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21.
The Cretaceous-Eocene volcano-sedimentary units of the Zonguldak region of the western Black Sea consist of subalkaline andesite and tuff, and sandstone dominated by smectite, kaolinite, accessory chlorite, illite, mordenite, and analcime associated with feldspar, quartz, opal-CT, amphibole, and calcite. Kaolinization, chloritization, sericitization, albitization, Fe–Ti-oxidation, and the presence of zeolite, epidote, and illite in andesitic rocks and tuffaceous materials developed as a result of the degradation of a glass shards matrix, enclosed feldspar, and clinopyroxene-type phenocrysts, due to alteration processes. The association of feldspar and glass with smectite and kaolinite, and the suborientation of feldspar-edged, subparallel kaolinite plates to fracture axes may exhibit an authigenic smectite or kaolinite. Increased alteration degree upward in which Al, Fe, and Ti are gained, and Si, Na, K, and Ca are depleted, is due to the alteration following possible diagenesis and hydrothermal activities. Micromorphologically, fibrous mordenite in the altered units and the presence of needle-type chrysotile in the residential buildings in which cancer cases lived were detected. In addition, the segregation pattern of cancer susceptibility in the region strongly suggested an environmental effect and a genetic influence on the increased cancer incidence in the region. The most likely diagnosis was Li-Fraumeni syndrome, which is one of the hereditary cancer predisposition syndromes; however, no mutations were observed in the p53 gene, which is the major cause of Li-Fraumeni syndrome. The micromorphology observed in the altered units in which cancer cases were detected may have a role in the expression of an unidentified gene, but does not explain alone the occurrence of cancer as a primary cause in the region.  相似文献   
22.
Monitored natural attenuation can be a viable option for remediation of groundwater contamination by BTEX compounds. Under the field conditions, the rate of contaminant mass attenuation through natural processes, such as biodegradation, to a large extent affected by the groundwater flow regime, which is primarily controlled by the aquifer heterogeneity. Numerical simulation techniques were used to describe quantitatively the relationship between biodegradation rate of BTEX and aquifer heterogeneity. Different levels of aquifer heterogeneity were described by random hydraulic conductivity fields (K) having different statistical parameters, the coefficient of variation (CV) and the correlation length (h). The Turning Bands Algorithm was used to generate such K fields. Visual MODFLOW/RT3D was used to simulate the fate and transport of dissolved BTEX plume within heterogeneous aquifers. The multispecies reactive transport approach described BTEX degradation using multiple terminal electron-accepting processes. First-order biodegradation rate constants were calculated from simulated BTEX plumes in heterogeneous flow fields. The results showed that aquifer heterogeneity significantly affected biodegradation rate; it decreased with increasing CV when h was in the range of up to 12 m, whereas it increased with increasing CV when h was greater than about 12 m. For well characterized aquifers, this finding could be of great value in assessing the effectiveness of natural attenuation during feasibility studies at BTEX contaminated sites.  相似文献   
23.
Two major earthquakes occurred on October 23rd, 2011 (M=7.1) and November 9th, 2011 (M=5.6) in Tabanli and Edremit districts of Van province in Turkey, respectively. New settlement areas for Van city were determined after these destructive earthquakes. One of the most important areas for new settlements to be built was Edremit region, consisting travertine where nearly 80% of new housing units (12.384) were built by TOKI (Housing Development Administration of Turkey). Travertines have different lithotypes depending on their depositional process such as crystalline crust, shrub, reed which can affect mechanical and engineering properties of travertine and each level has different handicaps. The purpose of this study is to investigate the relationship between lithotype and physico-mechanical properties of travertines. According to the results, lithotype has an effect on physical, mechanical and rock mass properties of travertine. It is ascertained by several research methods that various handicaps may occur on such areas when the active tectonic structure of the area is evaluated along with the karstic cavities within the travertine and different lithotype qualities.  相似文献   
24.
