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91.
Li isotopes and trace elements as a petrogenetic tracer in zircon: insights from Archean TTGs and sanukitoids 总被引:1,自引:0,他引:1
Anne-Sophie Bouvier Takayuki Ushikubo Noriko T. Kita Aaron J. Cavosie Reinhard Kozdon John W. Valley 《Contributions to Mineralogy and Petrology》2012,163(5):745-768
We report δ7Li, Li abundance ([Li]), and other trace elements measured by ion probe in igneous zircons from TTG (tonalite, trondhjemite,
and granodiorite) and sanukitoid plutons from the Superior Province (Canada) in order to characterize Li in zircons from typical
Archean continental crust. These data are compared with detrital zircons from the Jack Hills (Western Australia) with U–Pb
ages greater than 3.9 Ga for which parent rock type is not known. Most of the TTG and sanukitoid zircon domains preserve typical
igneous REE patterns and CL zoning. [Li] ranges from 0.5 to 79 ppm, typical of [Li] in continental zircons. Atomic ratios
of (Y + REE)/(Li + P) average 1.0 ± 0.7 (2SD) for zircons with magmatic composition preserved, supporting the hypothesis that
Li is interstitial and charge compensates substitution of trivalent cations. This substitution results in a relatively slow
rate of Li diffusion. The δ7Li and trace element data constrain the genesis of TTGs and sanukitoids. [Li] in zircons from granitoids is significantly
higher than from zircons in primitive magmas in oceanic crust. TTG zircons have δ7Li (3 ± 8‰) and δ18O in the range of primitive mantle-derived magmas. Sanukitoid zircons have average δ7Li (7 ± 8‰) and δ18O higher than those of TTGs supporting genesis by melting of fluid-metasomatized mantle wedge. The Li systematics in sanukitoid
and TTG zircons indicate that high [Li] in pre-3.9-Ga Jack Hills detrital zircons is a primary igneous composition and suggests
the growth in proto-continental crust in magmas similar to Archean granitoids. 相似文献
92.
John M. Ferry Takayuki Ushikubo John W. Valley 《Geochimica et cosmochimica acta》2010,74(22):6517-6540
Nineteen samples of metamorphosed carbonate-bearing rocks were analyzed for carbon and oxygen isotope ratios by ion microprobe with a ∼5-15 μm spot, three from a regional terrain and 16 from five different contact aureoles. Contact metamorphic rocks further represent four groups: calc-silicate marble and hornfels (6), brucite marble (2), samples that contain a reaction front (4), and samples with a pervasive distribution of reactants and products of a decarbonation reaction (4). The average spot-to-spot reproducibility of standard calcite analyses is ±0.37‰ (2 standard deviations, SD) for δ18O and ±0.71‰ for δ13C. Ten or more measurements of a mineral in a sample that has uniform isotope composition within error of measurement can routinely return a weighted mean with a 95% confidence interval of 0.09-0.16‰ for δ18O and 0.10-0.29‰ for δ13C. Using a difference of >6SD as the criterion, only four of 19 analyzed samples exhibit significant intracrystalline and/or intercrystalline inhomogeneity in δ13C at the 100-500 μm scale, with differences within individual grains up to 3.7‰. Measurements are consistent with carbon isotope exchange equilibrium between calcite and dolomite in five of six analyzed samples at the same scale. Because of relatively slow carbon isotope diffusion in calcite and dolomite, differences in δ13C can survive intracrystalline homogenization by diffusion during cooling after peak metamorphism and likely represent the effects of prograde decarbonation and infiltration. All but 2 of 11 analyzed samples exhibit intracrystalline differences in δ18O (up to 9.4‰), intercrystalline inhomogeneity in δ18O (up to 12.5‰), and/or disequilibrium oxygen isotope fractionations among calcite-dolomite, calcite-quartz, and calcite-forsterite pairs at the 100-500 μm scale. Inhomogeneities in δ18O and δ13C are poorly correlated with only a single mineral (dolomite) in a single sample exhibiting both. Because of relatively rapid oxygen isotope diffusion in calcite, intracrystalline inhomogeneities in δ18O likely represent partial equilibration between calcite and fluid during retrograde metamorphism. Calcite is in oxygen isotope exchange equilibrium with forsterite in one of four analyzed samples, in equilibrium with dolomite in none of six analyzed samples, and in equilibrium with quartz in neither of two analyzed samples. There are no samples of contact metamorphic rock with analyzed reactants and products of an arrested metamorphic reaction that are in oxygen isotope equilibrium with each other. The degree of departure from equilibrium in analyzed samples is variable and is often related, at least in part, to alteration of δ18O of calcite during retrograde fluid-rock reaction. In situ sub-grain-scale carbon and oxygen isotope analyses of minerals are advisable in the common applications of stable isotope geochemistry to metamorphic petrology. Correlation of sub-mm scale stable isotope data with imaging will lead to improved understanding of reaction kinetics, reactive fluid flow, and thermal histories during metamorphism. 相似文献
93.
