干酪根化学降解产物的碳同位素组成研究

采用一系列温和的化学降解法对松辽盆地南部嫩江组烃源岩的干酪根进行连续的选择性化学降解，并对不同降解产物进行色谱—同位素比值质谱分析。研究表明碱性水解和脱硫产物以一元脂肪酸和正构烷烃为主，其中正构烷烃碳同位素分布曲线呈现一定的“负倾”（即随碳数增加呈现逐渐贫13C）趋势；一元脂肪酸以C16和C18为主，具有明显的偶碳优势，与同碳数的正构烷烃具有相似的碳同位素组成。氧化产物则以一元脂肪酸和α,ω 二元脂肪酸为主，一元脂肪酸低碳数部分呈现“负倾”趋势，高碳数部分则呈现“正倾”的趋势；α,ω 二元脂肪酸与低碳数的一元脂肪酸具有相似的分布，表明它们可能具有相同的母源。对比研究表明JL 30抽提物中正构烷烃可能存在混源的影响，其碳同位素组成是多源混合的结果。     

Spatial pattern of Karst rock desertification in the Middle of Guizhou Province,Southwestern China

Karst rocky desertification is a typical type of land degradation in the Southwestern China. It has great ecological and economical implications for the local people. Landsat images from the middle of Guizhou Province collected in 1974, 1993 and 2001 were used for change detection of the pattern of Karst rocky desertification. The results show the following findings: (1) Desertification area expanded drastically in 27 years, at an increasing rate about 116.2 km²/year. (2) High areas (900–1,500 m) are the most affected. (3) Areas with the slope <5° or >25° are also easily tend to be Karst rocky deserted. (4) The process of Karst rocky desertification is nearly irreversible. Few areas of Karst rocky desertification could be meliorated to non-desertification land. (5) Most of the degraded lands are located in the south and the central of the study region, and the meliorated land areas are sparsely located in the east and the west part of the region. All these findings would provide bases for the decision-making of the local government to improve the Karst rocky desertification     

枯草芽孢杆菌(Bacillus subtilis)降解萘的动力学研究

枯草芽孢杆菌(Bacillus subtilis)HBS-4是从油田中分离出来的一株能高效降解有机物萘的菌株。当萘的初始浓度为100mg时,该菌株在pH为8.0,温度为40℃下具有较好的降解效果,作用69h能降解50%以上的萘。通过HBS-4菌株降解萘的动力学研究,在Williams结构模型的基础上建立了HBS-4作用萘的四组分动力学模型,并用此模型解释菌株HBS-4在降解萘的过程中,葡萄糖含量、菌液浓度、pH、Eh随时间的变化特征。     

气候影响下的荒漠下的荒漠化监测

根据揭示沙漠化扩张内在规律的相关气候驱动因子的假说,气候作用影响之下的沙漠化是在具反射率-降水正、负反馈特点的气候系统之中的区域干旱化过程与干旱土壤退化过程相互作用的结果。在辐射调节下的地表下垫面温度占主导的条件下,气候成因的沙漠化是由区域气候系统反馈所形成。正反馈的外部调节因子是降水量的变化和极端降水事件(特别是旱灾)的出现频率,降水量减少以及降水频率的降低直接影响沙漠化的程度。20世纪下半叶,人类因素导致的干旱土地退化作为另外的正反馈调节因子,其重要性正在增加。通常正反馈的扩大趋势会被通过蒸腾而进行的地表温度调节的负反馈所抑制。由正反馈到负反馈的转换是通过地球表面与大气层之间的热量交换的调节所确定的,其中非潜热因子处于增加状态。上述情况在反射率和地表温度同时增加的条件下发生。在超出绿色植物生物量及其NDVI指数阈值的条件下,负反馈向正反馈的转换就会发生。人为作用导致的植被退化加快了向绿色植物生物量阈值逼近的进程,从而引起气候因素驱动的沙漠化扩大。一个主要由气候因素影响的荒漠化区域,在大多数情况下,其绿色生物量均在季节变化和年际变化中达到了阈值。在中度的人为影响的植被退化条件下,这些地域一般都包括部分干旱与半干旱土地。然而有时,人类活动也会导致干旱的半湿润土地退化。本文运用Turan和Sahel地区1982-2001年NDVI指数的监测结果,分析了全球变暖和人为作用导致的土地退化。     

An assessment of land degradation in the Save catchment of Zimbabwe

The lack of reliable baseline information on land degradation is a hindrance towards its monitoring and mitigation. Of particular interest is the identification of areas susceptible to degradation. In this study, remote sensing and GIS technologies were applied to detect and map susceptibility to land degradation in Buhera district, in Save catchment, Zimbabwe. Data used included Landsat TM and ETM imagery for 1992 and 2002, agro-ecological zones, vegetation cover and population density. The study identified five preliminary categories of degradation susceptibility ranging from very high to low.     

