Strontium Isotope Geochemistry and Petrogenesis of the Early Tertiary Lava Pile of the Isle of Skye, Scotland, and other Basic Rocks of the British Tertiary Province: an Example of Magma--Crust Interaction

Most of the flows in the Palaeocene lava pile remnant of Skyeare members of the Skye Main Lava Series (SMLS), comprisingtransitional basalts and two associated suites of evolved lavas.The first suite evolves through Fe-rich hawaiites and mugearitesto benmoreites, and the second suite evolves through Fe-poorintermediates to trachytes. Ca-rich, alkali-poor olivine tholeiites(the Preshal Mhor magma type) occur as sparse flows in the stratigraphicallyhighest parts of the lava pile remnant and are abundant in thedyke swarm transecting it. Initial ⁸⁷Sr/⁸⁶Sr ratios rangingfrom 0.70308 to 0.70571 in 45 SMLS samples show no significantcorrelation with degree of zeolitization (H₂O⁺), silica saturation,or ⁸⁷Rb/⁸⁶Sr. A moderately good negative correlation with totalSr confirms published Pb-isotope evidence of interaction withancient, sialic crust. Details of the (⁸⁷Sr/⁸⁶Sr)_l versus Srpattern are consistent with previous hypotheses that the SMLSbasalt-benmoreite suite evolved at a depth near the Moho, whilstthe low-Fe trend to trachyte resulted from near-surface basaltfractionation. (⁸⁷Sr/⁸⁶Sr)_l values ranging from 0.70307 to 0.70621 for PreshalMhor basalts show a strong positive correlation with total Sr,consistent with a model of extensive fractionation within theupper crust of a mantle-derived low ⁸⁷Sr/⁸⁶Sr-low Sr magma,which became progressively contaminated with comparatively radiogeniccrustal Sr. The lowest measured (⁸⁷Sr/⁸⁶Sr)_l values of 0.70307and 0.70308, for a Preshal Mhor basalt and for an SMLS basaltrespectively, are consistent with the hypothesis that thesetwo magma types were produced by successive phases of partialmelting from a single volume of upper mantle. (⁸⁷Sr/⁸⁶Sr)_l values for additional miscellaneous basaltic lavas,dykes and major intrusives from Skye and from nearby Isle ofMull exhibit considerable variability within the range 0.7038to 0.7072, whilst three basaltic dykes from Northern Englandare in the range 0.7089 to 0.7123. The latter values overlapwith published (⁸⁷Sr/⁸⁶Sr)_l values for some of the granitesin the Tertiary Province of northwest Scotland and indirectlyremove objections based on Sr-isotopic arguments to the genesisof the granites by fractionation of basalt contaminated withcrustal Sr, but neither prove this nor disprove large-scalecrustal partial fusion.     

Meteorites at Meridiani Planum provide evidence for significant amounts of surface and near‐surface water on early Mars

Abstract– Six large iron meteorites have been discovered in the Meridiani Planum region of Mars by the Mars Exploration Rover Opportunity in a nearly 25 km‐long traverse. Herein, we review and synthesize the available data to propose that the discovery and characteristics of the six meteorites could be explained as the result of their impact into a soft and wet surface, sometime during the Noachian or the Hesperian, subsequently to be exposed at the Martian surface through differential erosion. As recorded by its sediments and chemical deposits, Meridiani has been interpreted to have undergone a watery past, including a shallow sea, a playa, an environment of fluctuating ground water, and/or an icy landscape. Meteorites could have been encased upon impact and/or subsequently buried, and kept underground for a long time, shielded from the atmosphere. The meteorites apparently underwent significant chemical weathering due to aqueous alteration, as indicated by cavernous features that suggest differential acidic corrosion removing less resistant material and softer inclusions. During the Amazonian, the almost complete disappearance of surface water and desiccation of the landscape, followed by induration of the sediments and subsequent differential erosion and degradation of Meridiani sediments, including at least 10–80 m of deflation in the last 3–3.5 Gy, would have exposed the buried meteorites. We conclude that the iron meteorites support the hypothesis that Mars once had a denser atmosphere and considerable amounts of water and/or water ice at and/or near the surface.     

