An evaluation of residential air radon concentrations and related variables in southeast Michigan,USA

Analysis of 153 residential air radon (Rn-222) screening measurements from southeast Michigan indicates that basements host Rn levels two to three times higher than upper-level rooms. Compared to unfinished basements, finished (e.g., paneled walls, tiled floors) basements apparently reduce indoor air Rn levels while partially finished basements may not. Factor analysis of residence questionnaire data explains 59 percent of the Rn data variance. The volume of pathways (e.g., foundation cracks/holes, uncapped sumps) allowing Rn seepage into the dwelling controls the largest portion, 23 percent, of the explained data variance. The residence water source explains 11 percent of the Rn data variance. Groundwater Rn levels contribute to the air Rn data variability, but the study data cannot quantitatively assess this contribution. Seven percent of the Rn data variance is likely controlled by house depressurization facilitated by residence structural properties. Residences with foundation cracks or poorly sealed joints and low-volume indoor-outdoor air exchange are more prone to this effect. Eighteen percent of the explained Rn data variance correlates with the residence's primary heat source. Evidently, operating combustion sources also induce house depressurization and allow Rn to be drawn into the house through entry paths. Twenty-four percent of the analyses equal or exceed 4 pCi/1 Rn. In residences occupied 5 years by the same individuals, 17 percent of the Rn data are 4 pCi/l; here the arithmetic mean air Rn level is 8.3 pCi/l and the average occupancy period 17.4 years.     

The history and impact of air pollution at Čertovo Lake,southwestern Czech Republic

This multi-disciplinary investigation documents the longterm effects of atmospheric pollution of metals and acids on a geologically sensitive catchment in the umava Mountains, southwestern Czech Republic, a region with a long history of human disturbance. A 30 cm long sediment core (I) from ertovo Lake was analyzed for natural and artifical radionuclides, metals, diatoms, chrysophytes, and pollen in sediments accumulated during the last 200 years. A second core (II), extending to 95 cm, included sediment judged to be free of atmospheric deposition of pollutants associated with the Industrial Revolution. Chronostratigraphic markers include several changes in the pollen assemblages corresponding to well-documented changes in land-use, and distinct distributions of ¹³⁷Cs, ¹³⁴Cs and ²⁴¹Am from weapons testing and the 1986 nuclear accident at Chernobyl, Russia. These markers corroborate the ²¹⁰Pb dating and, together, produce a reliable chronology extending back nearly to 1800 A.D.Stratigraphic profiles of Cu, Pb, and Zn in Core I are unlike any previously reported in the literature. Concentrations of Cu, Pb, and Zn remain generally above 100, 400, and 200 g g^-1, respectively, for the 200 years represented by Core I. These values are unusually high for sediments from a watershed with no known heavy-metal ore bodies. Accumulation rates for Cu, Pb, and Zn, which include both atmospheric and watershed contributions, are also high (ca 1, > 1 and > 1 g cm^-2 yr^-1, respectively) for the same period, although the anthropogenic contribution of Zn rose from nearly zero at 1800 A.D. The Cu and Pb accumulation rates rose dramatically about 1640 A.D.Accumulation rates of anthropogenically-derived Be, a relatively abundant element in the soft coals of the region, are also elevated by about 0.01 g cm^-2 yr^-1 in sediments of this period. Vanadium accumulation rates increased only since 1980 A.D., presumably along with increased consumption of oil.Diatom assemblages illustrate that the lake was acidic (pH between 4.5 and 5) through at least the past 200 years. The pH declined significantly (from ca 5 to 4) between 1960 and 1985 with a slight increase to 4.5 in the last few years. Recent diatom and chrysophyte assemblages suggest high trace metal concentrations, consistent with the present lake-water chemistry.     

金沙本底站空气质量与颗粒物浓度变化特征分析

利用华中区域代表性站点金沙国家大气本底站2007—2018年的PM_2.5、PM₁₀颗粒物质量浓度数据,2019年3月—2019年6月反应性气体数据,对华中区域空气质量进行整体评价,并分析了颗粒物浓度的变化特征及其影响因素。结果表明,反应性气体CO、SO₂、NO、NO₂质量浓度其日平均最大值、平均值均达到一级标准,O₃日平均值超标率为10.6%,PM_2.5超标率为18%,PM₁₀超标率为17%。从颗粒物质量浓度多年变化来看,2007—2013年金沙站大气颗粒物质量浓度属于上升趋势,2013年至今质量浓度呈现下降趋势,风向风速也在一定程度上影响颗粒物的来源。     

20世纪末广东省三大城市大气环境质量综合评价——改进密切值法的扩展应用

大气环境质量综合评价是一个城市环境质量考核的重要指标，改进的密切值法是其中一种切实可行的评价方法。通过对1991-2000年10年间广东省三大城市——广州、深圳和珠海的大气环境质量进行综合评价，发现20世纪末，大气环境质量最好的是珠海市，最差的是广州市。与广东省平均水平相比、三大城市中。广州市污染程度高于全省平均水平。从空气环境质量的变化趋势来看，自1997年开始，三大城市大气环境质量趋于好转，为新世纪城市空气环境质量改善提供了良好的基础。     

Magnetostratigraphic evidence from the Cold Creek bar for onset of ice-age cataclysmic floods in eastern Washington during the Early Pleistocene

