The geochemistry of sediments is primarily controlled by their provenances, and different tectonic settings have distinctive provenance characteristics and sedimentary processes. So, it is possible to discriminate provenances, depositional environments and tectonic settings in the development of a sedimentary basin with the geochemistry of the clastic rocks. The analytical results of the present paper demonstrate that sediments in the Songliao prototype basin are enriched in silica (SiO2=66.48-80.51 %), and their ΣREE are 30-130 dmes of that of chondrite with remarkable Eu anomalies. In discriminating diagrams of Eu/Eu vs eeeeeREE and (La/Yb)N vs ΣREE, most samples locate above the line Eu/ Eu=l, on the right of the line Eu/Eu/ΣREE=1 and under the line La/Yb)N/eeeeeREE=1/8, which indicates that the depositional environment of sediments in the basin was oxidizing. In addition, variations of MgO, TiO2, A12O3, FeO+Fe2O3, Na2O and CaO vs SiO2 reflect a tendency of increasing mineral maturity of sediments 相似文献
The Baishan Mo–Re deposit is located in the eastern section of the eastern Tianshan orogenic belt, NW China. The deposit has a grade of 0.06% Mo and a high content of rhenium of 1.4 g/t. Rhenium and osmium isotopes in sulfide minerals from the Baishan deposit are used to determine the age of mineralization. Rhenium concentrations in molybdenite samples are between 74 and 250 g/g. Analysis of eight molybdenite samples yields an isochron age of 224.8±4.5 Ma (2). Pyrite samples have rhenium and osmium concentrations varying in the range 33.4–330.6 ng/g and 0.08–0.81 ng/g, respectively. Isotope data on seven pyrite samples yield an isochron age of 225±12 Ma (2) on the 187Re/188Os versus 187Os/188Os plot and an age of 233±14 Ma (2) on the 187Os versus 187Re correlation diagram. The ages of molybdenite and pyrite are consistent within the analytical errors. Combined with field observations, the data indicate that Mo–Re mineralization in the Baishan deposit is produced by a magmatic-hydrothermal event in an intracontinental extensional setting after late Paleozoic orogeny. The initial 187Os/188Os ratio of pyrite is 0.3±0.07. The 34S values of molybdenite vary from +0.5 to +3.6. Both data indicate that mineralization is derived mainly from a mantle source.Editorial handling: J. Richards 相似文献
Dinoflagellate Alexandrium catenella is a cosmopolitan bloom-forming species with complex life cycle, the formation and germination of resting cysts are critical for its bloom dynamics. In the coastal waters of Qinhuangdao, A. catenella has been identified as the major causative agent for paralytic shellfish poisoning, but there is little knowledge concerning its resting cysts in this region. In this study, three surveys were carried out along the coast of Qinhuangdao from 2020 to 2021 to map the distribution of A. catenella resting cysts, using a quantitative PCR (qPCR) assay specific for A. catenella. The resting cysts were detected in surface sediments during all the three surveys, and their distribution patterns were similar. High abundance of resting cysts (maximum 1 300 cysts/g sediment (wet weight)) were found in a region (119.62°E–119.99°E, 39.67°N–39.98°N) northeast to the coastal waters of Qinhuangdao, where surface sediments were mainly composed of clay and silt (percentage above 50%). Prior to the formation of the A. catenella bloom in March 2021, the abundance of A. catenella vegetative cells in seawater had extremely significant positive correlation with the abundance of resting cysts in surface sediments, reflecting the important role of resting cysts in the initiation of A. catenella blooms. As far as we know, this is the first report on the distribution of A. catenella cysts along the coast of Qinhuangdao. The results will offer a sound basis for the future monitoring and mitigation of toxic A. catenella blooms and paralytic shellfish poisoning events in this region.