Volcanism in the Vitim Volcanic Field, Siberia: Geochemical Evidence for a Mantle Plume Beneath the Baikal Rift Zone

The Baikal Rift is a zone of active lithospheric extension adjacentto the Siberian Craton. The 6–16 Myr old Vitim VolcanicField (VVF) lies approximately 200 km east of the rift axisand consists of 5000 km³ of melanephelinites, basanites, alkaliand tholeiitic basalts, and minor nephelinites. In the volcanicpile, 142 drill core samples were used to study temporal andspatial variations. Variations in major element abundances (e.g.MgO = 3·3–14·6 wt %) reflect polybaric fractionalcrystallization of olivine, clinopyroxene and plagioclase. ⁸⁷Sr/⁸⁶Sr_i(0·7039–0·7049), ¹⁴³Nd/¹⁴⁴Nd_i (0·5127–0·5129)and ¹⁷⁶Hf/¹⁷⁷Hf_i (0·2829–0·2830) ratiosare similar to those for ocean island basalts and suggest thatthe magmas have not assimilated significant amounts of continentalcrust. Variable degrees of partial melting appear to be responsiblefor differences in Na₂O, P₂O₅, K₂O and incompatible trace elementabundances in the most primitive (high-MgO) magmas. Fractionatedheavy rare earth element (HREE) ratios (e.g. [Gd/Lu]_n > 2·5)indicate that the parental magmas of the Vitim lavas were predominantlygenerated within the garnet stability field. Forward major elementand REE inversion models suggest that the tholeiitic and alkalibasalts were generated by decompression melting of a fertileperidotite source within the convecting mantle beneath Vitim.Ba/Sr ratios and negative K anomalies in normalized multi-elementplots suggest that phlogopite was a residual mantle phase duringthe genesis of the nephelinites and basanites. Relatively highlight REE (LREE) abundances in the silica-undersaturated meltsrequire a metasomatically enriched lithospheric mantle source.Results of forward major element modelling suggest that meltingof phlogopite-bearing pyroxenite veins could explain the majorelement composition of these melts. In support of this, pyroxenitexenoliths have been found in the VVF. High Cenozoic mantle potentialtemperatures (1450°C) predicted from geochemical modellingsuggest the presence of a mantle plume beneath the Baikal RiftZone. KEY WORDS: Baikal Rift; mafic magmatism; mantle plume; metasomatism; partial melting     

Holocene sediments and magnetic stratigraphy from Lakes Zug and Zurich, Switzerland

Piston cores 7 m and 6.5 m long were collected from Lakes Zug and Zurich respectively. Radiocarbon age determinations, pollen assemblage zones and varve counts indicate dates of 5000–6000 years B.P. (Zug), and 12,000–13,000 years B.P. (Zurich) for the base of the cores. Declination of the magnetic remanence varies through 70° and inclination varies through 30°. Although the correlation with the geomagnetic secular variation curve covering the last 15,000 years as determined from Lake Windermere, England (Creer et al., 1972) is not precise, the results suggest that Lake Zug and Lake Zurich sediments have been recording the broad outline of past secular variations of the earth's magnetic field. Since intensity of magnetization and susceptibility correlate markedly with lithology, a detailed sediment stratigraphy is presented. The amount and texture of the detrital input appears to be a controlling factor for the natural magnetic remanence. Intensity varies from 90 μG in zones of organic, sulphide pigmentation and those with ultra-fine laminations to 0.8 μG in impure lacustrine chalk. Susceptibility ranges from 9 μG/Oe in laminated, fine-grained glacially derived muds to 0.5 μG/Oe in impure lacustrine chalk. Intensity of magnetization also varies systematically within individual turbidites with lowest values in the coarse-grained, basal fractions. Slumped beds were identified on the basis of erratic anomalies in magnetic declination and inclination measurements.     

Monitoring wetland ditch water levels in the North Kent Marshes,UK, using Landsat TM imagery and ground-based measurements

Abstract

An understanding of hydrology is a prerequisite for ensuring the successful management, conservation and restoration of wetland environments. Frequently, however, little is known about historical hydrological conditions, such as water levels, within wetlands. Moreover, many channel and ditch systems in wetlands are not routinely monitored, except perhaps for research purposes. A methodology is presented herein which makes use of satellite imagery to indirectly provide remotely sensed observations of water levels within channels and ditches. Using multi-temporal Landsat Thematic Mapper (TM) imagery and simultaneous ground-based measurements of water levels, statistical relationships are established between satellite-derived effective wet ditch widths and measured water levels in the drainage system of the Elmley Marshes, southeast England. These relationships can be used subsequently to estimate historical ditch water levels and to monitor contemporary ditch water levels in the wetland. The study shows that satellite imagery has much to offer in monitoring changes in the hydrological regime of wetlands and in providing complimentary approaches to field monitoring.     