In the equatorial plasmasphere, plasma waves are frequently observed. To improve our understanding of the mechanism generating plasma waves from instabilities, a comparison of observations, linear growth-rate calculations, and simulation results is presented. To start the numerical experiments from realistic initial plasma conditions, we use the initial parameters inferred from observational data obtained around the plasma-wave generation region by the Akebono satellite. The linear growth rates of waves of different modes are calculated under resonance conditions, and compared with simulation results and observations. By employing numerical experiments by a particle code, we first show that upper hybrid-, Z-, and whistler-mode waves are excited through instabilities driven by a ring-type velocity distribution. The simulation results suggest a possibility that energetic electrons with energies of some tens of keV confined around the geomagnetic equator are responsible for the observed enhancements of Z- and whistler-mode waves. While the comparison between linear growth-rate calculations and observations shows the different tendency of wave amplitude of Z-mode and whistler-mode waves, the wave amplitude of these wave modes in the simulation results is consistent with the observation. 相似文献
94.
Koichiro Fujimoto Hidemi Tanaka Takayuki Higuchi Naoto Tomida Tomoyuki Ohtani Hisao Ito 《Island Arc》2001,10(3-4):401-410
Abstract Mineralogical and geochemical studies on the fault rocks from the Nojima–Hirabayashi borehole, south-west Japan, are performed to clarify the alteration and mass transfer in the Nojima Fault Zone at shallow depths. A complete sequence from the hornblende–biotite granodiorite protolith to the fault core can be observed without serious disorganization by surface weathering. The parts deeper than 426.2 m are in the fault zone where rocks have suffered fault-related deformation and alteration. Characteristic alteration minerals in the fault zone are smectite, zeolites (laumontite, stilbite), and carbonate minerals (calcite and siderite). It is inferred that laumontite veins formed at temperatures higher than approximately 100°C during the fault activity. A reverse component in the movement of the Nojima Fault influences the distribution of zeolites. Zeolite is the main sealing mineral in relatively deep parts, whereas carbonate is the main sealing mineral at shallower depths. Several shear zones are recognized in the fault zone. Intense alteration is localized in the gouge zones. Rock chemistry changes in a different manner between different shear zones in the fault zone. The main shear zone (MSZ), which corresponds to the core of the Nojima Fault, shows increased concentration of most elements except Si, Al, Na, and K. However, a lower shear zone (LSZ-2), which is characterized by intense alteration rather than cataclastic deformation, shows a decreased concentration of most elements including Ti and Zr. A simple volume change analysis based on Ti and Zr immobility, commonly used to examine the changes in fault rock chemistry, cannot account fully for the different behaviors of Ti and Zr among the two gouge zones. 相似文献
95.
Takayuki Ishikawa Jinro Ukita Kay I. Ohshima Masaaki Wakatsuchi Takashi Yamanouchi Nobuo Ono 《Journal of Oceanography》1996,52(3):389-398
Coastal polynyas off East Queen Maud Land in Antarctica are examined using NOAA AVHRR infrared data. From image analyses, two locations of coastal polynyas in this region are identified; one in Breid Bay and the other along the shelf break. The areal coverage of the Breid Bay polynya is significantly related to the strength of katabatic winds, which maintain their strength over the coastal sea due to land topography favoring for their confluence, thereby being capable of removing newly formed ice. Land fast ice in the eastern part of the bay also plays an additional role in the formation mechanism. It is also found that the areal coverage of coastal polynyas in this region fluctuate coherently. Moreover, these fluctuations correspond to the synoptic index, which measures the strength of the offshore wind, with their peaks closely associated with the areal peaks. These facts strongly suggest the influence of synoptic scale weather on the formation and maintenance of polynyas in this region. 相似文献
96.
Akira Imai Yukiko Ohbuchi Takayuki Tanaka Seiya Morita Kentaro Yasunaga 《Resource Geology》2007,57(4):374-385
The porphyry Cu deposits at Waisoi in Namosi district, Viti Levu are separated into two deposits: the Waisoi East deposit and the Waisoi West deposit. In the Waisoi East deposit, quartz porphyry is exposed and in the Waisoi West deposit, diorite porphyry is sporadically exposed in addition to a small body of quartz porphyry. The mineralization in the Waisoi East deposit is characterized by the bornite–chalcopyrite–pyrite assemblage associated with traces of molybdenite and native gold. Polyphase fluid inclusions in stockwork quartz veinlets show homogenization temperatures ranging from 210 to >500°C. The high‐grade Cu mineralization in the Waisoi West deposit is characterized by the bornite–chalcopyrite–pyrite assemblage accompanied with sheeted and stockwork quartz veinlets. Polyphase fluid inclusions occasionally containing hematite flakes in quartz veinlets in the center of the Waisoi West deposit homogenize at temperatures ranging from 450°C to >500°C. However, fluid inclusions in stockwork quartz veinlets in the periphery, homogenize at lower temperatures around 210°C. Both in the Waisoi East and Waisoi West deposits, primary bornite–chalcopyrite–pyrite assemblage in the high Cu‐grade zone was deposited at the upper stability limit of chalcopyrite with respect to sulfur fugacity. Thus, the principal Cu mineralization at the Waisoi deposits occurred at a relatively high sulfur fugacity, that is, in a high‐sulfidation environment. 相似文献
97.
