Mineral grain availability and pupal-case building by lotic caddisflies: Effects on case architecture, stability and building expenses

The retreat-making larvae of many lotic caddisflies build entirely new pupal cases with fine gravel and sand that they collect in the neighbourhood of the building place to fix it with silk to cobbles in swift flow (where finer sediments are generally rare). Previous field observations on Hydropsyche siltalai pupal cases illustrate that natural local resource limitations of the preferred grain fraction (2.5–3.15 mm) produced chained effects across other grain fractions, as the alternative use of more grains in the 1.6–2 mm fraction (an unlimited resource) induced an increased use of more grains in the 0.315–0.5 mm fraction (another unlimited resource). To examine the implications of these observations for H. siltalai, we used (1) mesocosms to created minor deviations in the availability of the natural grain size composition of the building material of pupal cases at otherwise carefully replicated natural stream habitat conditions and (2) recently developed technologies to assess many case characteristics so far ignored in studies of caddisfly cases. When the preferred coarser grains (2.5–3.15 mm) were unavailable, more grains with intermediate size (1.25–2.0 mm) were used (and not other, still available coarse grains) and fewer larvae built cases in groups, thereby not only loosing the benefits (lower costs for grain transport and silk) but also avoiding potential disadvantages associated with grouped cases (more aggressive encounters with conspecifics for rare building material, less flow exposure and thus reduced water renewal in the pupal chamber). Unavailability of 2.5–3.15-mm and 0.315–0.5-mm grains caused a reduction of larvae building in groups, more use of grains with intermediate size, changes of several other grain characteristics (e.g. number, circularity) and considerable investment into silk to maintain the case resistance. Finally, grain availability deviating most from that observed in nature (no grains of 2.5–3.15 mm and 1.6–2.0 mm) caused dramatic responses, as mortality increased so that fewer pupal cases were built, using typically more coarse grains so that many cases had an elevated resistance against crushing forces; in addition, many males had a retarded development, whereas female development was unaffected. Thus, the response of H. siltalai to any of the three types of grain limitations differed, illustrating an immense diversity to respond to grain-size shortage.     

Volatile transport on inhomogeneous surfaces: I – Analytic expressions,with application to Pluto’s day

The two orders of magnitude drop between the measured atmospheric abundances of non-radiogenic argon, krypton and xenon in Earth versus Mars is striking. Here, in order to account for this difference, we explore the hypothesis that clathrate deposits incorporated into the current martian cryosphere have sequestered significant amounts of these noble gases assuming they were initially present in the paleoatmosphere in quantities similar to those measured on Earth (in mass of noble gas per unit mass of the planet). To do so, we use a statistical-thermodynamic model that predicts the clathrate composition formed from a carbon dioxide-dominated paleoatmosphere whose surface pressure ranges up to 3 bars. The influence of the presence of atmospheric sulfur dioxide on clathrate composition is investigated and we find that it does not alter the trapping efficiencies of other minor species. Assuming nominal structural parameters for the clathrate cages, we find that a carbon dioxide equivalent pressure of 0.03 and 0.9 bar is sufficient to trap masses of xenon and krypton, respectively, equivalent to those found on Earth in the clathrate deposits of the cryosphere. In this case, the amount of trapped argon is not sufficient to explain the measured Earth/Mars argon abundance ratio in the considered pressure range. In contrast, with a 2% contraction of the clathrate cages, masses of xenon, krypton and argon at least equivalent to those found on Earth can be incorporated into clathrates if one assumes the trapping of carbon dioxide at equivalent atmospheric pressures of ～2.3 bar. The proposed clathrate trapping mechanism could have then played an important role in the shaping of the current martian atmosphere.     

A three‐dimensional staggered finite element approach for random parametric modeling of thermo‐hygral coupled phenomena in porous media

The aim of this paper is to present a three‐dimensional (3D) finite element modeling of heat and mass transfer phenomena in partially saturated open porous media with random fields of material properties. Randomness leads to transfer processes within the porous medium that naturally need a full 3D modeling for any quantitative assessment of these processes. Nevertheless, the counterpart of 3D modeling is a significant increase in computations cost. Therefore, a staggered solution strategy is adopted which permits to solve the equations sequentially. This appropriate partitioning reduces the size of the discretized problem to be solved at each time step. It is based on a specific iterative algorithm to account for the interaction between all the transfer processes. Accordingly, a suitable linearization of mass convective boundary conditions, consistent with the staggered algorithm, is also derived. After some validation tests, the 3D numerical model is used for studying the drying process of a cementitious material with regard to its intrinsic permeability randomness. Copyright © 2011 John Wiley & Sons, Ltd.     

Large-Scale Mapping of Hard-Rock Aquifer Properties Applied to Burkina Faso

A country-scale (1:1,000,000) methodology has been developed for hydrogeologic mapping of hard-rock aquifers (granitic and metamorphic rocks) of the type that underlie a large part of the African continent. The method is based on quantifying the “useful thickness” and hydrodynamic properties of such aquifers and uses a recent conceptual model developed for this hydrogeologic context. This model links hydrodynamic parameters (transmissivity, storativity) to lithology and the geometry of the various layers constituting a weathering profile. The country-scale hydrogeological mapping was implemented in Burkina Faso, where a recent 1:1,000,000-scale digital geological map and a database of some 16,000 water wells were used to evaluate the methodology.     

