南海神狐海域沉积物自生黄铁矿和石膏S同位素特征及对甲烷渗漏强度的示踪

The northern slope of the South China Sea is a gas-hydrate-bearing region related to a high deposition rate of organic-rich sediments co-occurring with intense methanogenesis in subseafloor environments.Anaerobic oxidation of methane(AOM) coupled with bacterial sulfate reduction results in the precipitation of solid phase minerals in seepage sediment,including pyrite and gypsum.Abundant aggregates of pyrites and gypsums are observed between the depth of 667 and 850 cm below the seafloor(cmbsf) in the entire core sediment of HS328 from the northern South China Sea.Most pyrites are tubes consisting of framboidal cores and outer crusts.Gypsum aggregates occur as rosettes and spheroids consisting of plates.Some of them grow over pyrite,indicating that gypsum precipitation postdates pyrite formation.The sulfur isotopic values(δ~(34) S) of pyrite vary greatly(from –46.6‰ to –12.3‰ V-CDT) and increase with depth.Thus,the pyrite in the shallow sediments resulted from organoclastic sulfate reduction(OSR) and is influenced by AOM with depth.The relative high abundance and δ~(34) S values of pyrite in sediments at depths from 580 to 810 cmbsf indicate that this interval is the location of a paleo-sulfate methane transition zone(SMTZ).The sulfur isotopic composition of gypsum(from–25‰ to –20.7‰) is much lower than that of the seawater sulfate,indicating the existence of a 34 S-depletion source of sulfur species that most likely are products of the oxidation of pyrites formed in OSR.Pyrite oxidation is controlled by ambient electron acceptors such as MnO_2,iron(Ⅲ) and oxygen driven by the SMTZ location shift to great depths.The δ~(34) S values of gypsum at greater depth are lower than those of the associated pyrite,revealing downward diffusion of 34 S-depleted sulfate from the mixture of oxidation of pyrite derived by OSR and the seawater sulfate.These sulfates also lead to an increase of calcium ions from the dissolution of calcium carbonate mineral,which will be favor to the formation of gypsum.Overall,the mineralogy and sulfur isotopic composition of the pyrite and gypsum suggest variable redox conditions caused by reduced seepage intensities,and the pyrite and gypsum can be a recorder of the intensity evolution of methane seepage.     

拟穴青蟹(Scylla paramamosain)六个地理群体肌肉氨基酸和脂肪酸的比较分析

本文对广西钦州(Gq)、福建霞浦(Fx)、浙江温州(Zw)、浙江三门(Zs)、浙江宁海(Zn)、浙江慈溪(Zc)等6个野生群体拟穴青蟹(Scylla paramamosain)肌肉进行了氨基酸及脂肪酸分析。共测定出19种游离氨基酸和26种脂肪酸。氨基酸含量在80.94—191.39mg/g之间, Gq为最高;总脂肪酸含量在7.97—11.38mg/g之间,Zn为最高。主要氨基酸为甘氨酸和精氨酸;主要脂肪酸为C20:5n3(EPA),占总脂肪酸含量的平均值为(22.47±5.84)%。各群体风味氨基酸和多不饱和脂肪酸含量丰富,占总氨基酸比例(TDAA/TFAA)和总脂肪酸比例(PUFA/TFA)分别为(53.62±5.43)%和(59.27±5.29)%。Zs群体的必需氨基酸含量及C22:6n3(DHA)均为最高。主成分分析结果表明:各群体的氨基酸与脂肪酸组成与含量相似性与地理距离分布具有一定的相关性,特别是Gq群体,在氨基酸与脂肪酸的分类中与其他群体区分比较明显。各群体风味氨基酸和多不饱和脂肪酸的聚类分析结果均表明:Zw、Zc与Gq群体较为接近,具有较强的甜味; Fx、Zn与Zs群体较为接近,具有较强的香味及不饱和脂肪酸营养价值。     

Study of the flood control scheduling scheme for the Three Gorges Reservoir in a catastrophic flood