数据稀缺生态系统中多种类质量谱模型的构建

多种类生态模型已经被广泛应用于渔业活动影响应预测和管理措施效果评估。质量谱模型是一种基于生理过程构建的生态模型,该模型为描述鱼类群落在个体摄食变异和随个体发生的生态位迁移提供了一个可行的方法。尽管生态模型在增进生态系统认识上具有重要意义,其应用在数据稀缺的渔业中受到很大限制。作为实践基于生态系统渔业管理(EBFM)的第一步,本研究构建了海州湾鱼类群落的质量谱模型。本研究详述了数据收集和模型参数化的过程,以促进该模型在数据稀缺的生态系统中未来的应用。作为一个范例,研究展示了不同捕捞努力量对生态系统的影响,并采用一套生态指标监测其动态。群落生物量、多样性指数、W指数,大鱼指数(LFI),平均体重和群落质量谱斜率对捕捞压力的响应呈非线性,最大的捕捞强度并非总是对鱼类群落产生最强的影响。本文强调了构建谱模型在生态研究中的的价值和可行性,并讨论了模型的局限性和改进的可能。本研究旨在促进质量谱模型的广泛应用以更好地支持基于生态系统的渔业管理。     

Calc--Silicate Diffusion Zones between Marble and Pelitic Schist

Four distinct calc-silicate zones are observed between interlayeredmarble and pelite in roof-pendant (Gile Mountain Fm.) of a graniticintrusive at Lake Willoughby in northern Vermont. The zonesare characterized by garnet, coarse diopside-clinozoisite, fineclinozoisitediopside and amphibole-plagioclase. The bulk compositionsof the zones, calculated from modal data and microprobe analyses,deviate significantly from a gradational mixture marble andpelite. The observed zonal sequence is close to that predictedby a simple model of cation diffusion metasomatism. Possiblelocations of the initial marble-pelite boundary are suggestedon the basis of bulk compositional data and petrographic evidence.Calculated mass balance relations for the formation of the zonesby diffusion at constant volume are unrealistic for reasonablelocations of the initial boundary. Calculated mass balance relationsat constant AL₂O₃ suggest a volume decrease of about one thirdduring formation of the diffusion zones wholly from the pelite.In addition the data suggest that nearly equal volumes of initialmarble and pelite have disappeared, leading to a total volumedecrease of near 50 percent. The observations suggest that diffusionof calcium was dominant and that diffusion of aluminium, ironand magnesium was relatively unimportant. Evaluation relativediffusional mobilities is shown to be possible but intractablewith the quality available thermochemical data and activity-concentrationrelations of crystalline solutions.     

Early Cretaceous Basalt and Picrite Dykes of the Southern Etendeka Region, NW Namibia: Windows into the Role of the Tristan Mantle Plume in Parana-Etendeka Magmatism

Abundant dykes in the southern Etendeka region, NW Namibia,mostly contain 8–20% MgO. Almost all can be allocatedto previously described Early Cretaceous magma types. Horingbaai-typebasalts–picrites occur up to 120 km inland. Some havesuperficially mid-ocean ridge basalt (MORB)-like compositions:(La/Nb)_n     

Reactions in Amphibolite, Greenschist and Blueschist

Mineral assemblages in which chlorite [CHL], epidote [EPI],clinoamphibole [AMP], plagioclase [PLG] and quartz [QTZ] aremajor phases are characteristic of many low-grade mafic schists.The possible heterogeneous reactions in such an assemblage maybe separated into two types, exchange reactions and net-transferreactions. Only the latter alter significantly the modal proportionsof the minerals. A set of linearly independent reactions defines a reaction spaceof as many dimensions as there are independent reactions. Thespace defined by the net-transfer reactions alone is a sub-spacethat can be portrayed in three dimensions for the above assemblage.A procedure is presented herein that gives a set of independentreactions that may be taken as basis reactions for definingsuch a reaction space. All other reactions that can be writtenfor this assemblage, as well as observed whole-rock reactions,can be portrayed as vectors in these reaction spaces. Thesevectors connect the region (mineral facies) accessible to theabove assemblage. The whole-rock reactions of Laird (1980) relatinggreenschist, blueschist and various low-grade amphibolites fromVermont, provide informative examples, as do the whole-rockexperiments of Liou et al. (1974). Although reaction spaces apply to both equilibrium and disequilibriumassemblages the reactions selected as basis vectors correspondone-for-one to the chemical conditions for equilibrium thatmust obtain in any fully equilibrated assemblage. The set selectedis one that provides maximum sensitivity for geothermometric,geobarometric and geohygrometric purposes.