The stiffness degradation and damping ratio evolution of Taipei Silty Clay under cyclic straining

The non-linear behavior of Taipei Silty Clay under cyclic strain loading was investigated through a series of undrained cyclic strain-controlled tests. The Ramberg–Osgood equation was used with our proposed stiffness degradation model to calculate degraded secant moduli. The proposed degradation model is simple in that it has only one more component than Idriss's model, the modulus ratio for the first cycle, which reflects the effects of the previous cyclic strain history and the current level of the cyclic strain amplitude, and can be used to describe softening and hardening behavior under irregular cyclic straining. It was found that the Ramberg–Osgood equation successfully predicts the damping ratio for small to medium strains. However, it overestimates the damping ratio for larger strains, so we suggest it can be corrected with a damping ratio index. In addition, the proposed equation for describing the evolution of the damping ratio provides the means to assess the variation for Taipei Silty Clay in the measured damping ratio with both the number of cycles and the strain amplitude.     

SPECIFIC DEGRADATION OF WATERSHEDS

An extensive database of reservoir sedimentation surveys throughout continental United States is compiled and analyzed to determine specific degradation SD relationships as function of mean annual rainfall R, drainage area A, and watershed slope S. The database contains 1463 field measurements and specific degradation relationships are defined as function of A, R and S. Weak trends and significant variability in the data are noticeable. Specific degradation measurements are log normally distributed with respect to R, A, and S and 95% confidence intervals are determined accordingly. The accuracy of the predictions does not significantly increase as more independent variables are added to the regression analyses.     

地下水有机污染的水文地球化学标志物探讨——以河南油田为例

经过野外现场调查和取样分析及室内研究得知南阳油田地下水已遭受不同程度的有机物污染，且污染范围可能进一步向油田南部扩散。根据近似地下水流线方向上地下水中总油质量浓度和Fe,Mn等无机组分的变化势态，结合含水介质化学分析结果，发现硫酸盐、Fe和Mn可作为地下水有机污染和地球化学标志物。在含水介质中Fe和Mn质量浓度较高的地方，地下水有机污染物降解速度快，含水介质中Fe和Mn的氧化物和氢氧化物的还原作用导致了含水层介质中Fe和Mn的缺乏和地下水中溶解Fe和Mn的积聚；在含水介质中Fe和Mn质量浓度低的地方，地下水中的有机物质量浓度并没有降低，相应地地下水中溶解Fe和Mn的质量浓度也很低。同时，由于有机污染物的存在使地下水中硫酸盐被还原，导致城下水中硫酸盐质量浓度偏低，且地下水中Fe对有机物污染的敏感性比Mn强。     

低山丘陵区土地利用方式对土壤质量的影响—以河北省遵化市为例

通过调查河北省遵化市低山丘陵区油松林、板栗、草地和坡耕地等典型土地利用方式对土壤养分和土壤容重的影响，土地取样取土壤表层0-20cm，结果表明，森林的砍伐以及随后的耕种显著增加了土壤容重并降低了大部分土壤养分。和林地相比，草地、当年开垦的农地、板栗和耕种3年的农地容重分别增加了13.3%，14.2%,27.5%,39.7%。除全磷外，板栗和耕种3年的农地土壤养分有显著下降，和林地相比，板栗有机质减少了60.7%，全氮减少了35.6%，全钾减少了21.3%，速效钾减少了57%；耕种3年的农地土壤有机质、全氮、全钾和速效钾则分别减少了62.9%,52.6%,31%和60%。土壤退化指数的计算结果表明板栗和耕种3年的农地土壤发生了较为严重的退化。     

西南地区山地不同土地退化类型特征及调控途径

土地退化不仅是目前全还需性的重大环境问题之一，而且也是重大的社会和经济问题之一，西南地区的土地退化是以水力侵蚀为主要动力形成的，文中简述了西南地区的土地退化状况，选择了4个（楚雄市、遂宁市，毕节地区及元谋县）山地不同土地退化类型进行分析，讨论了土 退化过程，提出了土地退化调控途径。