The Three Gorges Project is the world's largest water conservancy project. According to the design standards for the 1,000‐year flood, flood diversion areas in the Jingjiang reach of the Yangtze River must be utilized to ensure the safety of the Jingjiang area and the city of Wuhan. However, once these areas are used, the economic and life loss in these areas may be very great. Therefore, it is vital to reduce this loss by developing a scheme that reduces the use of the flood diversion areas through flood regulation by the Three Gorges Reservoir (TGR), under the premise of ensuring the safety of the Three Gorges Dam. For a 1,000‐year flood on the basis of a highly destructive flood in 1954, this paper evaluates scheduling schemes in which flood diversion areas are or are not used. The schemes are simulated based on 2.5‐m resolution reservoir topography and an optimized model of dynamic capacity flood regulation. The simulation results show the following. (a) In accord with the normal flood‐control regulation discharge, the maximum water level above the dam should be not more than 175 m, which ensures the safety of the dam and reservoir area. However, it is necessary to utilize the flood diversion areas within the Jingjiang area, and flood discharge can reach 2.81 billion m³. (b) In the case of relying on the TGR to impound floodwaters independently rather than using the flood diversion areas, the maximum water level above the dam reaches 177.35 m, which is less than the flood check level of 180.4 m to ensure the safety of the Three Gorges Dam. The average increase of the TGR water level in the Chongqing area is not more than 0.11 m, which indicates no significant effect on the upstream reservoir area. Comparing the various scheduling schemes, when the flood diversion areas are not used, it is believed that the TGR can execute safe flood control for a 1,000‐year flood, thereby greatly reducing flood damage.     

东海蛾螺属二新记录种(腹足纲,蛾螺科)

在整理近年来东海采集的蛾螺科Buccinidae标本时,鉴定出属于蛾螺属Buccinum Linnaeus,1758的两个中国新记录种:(1)白肋蛾螺Buccinum leucostoma Lischke,1872,采自于东海300—400m深的泥沙质海底;(2)古式蛾螺Buccinum koshikinum Okutani,1988采自于东海400m深的泥沙质海底。文中分别对这两个新记录种的形态特征、生活习性等进行了描述,并与相似种进行了分类学讨论。此外,文中还列出了中国海已报道的其他蛾螺属种类。     

海水中铯-137的γ能谱测量不确定度评估

为科学评价测量结果的可靠性，对海水中137Cs γ能谱分析方法的不确定度进行了评估。根据《化学分析中不确定度的评估指南》，分析不确定度的来源并逐一对各不确定度分量进行了量化，最终计算了合成相对标准不确定度。结果表明，影响海水中137Cs γ能谱测量不确定度的因素分别为样品源137Cs峰区计数、标准源活度、取样体积、化学回收率、本底137Cs峰区计数及标准源137Cs峰区计数，其中样品源137Cs峰区计数的不确定度贡献最为突出。对于137Cs活度浓度为1.28 mBq/L的海水样品，其合成相对标准不确定度为9.78%。     

Predicting quantiles of water quality from catchment characteristics

Water quality is often highly variable both in space and time, which poses challenges for modelling the more extreme concentrations. This study developed an alternative approach to predicting water quality quantiles at individual locations. We focused on river water quality data that were collected over 25 years, at 102 catchments across the State of Victoria, Australia. We analysed and modelled spatial patterns of the 10th, 25th, 50th, 75th and 90th percentiles of the concentrations of sediments, nutrients and salt, with six common constituents: total suspended solids (TSS), total phosphorus (TP), filterable reactive phosphorus (FRP), total Kjeldahl nitrogen (TKN), nitrate-nitrite (NO_x), and electrical conductivity (EC). To predict the spatial variation of each quantile for each constituent, we developed statistical regression models and exhaustively searched through 50 catchment characteristics to identify the best set of predictors for that quantile. The models predict the spatial variation in individual quantiles of TSS, TKN and EC well (66%–96% spatial variation explained), while those for TP, FRP and NO_x have lower performance (37%–73% spatial variation explained). The most common factors that influence the spatial variations of the different constituents and quantiles are: annual temperature, percentage of cropping land area in catchment and channel slope. The statistical models developed can be used to predict how low- and high-concentration quantiles change with landscape characteristics, and thus provide a useful tool for catchment managers to inform planning and policy making with changing climate and land use conditions.     

