酸雨对桂林枯水期岩溶地下水δ13CDIC及碳汇效应的影响

定量评价硫酸对岩溶碳汇效应的影响有助于提高岩石风化碳汇通量估算精度, 对当前全球气候变化研究意义重大.选取受酸雨影响的桂林岩溶区为研究对象, 在枯水期对研究区14个岩溶大泉和15条地下河水化学成分和碳同位素进行了测试分析, 结果表明: 岩溶大泉和地下河中阳离子以Mg2+和Ca2+为主, 阴离子以HCO₃-为主, 分别占阳离子和阴离子组成的90%以上, SO₄2-含量较低, 其含量范围为0.004~0.213mmol/L; 所占阴离子组成比例为0.12%~6.11%;δ13C_DIC、[Ca2++Mg2+]/[HCO₃-]更偏向于碳酸溶解端元, 离硫酸溶解端元距离远, 证实硫酸参与碳酸盐岩的溶解对地下水无机碳(dissolved inorganic carbon, 简称DIC)及δ13C_DIC的影响有限; 与Sr2+/Ca2+值一样, δ13C_DIC主要受径流条件控制, 其大小可以反映地下水径流条件的强弱.利用化学计量关系计算出由硫酸溶蚀碳酸盐岩的平均比例为22.64%, 产生的DIC(HCO₃-_H2SO4)占总DIC的平均比例为13.04%, 碳酸产生的DIC(HCO₃-_H2CO3)占地下水总DIC的比例为86.96%, 其中来源于土壤大气中的HCO₃-比例为43.48%.因此, 扣除硫酸对地下水中DIC的贡献后, 岩溶碳汇效应将减少13.04%.      

珠江流域碳酸盐岩与硅酸盐岩风化对大气CO_2汇的效应

对珠江流域11个测站的河水1个水文年4次取样进行水化学和同位素测试分析,揭示无论是碳酸盐岩区还是硅酸盐岩区,岩石风化均使河流的离子成分以HCO3-、Ca2+、Mg2+为主,碳酸盐岩风化溶蚀速率和由碳酸盐岩风化溶蚀引起的大气CO2消耗量分别为27.60 mm/ka和540.21x103mol/(km2·a-1),是硅酸盐岩风化速率和由硅酸盐岩风化引起的大气CO2消耗量的10.8倍和6.7倍,说明碳酸盐岩风化是流域碳汇过程及效应的主体。由于有利的水热条件和高的碳酸盐岩面积比例,珠江流域平均岩石风化速率和由岩石风化作用引起的大气CO2消耗量分别为30.15mm/ka和620.36×103mol/(km2·a-1),为全球60条河流平均值的2.6倍。     

极锋以南洋区N_2O源汇特性初析

N_2O是大气中最重要的温室气体之一,目前已经有大量的研究对海洋N_2O循环及海洋对N_2O收支的贡献进行追踪报道。然而,极区相关研究仍然十分有限。本研究利用中国第25、26次南极科学考察的机会,对南大洋进行的采样以及实验室分析,结果显示,南大洋表层海水存在亚热带锋附近N_2O过饱和,亚南极锋附近接近饱和,和极锋以南洋面的不饱和的特征。海冰融化后,其融冰水的注入是N2O不饱和特征形成的主要原因。运用正态分布选取站观测风速95%以上的风速范围进行平局估算出极锋以南洋区海气通量,结果显示,极锋区以南表层海水是大气N_2O的汇区,年吸收通量约为3.5×10~(-4)—7.7×10-4Tg·a-1(百万吨氮/年)。     

2011年宁夏川区一次高温天气分析

文章利用Micaps资料及数值预报产品,对2011年6月15日宁夏川区高温天气进行了分析,结果表明:此次高温天气主要影响系统是河西一带产生暖性高压东移形成河套高压。从低层到高层盛行暖平流是高温出现的直接因素,气流的上升下沉加快了暖流扩散。     

ANALYSIS OF SURFACE SINK OF EXPLORATION VACANCY IN GOLD MINING AREA OF ZHAOYUAN CTIY BASED ON RS AND GIS

1 IN T R O D U C T IO NZhaoyuan C ity, located in northeast of ShandongProvince,iscalled "G old C ity"and itisone ofim portantgold production bases in C hina.The exploitation ofthegold broughtoutthe extensive vacantareas,leading tolarge-scale ground subsi…     

