酸性流体对碳酸盐岩储层的改造作用

普遍认为CO2、有机酸及H2S是碳酸盐岩储层溶蚀作用的酸性流体。CO2对碳酸盐岩储层的溶蚀作用已有不少学者进行了研究,本文则以一个全新的模拟实验方式对不同类型碳酸盐岩在有机酸和H2S水溶液中的相对溶蚀能力进行了研究,结果发现随温度从常温升高至200℃,有机酸对碳酸盐岩的溶蚀能力由弱变强再变弱,在90℃左右溶蚀能力最强。而H2S水溶液对碳酸盐岩的溶蚀作用则明显不同,60℃时基本达到最大溶蚀率,温度继续升高后,溶蚀能力一直维持在较高的水平并略有增加,150℃后突然降低。由于H2S主要是硫酸盐高温热还原产物（TSR）,因而在碳酸盐岩成岩早期阶段,溶蚀作用的流体可能主要是有机酸和C02,而在深埋阶段,H2S水溶液则可能是溶蚀作用的主要流体。     

ICESat-2植被冠层高度和地表高程数据产品用于森林高度提取的效果评价

由美国宇航局（NASA）研制的新一代冰、云和陆地高程卫星（ICESat-2）于2018-09-15发射成功,其搭载的先进地形激光测高系统（ATLAS）采用微脉冲多波束光子计数激光雷达技术,可用于全球高程线采样数据的获取。目前公开发布了9种数据产品,其中包括植被冠层高度和地表高程数据产品（ATL08）,为全球森林结构参数的估算提供了新的契机。本文以美国宾夕法尼亚州斯奈德县和印度尼西亚西加里曼丹吉打邦为研究区,在温带森林和热带雨林两种不同的生态系统立地条件下,对 ICESat-2的ATL08数据产品用于森林高度估算的效果进行评价。首先建立了地形高程数据产品（ATL03）与ATL08数据产品的关联规则,以获取分别记录在这两种产品中的光子空间分布信息和分类信息;进而以机载小光斑激光雷达数据为参考,对ATL08数据产品的光子分类可靠性及其用于森林高度估算的准确性进行了分析评价。结果表明：（1）在温带森林情况下,ATL08数据产品提供的平均冠层高度和最大冠层高度与参考数据的相关系数（R2）分别为0.54和0.61,相对误差分别为16.78%和10.71%,表明ATL08数据产品的光子分类结果能够用于刻画森林冠层结构和林下地形;（2）在热带雨林情况下,到达地面的光子数量相较于温带森林明显减少,地面光子类型识别的可靠性低,ATL08数据产品提供的平均冠层高度和最大冠层高度与参考数据的相关系数（R2）分别为0.21和0.19;（3）森林覆盖度的增大会导致ATL08计算的冠层高度误差增大,热带雨林平均冠层高度的误差随着坡度增大有增大趋势,在坡度为0°—10°、10°—20°和20°—30°共3组情况下,误差分别为5.7 m、6.6 m和9.3 m。因此,在高森林覆盖度情况下,现有的ATL08数据产品难以直接用于森林高度的提取。     

单窗算法的大气参数估计方法

根据地表热辐射传导方程,提出了一个简单可行且精度较高的专门用于从TM6数据中演算地表温度的方法——单窗算法.这一算法把大气和地表状态对地表热传导的影响直接包括在演算公式中.该方法需要两个大气参数进行地表温度的演算,即大气平均作用温度和大气透射率.本文论述这两个大气参数的估计方法:根据大气水分含量或地表附近空气湿度来估计大气透射率;通过分析标准大气剖面资料,尤其是大气水分和气温随高程的变化规律,根据地表温度推算大气平均作用温度.     

埃文斯目视日晕光度计测量原理研究

埃文斯目视日晕光度计（Evans Visual Sky Photometer,EVSP）是应用于日冕仪选址的重要仪器,从20世纪40年代一直使用至今,它为现代日晕光度计的定标提供了参考标准。通过使用云南天文台现存的一架EVSP研究了它的工作原理,并重点介绍了所利用的简易定标方法。给出了国际现有的多台EVSP日晕亮度定标曲线。由于EVSP内部光学元件反射率和透过率,以及中性渐变光楔的光学密度等存在未知的时间缓变特点,因此利用这种新定标手段可以高效经济地获得各自的定标曲线。     

川滇地区电离层多参量异常监测系统的设计与实现

介绍了川滇地区电离层多参量异常监测系统的设计思路与功能实现,并将该系统应用于2019年6月17日四川长宁M_S6.0地震的监测试验。结果表明:该系统实现了全球和中国区域垂直总电子含量VTEC、站点VTEC和F₂层临界频率f_oF₂异常变化的实时监测,有助于开展示范性地震电离层异常监测工作,其图形及数据结果可为地震-电离层异常扰动判识提供佐证,为川滇地区地震监测预报提供电离层前兆信息支持。      

Improved understanding of dynamic water and mass budgets of high-alpine karst systems obtained from studying a well-defined catchment area

Large areas of Europe, especially in the Alps, are covered by carbonate rocks and in many alpine regions, karst springs are important sources for drinking water supply. Because of their high variability and heterogeneity, the understanding of the hydrogeological functioning of karst aquifers is of particular importance for their protection and utilisation. Climate change and heavy rainfall events are major challenges in managing alpine karst aquifers which possess an enormous potential for future drinking water supply. In this study, we present research from a high-alpine karst system in the UNESCO Biosphere Reserve Großes Walsertal in Austria, which has a clearly defined catchment and is drained by only one spring system. Results show that (a) the investigated system is a highly dynamic karst aquifer with distinct reactions to rainfall events in discharge and electrical conductivity; (b) the estimated transient atmospheric CO₂ sink is about 270 t/a; (c) the calculated carbonate rock denudation rate is between 23 and 47 mm/1000a and (d) the rainfall-discharge behaviour and the internal flow dynamics can be successfully simulated using the modelling package KarstMod. The modelling results indicate the relevance of matrix storage in determining the discharge behaviour of the spring, particularly during low-flow periods. This research and the consequent results can contribute and initiate a better understanding and management of alpine karst aquifers considering climate change with more heavy rainfall events and also longer dry periods.     