The Xiaotian–Mozitan Shear Zone(XMSZ) is the boundary of the Dabie High-grade Metamorphic Complex(DHMC) and the North Huaiyang Tectonic Belt. It was deformed in ductile conditions with a top-to-NW/WNW movement.Geothermometers applied to mineral parageneses in mylonites of the shear zone give a temperature range of 623–691°C for the predeformation and 515–568°C for the syndeformation, respectively, which indicates a retrograde process of evolution.A few groups of zircon U-Pb ages were obtained from undeformed granitic veins and different types of deformed rocks in the zone. Zircons from the felsic ultramylonites are all magmatic, producing a weighted mean 206 Pb/238 U age of 754 ± 8.1 Ma, which indicates the time of magmatic activities caused by rifting in the Neoproterozoic. Zircons from the granitic veins, cutting into the mylonites, are also of magmatic origin, producing a weighted mean 206 Pb/238 U age of 130 ± 2.5 Ma,which represents the time of regional magmatic activity in the Cretaceous. Zircons from the mylonitic gneisses are of anatectic-metamorphic origins and are characterized by a core-mantle interior texture, which yielded several populations of ages including the Neoproterozoic ages with a weighted mean 206 Pb/238 U age of 762 ± 18 Ma, similar to that of the felsic ultramylonites and the Early Cretaceous ages with a weighted mean 206 Pb/238 U age of 143 ± 1.8 Ma, indicating the anatectic metamorphism in the Dabie Orogenic Belt(DOB). Based on integrated analysis of the structure, thermal conditions of ductile deformation and the contact relations of the dated rocks, the activation time of the Xiaotian–Mozitan Shear Zone is constrained between ~143 Ma and 130 Ma, during which the DOB was undergoing a transition in tectonic regime from compression to extension. Therefore, the deformation and evolution of this shear zone plays an instrumental role in fully understanding this process. This research also inclines us to the interpretation of it as an extensional detachment, with regard to the tectonic properties of the shear zone. It may also be part of a continental scale extension in the background of the North China Block's cratonic destruction, dominated by the subduction and roll-back of the Paleo-Pacific plate, but more detailed work is needed in order to unravel its complicated development. 相似文献
Mafic dike–granite associations are common in extensional tectonic settings and important and pivotal in reconstructing crust–mantle geodynamic processes. We report results of zircon U–Pb and hornblende 40Ar-39Ar ages and major-element and trace-element data for mafic dike–granite association from the northern West Junggar, in order to constrain their ages, petrogenesis, and geodynamic process. The mafic dike–granite association was emplaced in the early Devonian. The Xiemisitai monzogranites have high SiO2 contents and low MgO, Cr, and Ni concentrations, suggesting that they were mainly derived from crustal sources and were probably generated by partial melt of the juvenile mid-lower crust. The mafic dikes have low Mg# and Cr and Ni abundances, suggesting that they have experienced significant fractional crystallization. The Xiemisitai mafic dikes contain hornblende and biotite and display negative Nb–Ta–Ti anomalies, enrichment of LREEs and LILEs, and depletion of HREEs and HFSEs, consistent with an origin from a lithospheric mantle metasomatized by subducted slab-derived fluids. In addition, the Xiemisitai mafic dikes are plotted within melting trends with little to no garnet (Cpx: Grt = 6:1) in their source. The La/Yb versus Tb/Yb plot also indicates the presence of less than 1% residual garnet in the source region for the Xiemisitai mafic dikes. Therefore, it can be inferred that the Xiemisitai mafic dikes were generated at a correspondingly shallow depth, mostly within the spinel stability field. The Xiemisitai mafic dikes were most probably generated by the partial melting of the metasomatized lithospheric mantle at relatively shallow depths (<80 km). The Xiemisitai mafic dike–granite association could have been triggered by asthenospheric upwelling as a result of the rollback of the subducted Irtysh–Zaysan oceanic lithosphere. 相似文献
Urban land cover has major impacts on a city’s ecosystem services and the inherent quality of its urban residential environment. The spatio-temporal distribution of impervious surface area and green areas in Chinese cities has exhibited a significantly marked difference in comparison with USA cities. This study focused on monitoring and comparing the spatio-temporal dynamics, land cover patterns and characteristics of functional regions in six Chinese(n=3) and USA(n=3) cities. The study data were collated from Landsat TM/MSS imagery during the period 1978–2010. Results indicate that Chinese cities have developed compactly over the past three decades, while development has been notably dispersed among USA cities. Mean vegetation coverage in USA cities is approximately 2.2 times that found amongst Chinese urban agglomerations. Land use types within Chinese cities are significantly more complex, with a higher density of impervious surface area. Conversely, the central business district(CBD) and residential areas within USA cities were comprised of a lower proportion of impervious surface area and a higher proportion of green land. Results may be used to contribute to future urban planning and administration efforts in both China and the USA. 相似文献
