Trace metals in the Western Pacific: temporal and spatial variability in the concentrations of Cd, Cu, Mn and Ni

Profiles of total dissolvable Cd, Cu, Mn and Ni are reported for samples collected from the southwest Pacific in 1989, from the western equatorial Pacific along 155°E at 5°S, 0° and 5°N in 1990 and 1993, and along the equator from 143°E to 152°E and in the Bismarck Sea in 1997 and 2000. Profiles of Cd along 155°E in 1990 and along the equator were essentially the same but, in 1993, Cd values at 5°N were higher by a factor of about 1.5–2 than at 5°S over the depth range 500–1500 m. Similar, but less pronounced, differences were observed for PO₄ and Ni. Cd and Ni were both strongly correlated with PO₄, and an even stronger correlation was found between Ni and Cd. The concentration of Ni did not fall below ≈2 nmolkg⁻¹, even in the nitrate-depleted waters of the western equatorial Pacific, where primary production is strongly dependent on recycled nitrogen (mainly ammonia and urea). It is proposed that this residual Ni is not bioavailable and that Ni could be biolimiting, since the metabolism of urea requires the nickel-containing enzyme urease. The impact of the Sepik River on Cd, Cu and Ni concentrations was small but elevated concentrations of Mn were observed near the Sepik River and close to the coast suggesting that the rivers and sediments on the north coast of New Guinea are a significant local source of Mn to the Bismarck Sea. Simple mass balance calculations show that the elevated levels of Mn observed in the Equatorial Undercurrent cannot be due to input from the rivers of New Guinea and they were attributed to the trapping of particulate matter due to strong current shear. A strong hydrothermal source of Mn was observed in the central Bismarck Sea.     

Geochemical and hydrodynamic constraints on the distribution of trace metal concentrations in the lagoon of Nouméa, New Caledonia

Seawater samples were collected in the lagoon of Nouméa (southwest New Caledonia) along two transects from eutrophic coastal bays to the oligotrophic barrier reef. Land-based emissions to the lagoon were measured with dissolved and particulate concentrations of chromium (Cr) and nickel (Ni), used as tracers of both terrigenous and industrial (Ni ore treatment) activities, as well as dissolved and particulate concentrations of zinc (Zn), used as a tracer of urban effluents. The spatial variability of metal concentrations was related to geochemical and hydrodynamic conditions, i.e., respectively: (1) natural and anthropogenic emission sources, and chemical processes occurring in the water column; and (2) water residence times. The parameter used to describe the residence time of water masses was the local e-flushing time, i.e. the time required for a tracer mass contained within a given station to be reduced by a factor 1/e. High metal concentrations were found in coastal areas (up to 9000 ng dissolved Ni L⁻¹), and steeply decreased with distance from the coast (down to 101 ng dissolved Ni L⁻¹ near the barrier reef) to reach levels similar to those found in remote Pacific waters, suggesting a rapid renewal of waters close to the barrier. Distributions of metals in the lagoon are controlled upstream by land-based emission sources and later chemical processes. Then hydrodynamics constrain metal distributions, as shown by the observed relationship between local e-flushing times and the spatial variability of metal concentrations. In addition, a change in the direction of prevailing winds yielded a decrease of dissolved metal concentrations at the same site by a factor of 2.5 (Cr and Ni) and 2.9 (Zn). It is suggested that the residence time is a key parameter in the control of elemental concentrations in the lagoon waters, as much as land-based emission sources.     

The GeoForschungsZentrum Potsdam/Groupe de Recherche de Gèodésie Spatiale satellite-only and combined gravity field models: EIGEN-GL04S1 and EIGEN-GL04C