Fate and tidal transport of butyltin and mercury compounds in the waters of the tropical Bach Dang Estuary (Haiphong, Vietnam)

In this work, two field campaigns were performed in July 2008 (wet season) and March 2009 (dry season) to produce original data on the concentration, partition and distribution of mercury and butyltin compounds along the tropical Bach Dang Estuary located in North Vietnam (Haiphong, Red River Delta). The results demonstrate that mercury and butyltin speciation in the surface waters of this type of tropical estuary is greatly affected by the drastic changes in the seasonal conditions. During high river discharge in the wet season, there was a large estuarine input of total Hg and tributyltin, while the longer residence time of the waters during the dry season promotes increasing MMHg formation and TBT degradation. Although most of the Hg and TBT is transported into the estuary from upstream sources, tidal cycle measurements demonstrate that this estuary is a significant source of TBT and MMHg during the wet (～3kgTBT/day) and dry (～3gMMHg/day) seasons.     

The geological evolution of Merapi volcano, Central Java, Indonesia

Merapi is an almost persistently active basalt to basaltic andesite volcanic complex in Central Java (Indonesia) and often referred to as the type volcano for small-volume pyroclastic flows generated by gravitational lava dome failures (Merapi-type nuées ardentes). Stratigraphic field data, published and new radiocarbon ages in conjunction with a new set of ⁴⁰K–⁴⁰Ar and ⁴⁰Ar–³⁹Ar ages, and whole-rock geochemical data allow a reassessment of the geological and geochemical evolution of the volcanic complex. An adapted version of the published geological map of Merapi [(Wirakusumah et al. 1989), Peta Geologi Gunungapi Merapi, Jawa Tengah (Geologic map of Merapi volcano, Central Java), 1:50,000] is presented, in which eight main volcano stratigraphic units are distinguished, linked to three main evolutionary stages of the volcanic complex—Proto-Merapi, Old Merapi and New Merapi. Construction of the Merapi volcanic complex began after 170?ka. The two earliest (Proto-Merapi) volcanic edifices, Gunung Bibi (109?±?60?ka), a small basaltic andesite volcanic structure on Merapi’s north-east flank, and Gunung Turgo and Gunung Plawangan (138?±?3?ka; 135?±?3?ka), two basaltic hills in the southern sector of the volcano, predate the Merapi cone sensu stricto. Old Merapi started to grow at ~30?ka, building a stratovolcano of basaltic andesite lavas and intercalated pyroclastic rocks. This older Merapi edifice was destroyed by one or, possibly, several flank failures, the latest of which occurred after 4.8?±?1.5?ka and marks the end of the Old Merapi stage. The construction of the recent Merapi cone (New Merapi) began afterwards. Mostly basaltic andesite pyroclastic and epiclastic deposits of both Old and New Merapi (<11,792?±?90 ¹⁴C years BP) cover the lower flanks of the edifice. A shift from medium-K to high-K character of the eruptive products occurred at ~1,900 ¹⁴C years BP, with all younger products having high-K affinity. The radiocarbon record points towards an almost continuous activity of Merapi since this time, with periods of high eruption frequency interrupted by shorter intervals of apparently lower eruption rates, which is reflected in the geochemical composition of the eruptive products. The Holocene stratigraphic record reveals that fountain collapse pyroclastic flows are a common phenomenon at Merapi. The distribution and run-out distances of these flows have frequently exceeded those of the classic Merapi-type nuées ardentes of the recent activity. Widespread pumiceous fallout deposits testify the occurrence of moderate to large (subplinian) eruptions (VEI 3–4) during the mid to late Holocene. VEI 4 eruptions, as identified in the stratigraphic record, are an order of magnitude larger than any recorded historical eruption of Merapi, except for the 1872?AD and, possibly, the October–November 2010 events. Both types of eruptive and volcanic phenomena require careful consideration in long-term hazard assessment at Merapi.     

Sampling strategies based on sets of behavioural parameters. Application to a simple pesticide fate model

Sampling strategies are necessary to minimise the cost of data acquisition. We consider the case when several samples must be analysed at the same time, knowing rainfall data, optionally discharge data. We assume also that a rainfall-runoff and pesticide transfer model is available. Three methods are presented based on behavioural sets calculated on prior events, which provide optimal sampling times with respect to different statistical criteria, for a fixed number of samples. A methodology to compare these strategies, adapted to a context of data scarcity is proposed for proper validation. We consider that the combination of a model and a strategy is efficient if it does better than a strategy without a model based on equal volumes. Even with a simple and relatively poor model, it can be concluded that the different strategies are efficient and show similar efficiency in spite of their different levels of conceptual and algorithmic complexity.