天津城区春节期间大气气溶胶污染特征 和数浓度分布

利用天津城区2009-2014年春节期间大气气溶胶观测资料和相关气象资料,重点分析2013和2014年春节期间气溶胶污染特征,探求燃放烟花爆竹以及气象条件对春节期间大气气溶胶的影响。结果表明,受燃放烟花爆竹影响,春节期间PM_(2.5)质量浓度最高值均发生在除夕夜间;持续雾霾天气条件下燃放烟花爆竹,造成2013年除夕夜间PM_(2.5)质量浓度峰值达到1240μg·m～(-3),是近年来最严重的一次;2014年春节期间烟花爆竹燃放量有所减少,加之空气扩散条件较为有利,PM_(2.5)质量浓度显著低于2013年;不同天气条件下,气溶胶数浓度谱分布特征存在明显差异,燃放烟花爆竹期间气溶胶数浓度水平与严重雾-霾天气相当。     

太湖地区HJ-1卫星CCD数据反演气溶胶及大气校正

针对HJ-1卫星CCD数据,利用改进的暗像元法反演气溶胶光学厚度(AOD),再利用反演的AOD对其进行大气校正。将反演的气溶胶与地基太阳光度计数据进行对比验证,发现当反演的AOD值大于0.2时,反演值与地基观测值的相关系数为0.964,符合MODIS业务化反演AOD的精度要求。再将反演得到的气溶胶带入6S辐射传输模型中,对HJ-1卫星CCD数据进行大气校正实验。结果表明,该方法能有效提高HJ-1卫星CCD数据大气校正的精度,更好地复原地物的真实光谱信息。     

气溶胶大气辐射校正区域性分析

针对使用6S模型中标准气溶胶模型进行大气辐射校正时结果较差的问题,该文提出使用实测气溶胶模型代替其进行计算。利用AERONET数据产品分析了香河、榆中等部分站点的气溶胶成分及其区域性分布特点,证明了中国气溶胶的成分具有明显的区域特性;并对6S模型中标准气溶胶模型与香河地基观测气溶胶光学参数进行比较,结果表明,两者具有较大的差异;最后使用不同的气溶胶模型校正Landsat5TM影像,结果表明,采用实测气溶胶数据进行大气辐射校正结果较优。     

Satellite-measured atmospheric aerosol content in Korea: anthropogenic signals from decadal records

Spatiotemporal characteristics and anthropogenic signals of aerosol optical thickness (AOT) distributions over Korea are investigated in this study using AOT time-series data from the Moderate Resolution Imaging Spectroradiometer (MODIS). AOT observations, a quantitative measure of the atmospheric quality, had significant geographical variations during the study period (2000–2010). Comparing metro cities or counties with similar populations, western regions showed higher AOT values than eastern regions. Particular matter with a diameter < 10 µm (PM₁₀), including aeolian dust or yellow dust, is the primary component of atmospheric aerosols, and their transport into the region has shown a strong seasonal pattern with its peak from March to April and lows from July to September. These seasonal dust patterns, however, did not correspond well to temporal AOT records, which typically reached the maximum level in June nationwide. Rather, widespread regional fire events and humidity showed significant correlations with AOT time-series. This correlation rapidly increased as the range of fire occurrence was extended to the west as far as 115°E. The relative humidity also had a significant correlation with AOT during the month of June. In addition to urban emission of anthropogenic aerosols, regional biomass burning and secondary growth of hygroscopic aerosols are considered important contributors to the degradation of the atmospheric environment during the non-Asian Dust season over the Korean Peninsula.     

青藏高原东北部降尘通量及粒度特征分析

青藏高原东北缘是柴达木沙尘暴东移的必经之道和沉降区,对青藏高原东北部降尘时空分异特征进行分析,有助于认识青藏高原区域粉尘输送的现代过程和机制。2013年12月至2015年5月分别在青海湖小泊湖(XBH)、西宁多巴(DB)、西宁青海师大科技楼顶(KJLD)设置降尘缸,进行湿法收集。对其降尘通量和粒度特征进行了时空分异特征分析,结果显示,1)西宁地区2014年降尘通量为442~542 g/m~2·a,青海湖XBH采集点指示的2014年降尘通量为415 g/m~2·a,降尘通量年际变化较大,各站点降尘通量季节变化趋势一致,降尘主要集中在冬春季,夏季降尘通量最低;2)各站点降尘粒度组成特征非常相似,以粉砂为主(4~63μm),西宁地区尘暴与非尘暴降尘粒度频率曲线呈近似正态分布,尘暴期间降尘粒径较非尘暴时段大;3)XBH、DB和KJLD 3点所有样品平均粒径分别为37μm、34μm和31μm,中值粒径分别为31μm、27μm和26μm;对比低海拔兰州尘暴粒径特征,发现降尘粒径存在一定的海拔依赖性,即粒度随海拔增高逐渐变粗。     