The recent improvements in the Gravity Recovery And Climate Experiment (GRACE) tracking data processing at GeoForschungsZentrum Potsdam (GFZ) and Groupe de Recherche de Géodésie Spatiale (GRGS) Toulouse, the availability of newer surface gravity data sets in the Arctic, Antarctica and North-America, and the availability of a new mean sea surface height model from altimetry processing at GFZ gave rise to the generation of two new global gravity field models. The first, EIGEN-GL04S1, a satellite-only model complete to degree and order 150 in terms of spherical harmonics, was derived by combination of the latest GFZ Potsdam GRACE-only (EIGEN-GRACE04S) and GRGS Toulouse GRACE/LAGEOS (EIGEN-GL04S) mean field solutions. The second, EIGEN-GL04S1 was combined with surface gravity data from altimetry over the oceans and gravimetry over the continents to derive a new high-resolution global gravity field model called EIGEN-GL04C. This model is complete to degree and order 360 and thus resolves geoid and gravity anomalies at half- wavelengths of 55 km at the equator. A degree-dependent combination method has been applied in order to preserve the high accuracy from the GRACE satellite data in the lower frequency band of the geopotential and to form a smooth transition to the high-frequency information coming from the surface data. Compared to pre-CHAMP global high-resolution models, the accuracy was improved at a spatial resolution of 200 km (half-wavelength) by one order of magnitude to 3 cm in terms of geoid heights. The accuracy of this model (i.e. the commission error) at its full spatial resolution is estimated to be 15 cm. The model shows a reduced artificial meridional striping and an increased correlation of EIGEN-GL04C-derived geostrophic meridional currents with World Ocean Atlas 2001 (WOA01) data. These improvements have led to select EIGEN-GL04C for JASON-1 satellite altimeter data reprocessing. Electronic Supplementary Material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Quality Assessment of Cartographic Generalisation

This paper proposes a methodology to assess the quality of cartographic generalisa‐tion, which consists of representing geographic space in a simplified way according to the scale and the objectives of the intended map. The automation of this process makes the derivation of data easier, but the quality of the results is often not evaluated. This paper proposes an assessment model based on: (1) characterisation of the data in their initial and final states at different levels of analysis; (2) a data quality assessment by comparison of the two characterisations; and (3) aggregation of the various assessment results to summarise data quality. The assessment algorithm has been implemented and the method has been tested to assess the generalisation of a small urban area. A visualisation tool for assessment of the results has been developed to validate the generalisation evaluation. The results of the research are presented and discussed at the end of the paper.     

A methodology for regionalizing 3‐D effective porosity at watershed scale in crystalline aquifers

An innovative approach for regionalizing the 3‐D effective porosity field is presented and applied to two large, overexploited, and deeply weathered crystalline aquifers located in southern India. The method derives from earlier work on regionalizing a 2‐D effective porosity field in that part of an aquifer where the water table fluctuates, which is now extended over the entire aquifer using a 3‐D approach. A method based on geological and geophysical surveys has also been developed for mapping the weathering profile layers (saprolite and fractured layers). The method for regionalizing 3‐D effective porosity combines water table fluctuation and groundwater budget techniques at various cell sizes with the use of satellite‐based data (for groundwater abstraction), the structure of the weathering profile, and geostatistical techniques. The approach is presented in detail for the Kudaliar watershed (983 km²) and tested on the 730 km² Anantapur watershed. At watershed scale, the effective porosity of the aquifer ranges from 0.5% to 2% in Kudaliar and between 0.3% and 1% in Anantapur, which agrees with earlier works. Results show that (a) depending on the geology and on the structure of the weathering profile, the vertical distribution of effective porosity can be very different and that the fractured layers in crystalline aquifers are not necessarily characterized by a rapid decrease in effective porosity and (b) that the lateral variations in effective porosity can be larger than the vertical ones. These variations suggest that within a same weathering profile, the density of open fractures and/or degree of weathering in the fractured zone may significantly vary from a place to another. The proposed method provides information on the spatial distribution of effective porosity that is of prime interest in terms of flux and contaminant transport in crystalline aquifers. Implications for mapping groundwater storage and scarcity are also discussed, which should help in improving groundwater resource management strategies.     