This study provides a detailed magnetostratigraphy of sediments composing the Cold Creek cataclysmic flood bar in the Pasco Basin, Washington. Our interpretation suggests onset of Missoula floods or similar events prior to 1.1 myr, later than previously suggested by Bjornstad et al. [Bjornstad, B.N., Fecht, K.R., Pluhar, C.J., 2001. Long history of pre-Wisconsin, Ice Age cataclysmic floods: evidence from southeastern Washington State. Journal of Geology 109 (6), 695-713]. Nonetheless these data suggest that Channeled Scabland features formed over a much longer timespan than commonly cited, that continental ice sheets of the early Pleistocene reached as far south as those of the late Pleistocene, and that similar physiography existed in eastern Washington and perhaps Montana to both generate and route Missoula-flood-like events. This study adds paleomagnetic polarity results from 213 new samples of silts and sands derived from nine new drill cores penetrating the Cold Creek cataclysmic flood bar to our previous database of 53 samples from four boreholes, resulting in a much more robust and detailed magnetostratigraphy. Rock magnetic studies on these sediments show pure magnetite to be the predominant remanence-carrying magnetic mineral, ruling out widespread remagnetization by secondary mineralization. The magnetostratigraphy at eastern Cold Creek bar is characterized by a normal polarity interval bracketed by reversed polarities. Equating the normal zone with the Jaramillo subchron (0.99-1.07 myr) affords the simplest correlation to the magnetic polarity timescale. Western Cold Creek bar was likely deposited during the Brunhes chron (0-0.78 myr) since it exhibits mainly normal polarities with only two thin reversed-polarity horizons that we interpret as magnetic excursions during the Brunhes.     

Occurrence of microorganic pollutants in the atmosphere of Singapore during haze and non-haze periods

Microorganic pollutants such as polycylic aromatic hydrocarbons （PAHs）, organochlorine pesticides （OCPs）, polychlorinated biphenyls （PCBs） and total petroleum hydrocarbons （TPHs） are known to be present in urban ambient air. These organic compounds are prone to atmospheric transport and deposition over long distances, thus enabling them to accumulate even in regions remote from their sources. Deposition from the atmosphere can be via direct deposition and exchange with crops that may be directly or indirectly ingested by humans. It can also take place via wet and dry deposition and air-water exchange. Following their deposition, these microorganic pollutants tend to accumulate in soils, sediments and in human and ecological food chains. There are many reports in the literature on the atmospheric concentrations of microorganic pollutants, but there are few reports and data in Asia. This study was performed in Singapore to determine the relative amounts of persistent organic pollutants and TPHs in ambient aerosols. One of the important sources of these organic compounds in Southeast Asia is thought to be biomass burning （vegetation fires）. Hence, air sampling was conducted during both smoke haze and non-haze periods. The data obtained from this study will be presented and discussed.     

Lower Eocene carbonate-cemented “chimney” structures (Varna, Bulgaria) — Control of seepage rates on their formation and stable isotopic signature

The genesis of Lower Eocene calcite-cemented columns, “pisoid”-covered structures and horizontal interbeds, clustered in dispersed outcrops in the Pobiti Kamani area (Varna, Bulgaria) is related to fossil processes of hydrocarbon migration. Field observations, petrography and stable isotope geochemistry of the cemented structures and associated early-diagenetic veins, revealed that varying seepage rates of a single, warm hydrocarbon-bearing fluid, probably ascending along active faults, controlled the type of structure formed and its geochemical signature. Slow seepage allowed methane to oxidize within the sediment under ambient seafloor conditions (δ¹⁸O = − 1 ± 0.5‰ V-PDB), explaining columns' depleted δ¹³C ratios of − 43‰. Increasing seepage rates caused methane to emanate into the water column (δ¹³C = − 8‰) and raised precipitation temperatures (δ¹⁸O = − 8‰). Calcite-cemented conduits formed and upward migrating fluids also affected interbed cementation. Even higher-energy fluid flow and temperatures likely controlled the formation of “pisoids”, whereby sediment was whirled up and cemented.     

Timing of the late-glacial climate reversal in the Southern Hemisphere using high-resolution radiocarbon chronology for Kaipo bog, New Zealand

The pattern of climate change in the Southern Hemisphere during the Younger Dryas (YD) chronozone provides essential constraint on mechanisms of abrupt climate change only if accurate, high-precision chronologies are obtained. A climate reversal reported previously at Kaipo bog, New Zealand, had been dated between 13,600 and 12,600 cal yr B.P. and appeared to asynchronously overlap the YD chron, but the chronology, based on conventionally radiocarbon-dated bulk sediment samples, left the precise timing questionable. We report a new high-resolution AMS ¹⁴C chronology for the Kaipo record that confirms the original chronology and provides further evidence for a mid-latitude Southern Ocean cooling event dated between 13,800 and 12,400 cal yr B.P. (2σ range), roughly equivalent to the Antarctic Cold Reversal.     

Study of geothermal water intrusion due to groundwater exploitation in the Puebla Valley aquifer system, Mexico

Significant intrusion of geothermal water into fresh groundwater takes place in the Puebla Valley aquifer system, Mexico. The decline in the potentiometric surface due to the overexploitation of the groundwater induces this intrusion. This hydrological system comprises three aquifers located in Plio-Quaternary volcanic sediments and Mesozoic calcareous rocks. The hydraulic balance of the aquifer shows that the annual output exceeds the natural inputs by 12 million m³. Between 1973 and 2002, a drop in the potentiometric surface, with an 80 m cone of depression, was identified in a 5-km-wide area located southwest of the city of Puebla. Chemical analyses performed on water samples since 1990 have shown an increase in total dissolved solids (TDS) of more than 500 mg/L, coinciding with the region showing a cone of depression in the potentiometric surface. A three-dimensional flow and transport model, based on the hydrogeological and geophysical studies, was computed by using the MODFLOW and MT3D software. This model reproduces the evolution of the aquifer system during the last 30 years and predicts for 2010 an additional drawdown in the potentiometric surface of 15 m, and an increase in the geothermal water intrusion.