华南黑碳气溶胶浓度与南海夏季风关系的年代际突变

利用重建的华南区域黑碳气溶胶(Black Carbon, BC)浓度资料,分析其与南海夏季风在年际尺度上的关系。结果表明,华南区域BC浓度与南海夏季风的关系在2000年前后有明显的突变,由显著负相关变为显著正相关,即由高BC浓度弱季风变为高BC浓度强季风。通过合成对比分析,发现1988—1999年(第一时间段)的华南BC主要气候效应是间接辐射强迫作用:华南BC使云粒子半径减小,抑制华南区域春季降水,增加了云的生命期,从而使到达地面的短波辐射减少,表面和低层大气降温。负温度异常激发了异常反气旋,在南海区域即有东风异常。到夏季,东风异常减弱了季风强度,同时抑制了南海地区的降水。2000—2010年(第二时间段)的华南BC主要气候效应是直接辐射强迫作用:春季高BC浓度通过直接气候效应,增暖大气,加强降水,但是雨日减少,从而使到达地面的短波辐射增多,表面和低层大气增温。正温度异常激发了异常气旋,在南海区域即有西风异常一直维持到夏季,增大了季风强度,同时增强了南海地区的降水。     

Nitrogen and sulfur species in Antarctic aerosols at Mawson,Palmer Station,and Marsh (King George Island)

High volume bulk aerosol samples were collected continuously at three Antarctic sites: Mawson (67.60° S, 62.50° E) from 20 February 1987 to 6 January 1992; Palmer Station (64.77° S, 64.06° W) from 3 April 1990 to 15 June 1991; and Marsh (62.18° S, 58.30° W) from 28 March 1990, to 1 May 1991. All samples were analyzed for Na⁺, SO ₄ ^2– , NO ₃ ^– , methanesulfonate (MSA), NH ₄ ⁺ ,²¹⁰Pb, and⁷Be. At Mawson for which we have a multiple year data set, the annual mean concentration of each species sometimes vary significantly from one year to the next: Na⁺, 68–151 ng m^–3; NO ₃ ^– , 25–30 ng m^–3; nss SO ₄ ^2– , 81–97 ng m^–3; MSA, 19–28 ng m^–3; NH ₄ ⁺ , 16–21 ng m^–3;²¹⁰Pb, 0.75–0.86 fCi m^–3. Results from multiple variable regression of non-sea-salt (nss) SO ₄ ^2– with MSA and NO ₃ ^– as the independent variables indicates that, at Mawson, the nss SO ₄ ^2– /MSA ratio resulting from the oxidation of dimethylsulfide (DMS) is 2.80±0.13, about 13% lower than our earlier estimate (3.22) that was based on 2.5 years of data. A similar analysis indicates that the ratio at Palmer is about 40% lower, 1.71±0.10, and more comparable to previous results over the southern oceans. These results when combined with previously published data suggest that the differences in the ratio may reflect a more rapid loss of MSA relative to nss SO ₄ ^2– during transport over Antarctica from the oceanic source region. The mean²¹⁰Pb concentrations at Palmer and Marsh and the mean NO ₃ ^– concentration at Palmer are about a factor of two lower than those at Mawson. The²¹⁰Pb distributions are consistent with a²¹⁰Pb minimum in the marine boundary layer in the region of 40°–60° S. These features and the similar seasonalities of NO ₃ ^– and²¹⁰Pb at Mawson support the conclusion that the primary source regions for NO ₃ ^– are continental. In contrast, the mean concentrations of MSA, nss SO ₄ ^2– , and NH ₄ ⁺ at Palmer are all higher than those at Mawson: MSA by a factor of 2; nss SO ₄ ^2– by 10%; and NH ₄ ⁺ by more than 50%. However, the factor differences exhibit substantial seasonal variability; the largest differences generally occur during the austral summer when the concentrations of most of the species are highest. NH ₄ ⁺ /(nss SO ₄ ^2– +MSA) equivalent ratios indicate that NH₃ neutralizes about 60% of the sulfur acids during December at both Mawson and Palmer, but only about 30% at Mawson during February and March.     

气态SO_2转化及其数值模型研究

本文基于对室外烟雾箱实验,探讨了SO_2的转化机制及影响SO_2转化的因素,由此并借助于烟团模型,建立了SO_2转化和硫酸盐气溶胶细粒子生成的数值模型,用于估算从排放源排入大气的SO_2浓度及其转化成硫酸盐细粒子的浓度以及它们的空间分布,与实测结果相比,两者有较好的一致性.同时指出,由于大气中细粒子(粒径小于1μm)可通过人体呼吸进入并沉积在肺泡中而对健康有不利影响,从而说明研究大气中细粒子污染的迫切性.