The present study aims to provide carbon-isotope curves for the Cenomanian to Turonian rudist-dominated successions in north Sinai. The high-resolution carbon-isotope curves obtained from north Sinai sections provide new insight for calibrating the age of rudists as well as for evaluating the effects of the oceanic anoxic event 2 (OAE2) on rudist communities. The primary goals are (1) to provide a high-resolution sequence stratigraphic framework for the Cenomanian-Turonian succession, (2) to use rudist and ammonite biostratigraphic data to distinguish the stratigraphic levels of the rudist species, and (3) to integrate the chemostratigraphic (δ13C) profile and the rudist levels to improve the biostratigraphy based on the rudist distributions and the carbon-isotope data. The recognition of three ammonite zones through the Cenomanian-Turonian succession was utilized to identify four temporally significant rudist levels indicative of the Lower Cenomanian, Middle Cenomanian, Upper Cenomanian, and Middle Turonian, respectively. Most of the rudists occur in the highstand deposits of medium-scale sequences. Carbon- and oxygen-isotopic analyses were carried out on both rudists and surrounding carbonate units. Based on the variations in the carbon-isotope signals, 12 chronostratigraphic segments were identified in the studied sections. The Cenomanian carbon-isotope segments (C23–C30) were obtained from the Halal Formation at Gabal Yelleg and Gabal Maaza sections, while the Turonian segments (C30–C34) were measured from the Wata Formation at Gabal Yelleg section. The carbon-isotope record from the studied sections is consistent with the trends documented in previous studies of the Tethyan realm. The Cenomanian-Turonian boundary is placed at the onset of falling carbon-isotope values (δ13C) from 2.61 to ?0.25‰ in the upper part of OAE2 with the carbon-isotope segment C30 at Gabal Yelleg. The negative shift in δ13C values (C33) occurred in the Middle Turonian lowstand deposits characterizing the global sea level fall during this interval.  相似文献   
25.
The short-term periodicities of the flare index are investigated in detail using Fourier and wavelet transforms for the full disc and for the northern and the southern hemispheres of the Sun separately over the epoch of almost 4 cycles (1966–2002). The most pronounced power peaks were found by the Fourier transform to be present at 25.6, 27.0, 30.2, and 33.8 days. The wavelet transform results show that the occurrence of periodicities of flare index power is highly intermittent in time. A comparison of the results of the Fourier transform and the time-period wavelet transform of the flare index time series has clarified the importance of different periodicities, whether they are or are not the harmonics of the basic ones, as well as the temporal location of their occurrence. We found that the modulation of the flare index due to the 27-day solar rotation is more pronounced during the declining portion of solar cycle than during the rising portion.  相似文献   
26.
Magnetic properties of samples from Bell Island sedimentary rocks have been studied. X-ray analysis indicates that the main magnetic mineral is hematite in all samples. The other iron-bearing minerals identified are siderite and chamosite. Microscope observations of thin sections suggest that the rocks consist of oolitic hematite in a matrix of siderite or calcite. The intensity of natural remanent magnetization (NRM) varies in the range of (0.03–0.4 A m?1), depending on the percentage of hematite. The thermal demagnetization curves of NRM show in some cases a sharp increase in magnetization at temperatures in the range 500–600°C. The peaks that occur in these demagnetization curves are due to a chemical change of siderite during repeated laboratory heating. X-ray analysis confirmed that the newly formed material is magnetite. Since the original NRM has been masked by the new intergrown material, this would result in a serious error in the determination of paleomagnetic pole positions. The samples showing this behaviour were not considered for paleomagnetic study. The samples containing oolitic hematite in a calcite matrix exhibit very high stability of NRM, including directional stability until almost 670°C. For these samples, a virtual pole position based on N = 6 samples (32 specimens) demagnetized to 665°C is 34°N, 114°E, not far from published Ordovician poles for the North American craton.  相似文献   
27.
Gksu Delta is an important wetland where the Gksu River reaches to sea in the eastern of the town Tasucu-Ice1. The delta is classified as a Wetland of International Impor-tance according to the Ramsar Convention on Wetlands of International Importance. The amount of fertilizers used in this area was 7200 tons in 2006. These pollutants affect the surface and groundwater quality negatively. The intensively used fertilizers and pesticides contain not only N- and P compounds but also some heavy metals. The contents of all pol-lutants in surface waters were determined for four different seasons between 2006 and 2008 and with these data a Geographic Information System (GIS) has been constructed by using Map Info. From the photometric heavy metal analysis, it is inferred that the excess concen-tration of Fe, Ni, Mn, Mo and Cu at some locations is the cause of undesirable quality for drinking purposes. The source of excess concentration of various heavy metals is the agri-cultural activities and fertilizers. It is determined that in all periods between 2006 and 2008 the heavy metals and other pollutants in the fertilizers and pesticides transported easily to river water with irrigation return flow. The organic pollutants, including COD, BOD, NH3 and NO3 followed the sharply increasing trends from Silifke city to Mediterranean Sea. The water quality of Gksu River is modeled and determined that the waste water discharge of 10,700 m3/day from Silifke city does not create a serious problem because of the high amount of flow rate of Gksu River.  相似文献   
28.
