球粒状和棒状纳米赤铁矿光电化学特性研究

本文以乙二醇为诱导剂通过电化学沉积法成功合成了球粒状及棒状纳米赤铁矿。X射线衍射光谱(XRD)和Raman光谱结果表明,球粒状赤铁矿粒径20±5 nm;棒状赤铁矿截面直径约20 nm,长90±10 nm;二者物相皆为单一均匀的赤铁矿。紫外-可见吸收光谱显示两种赤铁矿在300~550 nm范围内均有较好吸收,Tauc方程计算球粒状和棒状赤铁矿禁带宽度分别为2.00 e V和1.99 e V。Mott-Schottky拟合结果表明1 M KOH溶液体系中,棒状赤铁矿载流子浓度为1.95×1021cm-3,高于球粒状赤铁矿(3.16×1020cm-3)。进一步的光电化学实验表明:0.6 V(vs.Ag/Ag Cl)电势下棒状赤铁矿光照下电流密度较暗电流提升550%,球粒状赤铁矿电流密度提升77%。研究证实,赤铁矿形貌对其半导体特性及光电化学特性有影响,且棒状赤铁矿电极表现出更好的可见光响应特性,具有更佳的光电催化潜力。     

东天山二叠纪镁铁-超镁铁质成矿岩体造岩矿物特征及其成因意义

东天山造山带与镁铁-超镁铁质岩体有关的铜镍硫化物矿床数量多,分布集中,是我国重要的铜镍成矿带之一。成矿岩体多以小岩体群形式产出,由西向东分布有白鑫滩、黄山和图拉尔根3个岩体群,大型矿床主要赋存在黄山岩体群内。本文对3个岩体群内成矿岩体的主要造岩矿物进行了系统的对比研究。成矿岩体的主要造岩矿物为贵橄榄石、古铜辉石、单斜辉石、斜长石和角闪石以及少量的铬尖晶石和金云母。橄榄石Al温度计计算结果表明,黄山岩体群内成矿岩体的母岩浆结晶温度介于1 143~1 257℃之间,略低于白鑫滩和图拉尔根岩体群(1 283~1 301℃)。单斜辉石压力计算表明成矿岩体的结晶压力相似,介于0.31~0.33 GPa之间。成矿岩体中均富含含水矿物,且单斜辉石结晶早于斜长石,指示成矿岩体的原始岩浆形成于富水环境。成矿岩体的单斜辉石具有较高的Al/Ti值,铬尖晶石和橄榄石具有与岛弧火山岩相似的矿物学特征,结合区域构造演化,认为东天山镁铁-超镁铁质成矿岩体的原始岩浆是被消减板片交代过的地幔部分熔融的产物。矿物学特征对比显示了黄山岩体群内成矿岩体更富斜方辉石和中性斜长石,且具有较低的铬尖晶石Cr~#值和橄榄石Ca含量。结合前人研究成果和相关地球化学数据,认为相对高的混染程度导致了黄山岩体群的母岩浆富SiO_2和Al_2O_3,同时降低了岩浆的结晶温度。     

Deformation of the Shirenshan Block in the North Qinling

<正>Objective The Qinling orogenic belt is a typical complex continental orogenic belt which has experienced multiperiod tectonic evolution and where some important tectonic belts formed.The Luoluan fault is one of the most important belts,which is the boundary fault of the North China Plate and the Qinling orogenic belt.The Shirenshan block is located in the north section between Luanchuan and Fangcheng of the Luoluan fault.The north part is     

Petrogenesis of the Early Cretaceous Laojunshan monzogranite at the southern margin of the North China Craton: Constrains on the transition of the tectonic regime

<正>1 Introduction Voluminous Mesozoic magmatic rocks containing abundant Au-Mo polymetallic mineralization resources are developed in the Xiaoqinling-Xiong’ershan district of the southern margin of the North China Craton(NCC).     

Tectonic-Thermal Evolution History and Its Controls on Petroleum Geology of Weibei Uplift

<正>1 Introduction The Weibei Uplift is located in the southwest of the North China Plate,where is the stable block(the Ordos Block)in the north and the active belt(the QinlingOrogenic Belt)in the south(Ren et al,2014,2015).And the belt is separated from the Weihe basin.The Weibei uplift has a uniform crystalline basement with the North     

黑龙江省张广才岭南部早侏罗世花岗岩暗色微粒包体成因研究

黑龙江省张广才岭南部早侏罗世花岗岩具有明显的岩浆混合特征。岩体中暗色微粒包体发育,主要为细粒闪长质岩浆包体,包体形态多样,与寄主岩呈截然、过渡关系。包体的矿物组合明显不平衡,如矿物具有定向排列的特点,斜长石发育自形环带并存在新、老两个世代,发育针状磷灰石。由电子探针对斜长石、角闪石和黑云母等矿物分析结果可知,寄主花岗岩和包体中各主要矿物含量基本一致。岩石地球化学特征研究显示,包体与寄主花岗岩关系密切,两者在稀土元素和微量元素方面也表现为明显的地球化学亲缘关系。这表明张广才岭南部早侏罗世花岗质岩石具有壳幔混合成因特征,暗色微粒包体是由较基性的地幔岩浆进入寄主岩浆中淬火结晶而成,花岗质岩浆的源区主要为新生的地壳物质。     

Carboniferous–Permian Stratigraphy and Sedimentary Environment of Southeastern Inner Mongolia, China: Constraints on Final Closure of the Paleo-Asian Ocean