Phytochemical changes in leaves of subtropical grasses and fynbos shrubs at elevated atmospheric CO2 concentrations

The effects of elevated atmospheric CO₂ concentrations on plant polyphenolic, tannin, nitrogen, phosphorus and total nonstructural carbohydrate concentrations were investigated in leaves of subtropical grass and fynbos shrub species. The hypothesis tested was that carbon-based secondary compounds would increase when carbon gain is in excess of growth requirements. This premise was tested in two ecosystems involving plants with different photosynthetic mechanisms and growth strategies. The first ecosystem comprised grasses from a C₄-dominated, subtropical grassland, where three plots were subjected to three different free air CO₂ enrichment treatments, i.e., elevated (600 to 800 μmol mol⁻¹), intermediate (400 μmol mol⁻¹) and ambient atmospheric CO₂. One of the seven grass species, Alloteropsis semialata, had a C₃ photosynthetic pathway while the other grasses were all C₄. The second ecosystem was simulated in a microcosm experiment where three fynbos species were grown in open-top chambers at ambient and 700 μmol mol⁻¹ atmospheric CO₂ in low nutrient acid sands typical of south western coastal and mountain fynbos ecosystems. Results showed that polyphenolics and tannins did not increase in the grass species under elevated CO₂ and only in Leucadendron laureolum among the fynbos species. Similarly, foliar nitrogen content of grasses was largely unaffected by elevated CO₂, and among the fynbos species, only L. laureolum and Leucadendron xanthoconus showed changes in foliar nitrogen content under elevated CO₂, but these were of different magnitude. The overall decrease in nitrogen and phosphorus and consequent increase in C:N and C:P ratio in both ecosystems, along with the increase in polyphenolics and tannins in L. laureolum in the fynbos ecosystem, may negatively affect forage quality and decomposition rates. It is concluded that fast growing grasses do not experience sink limitation and invest extra carbon into growth rather than polyphenolics and tannins and show small species-specific chemical changes at elevated atmospheric CO₂ concentrations. Responses of fynbos species are varied and were species-specific.     

Diffuse CO<Subscript>2</Subscript> degassing at Vesuvio,Italy

At Vesuvio, a significant fraction of the rising hydrothermal–volcanic fluids is subjected to a condensation and separation process producing a CO₂–rich gas phase, mainly expulsed through soil diffuse degassing from well defined areas called diffuse degassing structures (DDS), and a liquid phase that flows towards the outer part of the volcanic cone. A large amount of thermal energy is associated with the steam condensation process and subsequent cooling of the liquid phase. The total amount of volcanic–hydrothermal CO₂ discharged through diffuse degassing has been computed through a sequential Gaussian simulation (sGs) approach based on several hundred accumulation chamber measurements and, at the time of the survey, amounted to 151 t d^–1. The steam associated with the CO₂ output, computed assuming that the original H₂O/CO₂ ratio of hydrothermal fluids is preserved in fumarolic effluents, is 553 t d^–1, and the energy produced by the steam condensation and cooling of the liquid phase is 1.47×10¹² J d^–1 (17 MW). The location of the CO₂ and temperature anomalies show that most of the gas is discharged from the inner part of the crater and suggests that crater morphology and local stratigraphy exert strong control on CO₂ degassing and subsurface steam condensation. The amounts of gas and energy released by Vesuvio are comparable to those released by other volcanic degassing areas of the world and their estimates, through periodic surveys of soil CO₂ flux, can constitute a useful tool to monitor volcanic activity.Editorial responsibility: H. Shinohara     

中国不同区域能源消费碳足迹的时空变化(英文)

