The Production of Methanol by Flowering Plants and the Global Cycle of Methanol

Methanol has been recognised as an important constituent of the background atmosphere, but little is known about its overall cycle in the biosphere/atmosphere system. A model is proposed for the production and emission to the atmosphere of methanol by flowering plants based on plant structure and metabolic properties, particularly the demethylation of pectin in the primary cell walls. This model provides a framework to extend seven sets of measurements of methanol emission rates to the global terrestrial biosphere. A global rate of release of methanol from plants to the atmosphere of 100 Tg y^–1 is calculated. A separate model of the global cycle of methanol is constructed involving emissions from plant growth and decay, atmospheric and oceanic chemical production, biomass burning and industrial production. Removal processes occur through hydroxyl radical attack in the atmosphere, in clouds and oceans, and wet and dry deposition. The model successfully reproduces the methanol concentrations in the continental boundary-layer and the free atmosphere, including the inter-hemispheric gradient in the free atmosphere. The model demonstrates a new concept in global biogeochemistry, the coupling of plant cell growth with the global atmospheric concentration of methanol. The model indicates that the ocean provides a storage reservoir capable of holding at least 66 times more methanol than the atmosphere. The ocean surface layer reservoir essentially buffers the atmospheric concentration of methanol, providing a physically based smoothing mechanism with a time constant of the order of one year.     

挑战地球科学的新前沿 21世纪大洋综合钻探计划(OD21)

简要介绍即将实施的“21世纪大洋综合钻探计划”的目的、要求、设施等。     

Changes in the mode of Southern Ocean circulation over the last glacial cycle revealed by foraminiferal stable isotopic variability

Benthic foraminiferal oxygen and carbon isotopic records from Southern Ocean sediment cores show that during the last glacial period, the South Atlantic sector of the deep Southern Ocean filled to roughly 2500 m with water uniformly low in δ¹³C, resulting in the appearance of a strong mid-depth nutricline similar to those observed in glacial northern oceans. Concomitantly, deep water isotopic gradients developed between the Pacific and Atlantic sectors of the Southern Ocean; the δ¹³C of benthic foraminifera in Pacific sediments remained significantly higher than those in the Atlantic during the glacial episode. These two observations help to define the extent of what has become known as the ‘Southern Ocean low δ¹³C problem’. One explanation for this glacial distribution of δ¹³C calls upon surface productivity overprints or changes in the microhabitat of benthic foraminifera to lower glacial age δ¹³C values. We show here, however, that glacial-interglacial δ¹³C shifts are similarly large everywhere in the deep South Atlantic, regardless of productivity regime or sedimentary environment. Furthermore, the degree of isotopic decoupling between the Atlantic and Pacific basins is proportional to the magnitude of δ¹³C change in the Atlantic on all time scales. Thus, we conclude that the profoundly altered distribution of δ¹³C in the glacial Southern Ocean is most likely the result of deep ocean circulation changes. While the characteristics of the Southern Ocean δ¹³C records clearly point to reduced North Atlantic Deep Water input during glacial periods, the basinal differences suggest that the mode of Southern Ocean deep water formation must have been altered as well.     

内蒙古达茂旗北部奥陶纪花岗岩类特征及其构造意义

研究区奥陶纪花岗岩分布于乌兰布拉格 -哥舍深大断裂 (槽台断裂 )以北 ,岩石类型主要有闪长岩、石英闪长岩、斜长花岗岩和花岗闪长岩。岩石中 Si O2 质量分数为 5 6.76%～ 69.2 4 % ,Al2 O3较高 (多 >1 6% ) ,富 Na2 O贫 K2 O,A/ CNK均 <1 .1 ,为准铝质的钙碱性岩石系列。稀土总量普遍较低 ,为 (63 .4 1～ 1 4 0 .61 )× 1 0 - 6 ,轻重稀土分馏强烈 ,铕异常不明显 (δEu=0 .95～1 .2 2 6)。痕量元素特征与典型的火山弧花岗岩相似。结合区域地质背景 ,认为该套花岗岩类为与洋壳消减有关的岛弧型花岗岩 ,岩浆起源于加厚陆壳的底部。从花岗岩的分布及迁移规律推测 ,华北陆块与其北缘增生带之间的早古生代洋壳可能是由南西向北东的斜向消减     

大洋多金属结核研究概况

从多金属结核的分布及富集规律、物质成分、内部结构、形成机制等方面论述了目前国内外的一些研究动态,对目前在这一研究领域提出的一些新概念、新方法作了一定的介绍.在分析和总结前人研究成果的基础上,指出了在这一研究领域还存在的一些问题及今后研究的方向.     