An original semi‐discrete approach to assess gas conductivity of concrete structures

For civil engineering structures with a tightness role, structural permeability is a key issue. In this context, this paper presents a new proposition of a numerical modelling of leakage rate through a cracked concrete structure undergoing mode I cracking. The mechanical state of the material, considered in the framework of continuum mechanics based on finite element modelling, is described by means of the stress‐based nonlocal damage model which takes into account the stress state and provides realistic local mechanical fields. A semi‐discrete method based on the strong discontinuity approach to estimate crack opening is then considered in the post‐treatment phase. Using a Poiseuille's like relation, the coupling between the mechanical state of the material and its dry gas conductivity is performed. For validation purposes, an original experimental campaign is conducted on a dry concrete disc loaded in a splitting setup. During the loading, gas conductivity and digital image correlation analysis are performed. The comparison with the 3D experimental mechanical global response highlights the performance of the mechanical model. The comparison between crack openings measured by digital image correlation and estimated by the strong discontinuity method shows a good agreement. Finally, the results of the semi‐discrete approach coupled with the gas conductivity compared with experimental data show a good estimation of the structural conductivity. Consequently, if the mechanical problem is well modelled at the global scale, then the proposed approach provides good estimation of gas conductivity. Copyright © 2016 John Wiley & Sons, Ltd.     

Were merely storm-landslides driven by the 2015-2016 Niño in the Mendoza River valley?

Since Holocene time, above-mean precipitations recorded during the El Niño warm ENSO phase have been linked to the occurrence of severe debris flows in the arid Central Andes. The 2015–2016 El Niño, for its unusual strength, began driving huge and dangerous landslides in the Central Andes (32°) in the recent South Hemisphere summer. The resulting damages negatively impacted the regional economy. Despite this, causes of these dangerous events were ambiguously reported. For this reason, a multidisciplinary study was carried out in the Mendoza River valley. Firstly, a geomorphological analysis of affected basins was conducted, estimating morphometric parameters of recorded events such as velocity, stream flow, and volume. Atmospheric conditions during such events were analyzed, considering precipitations, snow cover, temperature range, and the elevation of the zero isotherm. Based on our findings, the role of El Niño on the slope instability in the Central Andes is more complex in the climate change scenario. Even though some events were effectively triggered by intense summer rainstorm following expectations, the most dangerous events were caused by the progressive uplifting of the zero isotherm in smaller basins where headwaters are occupied by debris rock glaciers. Our research findings give light to the dynamic coupled system ENSO–climate change–landslides (ECCL) at least in this particular case study of the Mendoza River valley. Landslide activity in this Andean region is driven by wetter conditions linked to the ENSO warm phase, but also to progressive warming since the twentieth century in the region. This fact emphasizes the future impact of the natural hazards on Andean mountain communities.     

Effects of local accelerations and baroclinity on the mean structure of the atmospheric boundary layer over the sea

Substitution of the geostrophic wind by the actual upper wind in the equations of motion for the boundary layer implies less sensitivity of the mean wind to inertial effects. This is confirmed by observations, although the problem of computing time or spatial derivatives from scattered data reduces the accuracy and the clarity of the results. It is found that acceleration (deceleration) increases (decreases) the cross-isobar angle whereas the geostrophic drag coefficient is a minimum (maximum) for crosswind acceleration (deceleration). On the other hand, cold air advection increases the cross-isobar angle whereas the geostrophic drag coefficient is a maximum when the thermal wind is parallel to the surface wind. The universal functions A _m and B _m based on vertically averaged winds are also rather insensitive to inertial influences.     

Shallow seismicity at Montagne Pelée volcano,Martinique, Lesser Antilles

Continuous seismic monitoring at Martinique since the 1902 eruption of the Montagne Pelée volcano did not detect local earthquakes for the first 70 years. For the only eruption which occurred in this time span in 1929 the seismograph was 20 km away and of a standard type, not particularly suited for the detection of small-scale local seismicity. Improvement of the monitoring array over the last 15 years with the installation of sensors on the volcano itself allowed the detection of signals of local origin which were interpreted as being due to surface sources, such as rockfalls and landslides. Since December 1985 seismic sources in the volcano itself, i.e. small earthquakes at shallow depth, were identified and located with the aid of a temporary upgrading of the array close to these weak sources. Such an onset of local seismicity could not have been detected with previous seismic equipment; such episodes of seismicity in the volcano might have occurred in the past, apparently quiescent history of the volcano as the reinterpretation of seismograms of some events in 1976 would indicate, without evolving to more important volcanic phenomena. For seismographs on volcanoes the constant upgrading of observation capabilities is certainly perferred to a strict continuity of standard observations.