The UBV observations of the massive binary BF Aur were made at the Ankara University Observatory during 1988, 1989 and 1996. Asymmetry of the light curves, arising from unequal height of successive maxima, indicates that the system is active. By analysing these observations in the framework of the Roche model (including the presence of bright regions on the components) one obtains a semidetached configuration of the system, with the cooler secondary component filling its Roche lobe. The analysis of the light curves yields consistent solutions for mass ratio q = m2/m1 somewhat less than one. The influence of the mass transfer on the change of the system-orbital-period is relatively small. The upward parabolic character of the O–C diagram (Zhang et al., 1993) indicates a mass transfer from the less massive secondary to the more massive primary. This inturn requires the less massive secondary to fill its Roche lobe. This is consistent with our solution. Based on these facts we introduced the following working hypothesis. At the place where the gas stream from the secondary falls on the primary, relatively small in size but a high temperature contrast active hot-spot (hs) region is formed. As a result of the heating effect caused by the irradiation of the hot-spot region, on the secondary's side facing the hot spot a bright-spot (bs) region is formed. The bright-spot region is larger in size but with significantly lower temperature than the hot spot. This region can be treated as a ‘reflection cap’. By analysing the light curves in the framework of this working hypothesis the basic parameters of the system and the active regions are estimated. The problem is solved in two stages: by obtaining a synthetic light curve in the case when the parameters of the corresponding Close Binary (CB) Roche model (Djurašević, 1992a) are given a priori (the direct problem) and by determining the parameters of the given model for which the best fit between the synthetic light curve and the observations is achieved (the inverse problem) (Djurašević, 1992b). This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
29.
Summary. Titanomagnetites of composition Fe2.4-δAlδTi0.6O4 and Fe2.6-δAlδTi0–4O4(δ=0, 0.1 and 0.2 in both cases) were prepared in the monodomain state by pulverization of sintered synthetic material. In low fields, the thermoremanence (TRM) was found to be linear with inducing field and of high enough intensity to account for typical natural remanent magnetizations of fresh submarine basalts. The higher field TRM acquisition curves follow the Néel model curve for an assemblage of non-interacting identical particles in a general way only, the differences being due to interactions, or the range of particle blocking temperatures and volumes or other features of the samples not included in the model. The unblocking temperatures of low field TRM lie in a narrow range below the Curie point. The low field TRM is very resistant to alternating field demagnetization and provides a very striking illustration of the strength of the TRM mechanism in preserving a stable record of a weak magnetic field. The result of a Lowrie-Fuller test on the material is consistent with the monodomain state.  相似文献   
30.
A Paleoarchean impact spherule‐bearing interval of the 763 m long International Continental Scientific Drilling Program (ICDP) drill core BARB5 from the lower Mapepe Formation of the Fig Tree Group, Barberton Mountain Land (South Africa) was investigated using nondestructive analytical techniques. The results of visual observation, infrared (IR) spectroscopic imaging, and micro‐X‐ray fluorescence (μXRF) of drill cores are presented. Petrographic and sedimentary features, as well as major and trace element compositions of lithologies from the micrometer to kilometer‐scale, assisted in the localization and characterization of eight spherule‐bearing intervals between 512.6 and 510.5 m depth. The spherule layers occur in a strongly deformed section between 517 and 503 m, and the rocks in the core above and below are clearly less disturbed. The μXRF element maps show that spherule layers have similar petrographic and geochemical characteristics but differences in (1) sorting of two types of spherules and (2) occurrence of primary minerals (Ni‐Cr spinel and zircon). We favor a single impact scenario followed by postimpact reworking, and subsequent alteration. The spherule layers are Al2O3‐rich and can be distinguished from the Al2O3‐poor marine sediments by distinct Al‐OH absorption features in the short wave infrared (SWIR) region of the electromagnetic spectrum. Infrared images can cover tens to hundreds of square meters of lithologies and, thus, may be used to search for Al‐OH‐rich spherule layers in Al2O3‐poor sediments, such as Eoarchean metasediments, where the textural characteristics of the spherule layers are obscured by metamorphism.  相似文献   
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