等离子体发射光谱法直接测定海洋沉积物中的微量稀土元素

应用全谱直读电感耦合等离子体发射光谱法对海洋沉积物中微量稀土元素的测定进行了研究，选择了最佳的仪器工作条件，采用多谱线拟合技术进行校正，样品的加标回收率为94．0％-110．0％。方法采用海底沉积物国家一级标准物质进行验证，测定结果与标准值较吻合，各元素10次测定的RSD≤11．3％。     

GPS精密定位中的海潮位移改正

根据海洋负荷潮理论，利用NAO99b全球海潮模型，计算了中国部分IGS站的海潮位移改正，并将海潮位移改正应用到GPS数据处理当中。在GAMIT软件的解算过程中，分别按加入和不加入海潮位移改正，对GPS基线分量和测站坐标分别进行了计算和比较分析。结果表明，海潮位移改正无论是对GPS基线分量还是对测站坐标，都有一定的影响。     

ENSO事件中纬向异常流反向与东西侧边界反射的联系

建立一个中等复杂程度的海-气耦合模式研究东、西边界反射,纬向平流项-u′(δ)(T+T′)/(δ)x在ENSO循环位相转换中的作用及东、西边界反射与纬向异常流(u′) 符号改变的关系.结果得到:u′超前Nio3区SSTA位相转变的原因是东、西边界反射造成的.Sverdrup 平衡时所产生的地转流(ur)与东、西边界反射所产生的地转流(ur)的方向在大部分时间里是相反的,同时ur与风应力强迫之间大约有9个月的滞后时间(Kelvin波从180°E出发经东边界反射产生的Rossby波到达180°E时间).在模式ENSO事件消亡过程中的某一时刻以后,边界反射产生的调整过程变为主要过程,u′主要由ur来决定,这样就造成了u′的反向先于Nio区SSTA的反向.它实际上是海洋的调整过程与风应力强迫之间滞后关系的一种反映.敏感性数值试验表明,取消东边界反射,耦合模式能够模拟ENSO循环,但其周期比控制试验的周期短一年(3年).取消-u′(δ)(T+T′)/(δ)x,耦合模式能够模拟ENSO循环,但其周期比控制试验的周期长2年(6年).     

一个大洋环流模式和相应的海气耦合模式的评估 I.热带太平洋年平均状态

评估了中国科学院大气物理研究所大气科学和地球流体动力学数值模拟国家重点实验室海洋环流模式L30T63和海气耦合模式FGCM 0模拟的热带太平洋年平均状态 ,资料取自L30T63由观测的大气强迫驱动的Control试验、由NCARCCM3大气强迫驱动的Spinup试验、以及相应的海气耦合模式FGCM 0。主要的结论是 :( 1 )在“准确”的海表强迫下 ,Control模拟的海面温度和温跃层与观测结果相当接近 ,模式的固有误差是赤道冷舌过分西伸和东南太平洋温跃层偏浅。 ( 2 )Spinup能模拟出合理的热带太平洋上层海洋环流 ,但存在两个问题 ,即 :暖池区海面温度显著偏高、沿赤道的梯度过大 ;赤道温跃层偏浅、东西向坡度偏小 ,它们分别与CCM3提供的海表短波辐射通量和风应力的系统误差有关。这两个问题很可能是海气耦合模式FGCM 0运行初期误差迅速发展的重要原因。 ( 3)FGCM 0模拟的赤道暖池区上层 1 0 0m的平均温度比观测低 3℃。分析表明FGCM 0夸大了暖池区海洋动力过程的降温作用 ,使得模拟的“暖池”在一定程度上具有冷舌的属性。FGCM 0模拟的热带南太平洋温跃层比观测结果偏浅数十米到 1 0 0m ,以致赤道两侧的上层海洋温度分布趋于对称 ,成为“doubleITCZ”现象在上层海洋中的表现。风应力旋度的系统误差和垂直混合随深度衰减过快     

A TWO-LAYER PRIMITIVE EQUATION OCEAN CURRENT MODEL AND ITS SIMULATION

A two-layer primitive equation model is developed in this paper. The capabilities of this model aretested by the use of multiyearly averaged January and July sea surface level pressure fields and windfields which can be diagnosed from the pressure fields. The results show that the ocean surface currentsand undercurrents in the second layer driven by the sea surface wind and the sea surface pressure areclose to the observation. The results are also compared with that of the IAP OGCM and the OSUOGCM.