The Solonker suture zone of the Central Asian Orogenic Belt (CAOB) records the final closure of the Paleo-Asian Ocean. The nature and timing of final collision along the Solonker suture has long been controversial, partly because of an incomplete record of isotopic ages and differing interpretations of the geological environments of key tectonic units. The Xilin Gol Complex, consisting of strongly deformed gneisses, schists and amphibolites, is such a key tectonic unit within the CAOB. Lenticular or quasi-lamellar amphibolites are dispersed throughout the complex, intercalated with biotite–plagioclase gneiss. Both rock types experienced amphibolite-facies metamorphism. The protolith of the amphibolite is a basic rock that intruded into the biotite–plagioclase gneiss at 319 ± 4 Ma based on LA-ICPMS zircon U–Pb dating. The basic intrusion was sourced from a modified magma that experienced crystal fractionation and was admixed with slab-derived fluids. The slab-derived fluids, which formed during Early Paleozoic oceanic subduction along the north-dipping Sonidzuoqi–Xilinhot subduction zone, mixed with the magma source and produced subduction-related geochemical signatures superimposed on volcanic arc chemistry. After Early Paleozoic oceanic subduction and arc-continent collision, a transient stage of extension occurred between 313 and 280 Ma in the Sonidzuoqi–Xilinhot area. Deformation and recrystallization during the switch from compression to extension and reheating by the later magmatic intrusions reset the isotope systems of minerals in the Xilin Gol Complex, recorded by a 312.2 ± 1.5 Ma biotite 40Ar/39Ar age from biotite–plagioclase gneiss, a 309 ± 12 Ma zircon intercept age and a 307.5 ± 3.5 Ma hornblende 40Ar/39Ar age from amphibolites in the complex. There was an arc/forearc-related marine basin at the southern margin of the Xilin Gol Complex during the Permian. The closure of the oceanic basin led to Late Paleozoic–Middle Triassic north-dipping subduction beneath the Xilin Gol Complex and induced the amphibolite-facies metamorphism of the complex. The final suturing of the Solonker zone occurred from 269 to 231 Ma. This latest amphibolite-facies metamorphism with pressures of 0.31–0.39 GPa and temperatures of 620–660 °C was recorded at 263.4 ± 1.4 Ma to the Xilin Gol Complex, as indicated by the hornblende 40Ar/39Ar age from the amphibolites, as well as several zircon ages of 260 ± 3–231 ± 3 Ma. The Xilin Gol Complex documented the progressive accretion of a single, long-lived subduction system at the southern margin of the south Mongolian microcontinent from the Early Paleozoic (~452 Ma) to Middle Triassic (~231 Ma). The CAOB shows protracted collision prior to final suturing. 相似文献
Voluminous granitoids are widely distributed in the Langshan region, northeast of the Alxa block, and record the evolutionary processes of the southern Central Asian Orogenic Belt. The Dabashan pluton was emplaced into the Paleoproterozoic Diebusige complex. Early Carboniferous zircon LA-ICP MS U-Pb ages were from 327 Ma to 346 Ma. The Dabashan pluton can be classified as monzogranite and syenogranite, and exhibits high K2O contents and K2O/Na2O ratios, which reveal a high-K calc-alkaline nature. The samples display strongly fractionated REE patterns, and are enriched in large ion lithophile elements (LILE) relative to high field strength elements (HFSE). The Dabashan plutons display unusually high Ba (823–2817 ppm) and Sr (166–520 ppm) contents and K/Rb ratios (315–627), but low Rb/Ba ratios (0.02–0.14), and exhibit fertile zircon Hf isotopic compositions [εHf(t)=?14 to ?20], which are comparable to those of typical high Ba–Sr granitoids. Based on the geochemical compositions of the samples, we suggest that subducted sediments and ancient crustal materials both played important roles in their generation. Basaltic melts were derived from partial melting of subcontinental lithophile mantle metasomatized by subducted sediment-related melts with residual garnet in the source, which caused partial melting of ancient lower crust. Magmas derived from underplating ascended and emplaced in the middle–upper crust at different depths. The resultant magmas experienced some degree of fractional crystallization during their ascent. Given these geochemical characteristics, together with regional tectonic, magmatic, and structure analysis data, an active continental margin environment is proposed for the generation of these rocks. 相似文献