Study on regional carbon emission is one of the hot topics under the background of global climate change and low-carbon economic development, and also help to establish different low-carbon strategies for different regions. On the basis of energy consumption and land use data of different regions in China from 1999 to 2008, this paper established carbon emission and carbon footprint models based on total energy consumption, and calculated the amount of carbon emissions and carbon footprint in different regions of China from 1999 to 2008. The author also analyzed carbon emission density and per unit area carbon footprint for each region. Finally, advices for decreasing carbon footprint were put forward. The main conclusions are as follows: (1) Carbon emissions from total energy consumption increased 129% from 1999 to 2008 in China, but its spatial distribution pattern among different regions just slightly changed, the sorting of carbon emission amount was: Eastern China > Northern China > Central and Southern China > Southwest China > Northwest China. (2) The sorting of carbon emission density was: Eastern China > Northeast China > Central and Southern China > Northern China > Southwest China > Northwest China from 1999 to 2003, but from 2004 Central and Southern China began to have higher carbon emission density than Northeast China, the order of other regions did not change. (3) Carbon footprint increased significantly since the rapid increasing of carbon emissions and less increasing area of pro-ductive land in different regions of China from 1999 to 2008. Northern China had the largest carbon footprint, and Northwest China, Eastern China, Northern China, Central and Southern China followed in turn, while Southwest China presented the lowest area of carbon footprint and the highest percentage of carbon absorption. (4) Mainly influenced by regional land area, Northern China presented the highest per unit area carbon footprint and followed by Eastern China, and Northeast China; Central and Southern China, and Northwest China had a similar medium per unit area carbon footprint; Southwest China always had the lowest per unit area carbon footprint. (5) China faced great ecological pressure brought by carbon emission. Some measures should be taken both from reducing carbon emission and increasing carbon absorption.     

云凝结核浓度对WRF模式模拟飑线降水的影响：不同云微物理参数化方案的对比研究

采用WRF模式模拟一次影响中国广东省的飑线过程, 分别选取Morrison、 Thompson07、 Thompson09和WDM6云微物理方案实施了四组试验, 每组试验包括不同云凝结核（CCN）浓度的三次模拟, 称为 “低浓度”、 “中浓度” 和 “高浓度”, 将模拟区域划分为深对流、 浅对流和层云区域, 对比分析四组试验中CCN浓度变化对模拟的总降水量、 不同区域降水率和不同区域面积的影响, 进一步分析了云微物理过程、 动力环流强度等受CCN浓度变化的影响。发现: （1） 由于不同云微物理过程与CCN浓度有着直接或间接的联系、 不同云微物理过程之间存在复杂的关联、 云微物理过程与动力环流之间发生非线性耦合, 采用不同的云微物理方案导致模拟的CCN—降雨影响既有相似、 也有差异; （2）模拟的CCN—降水影响在采用Thompson09和Thompson07方案时更显著, 采用WDM6方案时最小; （3）四组模拟试验均出现CCN浓度增加延迟降水产生、 初期降水减弱的情况, 在模拟后期降水量也随着CCN浓度增加而减小, 而飑线成熟阶段CCN—降水影响更加复杂。     

天津武清地区云凝结核变化特征

利用2009年11—12月在天津武清气象局测量的云凝结核(CCN:Cloud Condensation Nuclei)浓度资料以及气溶胶数谱分布的观测资料,分析了武清地区在不同过饱和度(0.1%～1.0%)下云凝结核浓度及活化率的变化特征。结果表明:武清地区冬季CCN数浓度变化范围很大,过饱和度1%时,浓度变化范围为4000～32000cm-3,且浓度受风速影响明显,风速2级以下CCN数浓度很高,过饱和度1%时,其平均浓度可达16000cm-3,但对于4级风速以上CCN平均浓度为4000cm-3左右;在过饱和度0.1%～0.4%间CCN浓度变化较大,过饱和度每增加0.1%,CCN浓度增加值平均约为过饱和度0.4%～1.0%间浓度增量的5倍。低过饱和度(0.1%、0.2%)下,活化率受风速影响明显,1级风速下的CCN活化率约为4级风速下的3倍,但在过饱和度1%时活化率则相差不大。CCN浓度的日变化呈双峰型,峰值时刻为北京时间08:00和18:00左右,活化率的日变化则呈双谷型,这主要是受局地排放影响的结果。利用指数函数拟合各风速下CCN浓度过饱和度谱,表明该地谱型为典型的大陆型。