沉积物中硬质粘土层的研究进展

大量的钻孔资料表明,平原地区及其海域沉积物中普遍有硬质粘土层的存在。硬质粘土层在工程地质、地理学研究等方面具有重要的价值,它不仅是高层建筑的持力层,而且是研究全球环境变化事件、古气候演变的良好载体。该文阐述了硬质粘土层的一般特征、成因以及在粒度、地球化学元素、年代学、沉积环境等方面的研究进展,并展望了硬质粘土层在年代、物质来源和沉积环境等方面的研究方向,认为黄河三角洲硬质粘土层研究较少,需要开展大范围的、系统深入的、多学科的宏观和微观综合分析,挖掘硬质粘土层蕴含的古环境意义和应用价值。     

Dynamic modelling of retrogressive landslides with emphasis on the role of clay sensitivity

This paper presents a detailed numerical study of the retrogressive failure of landslides in sensitive clays. The dynamic modelling of the landslides is carried out using a novel continuum approach, the particle finite element method, complemented with an elastoviscoplastic constitutive model. The multiwedge failure mode in the collapse is captured successfully, and the multiple retrogressive failures that have been widely observed in landslides in sensitive clays are reproduced with the failure mechanism, the kinematics, and the deposition being discussed in detail. Special attention has been paid to the role of the clay sensitivity on each retrogressive failure as well as on the final retrogression distance and the final run‐out distance via parametric studies. Moreover, the effects of the viscosity of sensitive clays on the failure are also investigated for different clay sensitivities.     

基于UDF的水平轴潮流能水轮机被动旋转水动力性能研究

针对水平轴潮流能水轮机被动旋转问题,基于Fluent 17.0,运用UDF(User Defined Function)控制滑移网格对网格进行动态调整,仿真研究水轮机在不同安放角下被动旋转的水动力特性。通过仿真分析,结果表明:潮流能水轮机随着叶片安放角度的增加,尖速比、输出功率、捕能系数都是先增大后减小,叶片安放角为6°时,叶轮前后速度差最大,对潮流能利用充分,且各项性能均达到最佳;通过分析叶片受力,叶尖叶素在安放角为2°时阻力最大,3°时升力最大,升阻比在6°时最大,此时叶尖叶素升阻比C_L/C_D=6.27、攻角α=3.06°。由仿真结果可知水平轴潮流能叶轮的自启动过程由5个阶段组成,即加速度增大的加速运动段—加速度减小的加速运动段—加速度反向增大的减速运动段—加速度反向减小的减速运动段—稳定运行段,这对潮流能水轮机的设计具有重要的指导意义。     

基于灯光数据的京津冀城市多标度异速分析

城镇体系的时空演化是一个复杂的动力学过程,具有无尺度性,其特征可以采用异速标度指数定量描述。论文以京津冀为例,基于1992—2013年夜间灯光数据的校正结果,提取城镇夜间灯光信息,采用多标度异速分析方法,分析京津冀城镇体系的相对发展特征及其空间分异格局。研究发现：①京津冀大城市的增长空间局限日益显著。虽然大城市如京津唐的绝对发展水平高,但接近环境承载量的极限,22 a间增长快速的是大城市交接地带的小城市(如三河、迁安、廊坊等)。②相对增长速度快的城市从东北到西南呈现带状分布——政府选择发展的“雄安新区”就在这个轴带上。由此可以得出两个结论：其一,京津冀城市演化的趋势相对均衡化,空间结构异质性逐步减弱,整个城镇体系的发展趋于相对平衡状态;其二,大、小城市“两极”贯通或许是增强城镇体系功能的有效途径。京津冀的空间格局优化不能仅仅考虑主要的、规模大的中心城市,而应该基于等级结构协调整个城镇网络体系。