In this paper we discuss the timing of final closure of the Paleo-Asian Ocean based on the field investigations of the Carboniferous–Permian stratigraphic sequences and sedimentary environments in southeastern Inner Mongolia combined with the geology of its neighboring areas. Studies show that during the Carboniferous–Permian in the eastern segment of the Tianshan-Hinggan Orogenic System, there was a giant ENE–NE-trending littoral-neritic to continental sedimentary basin, starting in the west from Ejinqi eastwards through southeastern Inner Mongolia into Jilin and Heilongjiang. The distribution of the Lower Carboniferous in the vast area is sparse. The Late Carboniferous or Permian volcanic-sedimentary rocks always unconformably overlie the Devonian or older units. The Upper Carboniferous–Middle Permian is dominated by littoral-neritic deposits and the Upper Permian, by continental deposits. The Late Carboniferous–Permian has no trace of subduction-collision orogeny, implying the basin gradually disappeared by shrinking and shallowing. In addition, it is of interest to note that the Ondor Sum and Hegenshan ophiolitic mélanges were formed in the pre-Late Silurian and pre-Late Devonian respectively, and the Solonker ophiolitic mélange formed in the pre-Late Carboniferous. All the evidence indicates that the eastern segment of the Paleo-Asian Ocean had closed before the Late Carboniferous, and most likely before the latest Devonian (Famennian).     

西藏多龙矿集区地堡那木岗铜(金)矿床流体包裹体特征及矿床成因

地堡那木岗铜(金)矿床位于西藏多龙矿集区,探明储量达大型规模;矿床的成矿过程分为岩浆作用阶段、钾长石-硫化物阶段、石英-多金属硫化物阶段、碳酸盐-黄铁矿阶段和氧化作用阶段,其中石英-多金属硫化物阶段和碳酸盐-黄铁矿阶段为主要成矿阶段;为查明成矿流体特征,确定矿床成因类型,对取自深部矿石中的碳酸盐脉(均为碳酸盐-黄铁矿成矿阶段含黄铁矿黄铜矿石英脉)开展流体包裹体的岩相学观察和显微测温分析。分析结果表明,上述矿物中主要发育富液相、富气相和含子矿物三相包裹体。其中,富液相包裹体的均一温度与盐度分别为:t=80~600℃、w(NaCl,eq)=4.48%~18.79%;富气相包裹体的均一温度和盐度分别为:t=240~560℃、w(NaCl,eq)=5.09%~9.73%;含子矿物三相包裹体的均一温度与盐度分别为:t=240~560℃、w(NaCl,eq)=36%~72%。综合分析认为,地堡那木岗铜(金)矿床成矿流体发生了强烈的沸腾作用,流体沸腾作用是该矿床的重要成矿机制。通过与国内外典型斑岩型矿床与高硫化型浅成低温热液矿床的流体包裹体特征进行对比,其与斑岩型矿床的中高温、高盐度流体特征相似。因此,推测地堡那木岗矿床的成因类型为斑岩型铜(金)矿床。     

黑龙江三道湾子金矿床火山岩-次火山岩年代学、地球化学和地质意义

三道湾子金矿床位于小兴安岭北麓,是典型的以碲金化合物为主的矿床,为了限定其成矿时代和厘定其成矿地质背景,笔者对同成矿地质体火山岩和成矿期后的玄武粗安玢岩的单颗粒锆石U-Pb年龄和元素地球化学进行测定,获得同成矿地质体粗面英安斑岩及玄武粗安玢岩的~(206)Pb/~(238)U年龄加权平均值分别为(124.2±0.9)Ma(MSWD=0.5,n=18)和(118.9±2.3)Ma(MSWD=0.5,n=6);赋矿围岩为玄武粗安岩与同成矿地质体粗面英安斑岩,Si O2含量为52.75%~62.30%,K_2O和Na_2O含量分别为2.02%~2.85%和3.96%~4.24%。里特曼指数(δ)在0.85~3.67之间,属于钙碱性到高钾钙碱性岩系特征;成矿期后脉岩玄武粗安玢岩,SiO_2含量为51.53%~52.32%,K_2O含量为2.30%~2.36%,Na_2O含量为3.78%~4.14%,里特曼指数(δ)在4.05~4.86之间;微量和稀土元素均显示富集大离子亲石元素(Cs、K、Rb、Ba、LREE等),相对亏损高场强元素(Nb、Ta、Zr、Hf等)和HREE,特别是强烈亏损Th、U和Nb、Ta的特征,与岛弧钙碱性玄武岩相似。研究揭示了该矿床形成于早白垩世(124~119 Ma)或晚中生代造山后伸展构造环境,成矿热动源可能是交代大洋性质的岩石圈地幔。     

云南先峰中新世木乃伊化木化石α-纤维素的提取

本文对云南先锋中新世木乃伊化木化石进行α-纤维素实验提取,以验证化石纤维素的可得性。实验利用有机溶剂分离、碱液分离、无机酸分离等方法分别对研究区5件木乃伊化化石样品进行处理,并采用红外光谱检测方法与现代木材α-纤维素和国际标准α-纤维素进行对比试验。实验结果显示,3种提取方法均可以从化石木材中提取出α-纤维素,但过程特征各有不同。其中,有机溶剂分离实验过程耗时最长,碱液分离方法样品损失最大。相比之下,无机酸分离方法对于木乃伊化木化石α-纤维素提取的效率最高。