Atmospheric inputs of trace metals to the northeast Atlantic Ocean: the importance of southeasterly flow

The study of aerosols and rainwater presented here demonstrates that episodic atmospheric deposition events associated with southeasterly flow are quantitatively significant for large areas of the North Atlantic Ocean. This paper considers aluminium and manganese, with predominantly crustal sources, and lead and zinc, which are mobilised into the atmosphere primarily through anthropogenic activity. High levels of all trace metals are associated with southeasterly flow from Europe as the air passes over heavily populated and industrialised regions before reaching the northeast Atlantic Ocean. Fluxes calculated using the 1% HNO₃ acid soluble metal concentration show that, although the climatological norm for this area is westerly flow, short-lived southeasterly transport events dominate the input of trace metals to this ocean region. This material may be toxic to phytoplankton or may be represent a new source of nutrients to the biological community. A significant decrease in atmospheric lead levels in polluted air is seen between June 1996 and May 1997, reflecting the decrease in use of leaded fuels in Europe. Comparing atmospheric flux values to sediment trap metal fluxes shows that the atmosphere represents the dominant source of zinc to the deep ocean, whereas an additional, non-atmospheric, manganese source this required, perhaps from mobilisation of sedimentary material from the continental shelf or long range advection of manganese rich Saharan material.     

Multiple sulfur isotope chemostratigraphy across the Permian–Triassic boundary at Chaotian,China: Implications for a shoaling model of toxic deep-waters

Previous studies on multiple sulfur isotopes (³²S, ³³S, and ³⁴S) in sedimentary pyrite at the end-Permian suggested a shoaling of anoxic/sulfidic deep-water contributing to the extinction. This scenario is based on an assumption that the sedimentary sulfur cycle was largely controlled by benthos activity, though a stratigraphic correlation between the sulfur records and ichnofabrics of the sediments at the end-Permian has not yet been examined. We report the multiple sulfur isotopic composition of pyrite in the Permian–Triassic boundary interval at Chaotian, South China. Our data can be generally explained by a mixing of sulfur in sulfide from two different sources: one produced via sulfate reduction in an open system with respect to sulfate and the other produced in a closed system. In particular, the former with the substantially low δ³⁴S (<−40 ‰) and high ∆³³S (up to +0.100 ‰) values was likely produced via water-mass sulfate reduction or via sulfate reduction in oxic sediments with common burrows. The frequent occurrence of small pyrite framboids (mostly <5 μm in diameter) in the Lopingian (Late Permian) Dalong Formation of deep-water facies supports the enhanced water-mass sulfate reduction in an anoxic deep-water mass. The negative ∆³³S values are observed only in the oxic limestones, and no substantial ∆³³S change is observed across the extinction horizon despite of the disappearance of bioturbation. Our results are apparently inconsistent with the previous shoaling model. We expand the model and infer that, when the deep-water was sulfidic and its shoaling rate was high, a substantial amount of hydrogen sulfide (H₂S) was supplied onto the shelf via the shoaling; that resulted in the positive ∆³³S value of the bulk sediments. The observed ∆³³S variation on a global scale suggests a substantial variation in H₂S concentration and/or in upwelling rate of shoaling deep-waters during the Permian–Triassic transition.     

边界层湍流输送的若干问题和大气线性热力学

总结了大气线性热力学基本理论,讨论了大气边界层的能量和物质输送交叉耦合效应,还讨论了大气系统动力过程和热力过程的交叉耦合效应。分析指出：由于动力过程和热力过程的交叉耦合效应,导致大气边界层能量和物质输送过程除了湍流输送外,还应包括大气辐散和辐合运动对能量和物质的输送。非均匀下垫面大气边界层和对流边界层辐散和辐合运动对能量和物质输送是重要的。在这个基础上,讨论了非均匀下垫面和对流边界层地表能量的平衡问题,非均匀下垫面和对流边界层陆面过程边界层参数化等问题。这些研究不仅丰富了大气边界层物理理论,而且为克服当前大气边界层物理应用中所遇到的困难提供了理论依据。     

中国春季沙尘暴的趋势变化及年代际变化

利用奇异谱分析等方法,对北疆等7个区春季1960—2000年的沙尘暴日数的趋势和周期进行了初步分析,结果表明：除北疆区未表现出明显的趋势外,南疆区等其它6个区春季沙尘暴日数变化总的趋势是减少的,都是在20世纪60年代和70年代偏多,80年代沙尘暴开始减少,90年代最少;其中南疆区、河西区和东北区的年代际变化最为明显,大约是80年代初开始沙尘暴明显减少,其它几个区的年代际变化不是很明显。南疆等大部分地区春季的沙尘暴日数在70年代末和80年代初发生了由多到少的转变,基本上与北半球大气环流的调整同步,这可能是对大气环流调整的响应;除西藏区有7．7年的周期外,其它6个区的周期基本上都集中在准2年和5～6年两个周期段。