Toshio Kataoka Eiji Yunoki Mitsuo Shimizu Tadashige Mori Osamu Tsukamoto Satoshi Takahashi Hironori Fudeyasu Yukitaka Ohashi Ken Sahashi Toshihiko Maitani Koh'ichi Miyashita Toru Iwata Takayuki Sasaki Yoko Fujikawa Akira Kudo Roger H. Shaw 《Boundary-Layer Meteorology》2003,107(1):219-249
Atmospheric activity concentrations of 212Pb and short-lived 222Rndaughters, together with meteorological elements, have been observed continuously atthree sites at Kamisaibara Village in Japan. In addition, atmospheric activity concentrationof 222Rn, equilibrium-equivalent concentration of 222Rn and conditionsof the lower atmosphere were observed for three intensive observation periods at Akawase,one of the three sites in Kamisaibara Village. The equilibrium-equivalent concentration of222Rn is almost the same as the atmospheric activity concentration of short-lived222Rn daughters.The activity concentrations of 212Pb and the short-lived 222Rn daughtersand their ratio were low in the daytime owing to convective mixing, and high at nightowing to the surface-based inversion during periods of no precipitation. Their variationshave several patterns corresponding to the scale of the drainage wind or weak mixing.Mechanical mixing due to strong winds through both day and night during the first andsecond observation periods made the atmospheric activity concentrations of 212Pb and the short-lived 222Rn daughters continuously low. However, their ratios werecontinuously high during the first period yet continuously low during the second period.This difference can be explained by the effect ofextraction of 220Rn and 222Rndue to strong winds and snow cover. There were also cases in which the ratio of theatmospheric activity concentration of 212Pb to that of the short-lived 222Rndaughters at night was equal to or less than the ratio in the daytime. Thisinverse trend, asin the periods of no precipitation mentioned above, is considered to be due to near-neutralconditions on these nights.We find a difference in the ratio of the equilibrium-equivalent concentration of222Rn (the activity concentration of short-lived 222Rn daughters) tothe activity concentration of 222Rn during the first observation period and thatduring the second. The difference can be explained by snow cover on the ground. Wealso find differences among the ratios of the activity concentration of the short-lived222Rn daughters to that of 222Rn during the three observation periods.These differences can be explained by the submergence of paddy fields. 相似文献
98.
99.
Munetake Sasaki Koichiro Fujimoto Hitoshi Tsukamoto Takayuki Sawaki Masakatsu Sasada Masanori Kurosawa Masahiko Yagi Yoichi Muramatsu Osamu Kato + Ryo Komatsu + Kaichiro Kasai + Nobuo Doi+ 《Resource Geology》2003,53(2):127-142
Abstract. Cathodoluminescence (CL) color, rare earth element (REE) content, sulfur and oxygen isotopes and fluid inclusions of anhydrite, which frequently filled in hydrothermal veins in the Kakkonda geothermal system, were investigated to elucidate the spatial, temporal and genetical evolution of fluids in the deep reservoir. The anhydrite samples studied are classified into four types based on CL colors and REE contents: type-N (no color), type-G (green color), type-T (tan color) and type-S (tan color with a high REE content). In the shallow reservoir, only type-N anhydrite is observed. In the deep reservoir, type-G anhydrite occurs in vertical veins whereas type-T and -N in lateral veins. Type-S anhydrite occurs in the heat-source Kakkonda Granite. The CL textures revealed that type-G anhydrite deposited earlier than type-T in the deep reservoir, implying that fracture system was changed from predominantly vertical to lateral.
Studies of fluid inclusions and δ34 S and δ18 O values of the samples indicate that type-N anhydrite deposited from diluted fluids derived from meteoric water, whereas type-G, -T and -S anhydrites deposited from magmatic brines derived from the Kakkonda Granite with the exception of some of type-G with recrystallization texture and no primary fluid inclusion, which deposited from fossil seawater preserved in the sedimentary rocks. Type-G, -T and -S anhydrites exhibit remarkably different chondrite-normalized REE patterns with a positive Eu anomaly, with a convex shape (peak at Sm or Eu) and with a negative Eu anomaly, respectively. The difference in the patterns might result from the different extent of hydrothermal alteration of the reservoir rocks and contribution of the magmatic fluids. 相似文献
Studies of fluid inclusions and δ
100.
The horizontal and vertical distributions of manganese in sea water, interstitial water and sediments in the Hiro Bay, Seto Inland Sea, Japan, have been investigated. The outflow from a pulp mill is the primary source of manganese in this bay. The industrial waste water contained 0.19 mg l–1 of manganese, mostly in a dissolved form. This manganese diffused out both horizontally and vertically into the surrounding sea water. The content of manganese in the liquid and solid phases in the sediments, however, are inverse with that in the sea water; namely the lowest concentration of manganese in the sediments was observed at the station near the outfall and manganese concentration increased with the distance from the outfall. 相似文献