative values describe aquifers with a decreasing thickness in the inland direction. The comparison of the new solution and the solution for a finite aquifer with constant thickness indicates that the sign of the wedging parameter enhances or decreases the amplitude of the tide-induced signal. However, the differences in time-lag between both solutions are negligible near the coast. The slope factor, which quantifies the inconsistencies between aquifer diffusivities estimated from attenuation and time-lag data, is computed and analysed. Near the coast, slope factor values greater than one are obtained for negative wedging parameters while slope factor values less than one are obtained for positive wedging parameters. The analysis of the new solution also indicates that more reliable estimates of the hydraulic diffusivity can be obtained from time-lag data.