Constraints on incipient charnockite formation from zircon geochronology and rare earth element characteristics

We present high spatial resolution ion-microprobe U–Th–Pb geochronology and rare earth element (REE) data combined with cathodoluminescence (CL) and back-scattered electron (BSE) imaging for complex zircons in incipient charnockites from Söndrum, SW Sweden. Examination of closely paired samples across the dehydration zone demonstrates that incipient charnockite formation at Söndrum is a zircon-forming process. We determined the age of the dehydration event (i.e. charnockitisation) to 1,397 ± 4 Ma (2σ, MSWD = 1.7). This is the first successful attempt to date incipient charnockite formation using U–Pb systematics of zircon. Internal structure, chemical and isotopic characteristics of zircon indicate that the granitic pegmatite in the core of the incipient charnockite is a melting zone. Commonly observed bulk rock HREE depletion in incipient charnockites is not caused by zircon dissolution but by involvement of garnet as a reactant in the dehydration reactions. Moreover, REE patterns of the newly formed zircon are HREE-enriched, indicating non-concurrent growth and suggesting that the degree of charnockite depletion in HREE might be controlled by the volume of newly formed zircon.     

Recharge mode and mineralization of groundwater in a semi-arid region: Sidi Bouzid plain (central Tunisia)

Groundwater is the most important source of water supply in Sidi Bouzid plain located in central Tunisia. Proper understanding of the geochemical evolution of groundwater is important for sustainable development of water resources in this region. A hydrogeochemical survey was conducted on the Mio–Plio–Quaternary aquifer system using stable isotopes, radiocarbon, tritium and major elements, in order to evaluate the groundwater chemistry patterns and the main mineralization processes occurring in this system. The chemical data indicate that dissolution of evaporate minerals and evaporation are the main processes controlling groundwater mineralization. The isotopic data show that groundwater in the study area is a mixture of recent shallow waters located upstream and along Wadi Al Fakka bed and paleowaters located towards plain limits and discharge areas. Low ³H and ¹⁴C contents are observed in major part of the plain indicating that recharge of the aquifer occurs mainly through direct infiltration at Wadi Al Fakka while there is no evidence of significant recharge in major part of the plain and mountains piedmonts.     

Extraction procedures of toxic and mobile heavy metal fraction from complex mineralogical tailings affected by acid mine drainage

The wall rocks of Sidi Driss mineralization contain continental molassic deposits: lacustrine limestones, ferruginous fragments, Ed Diss unit and Numidian unit fragments, rhyodacitic fragments, pyroclasts, and gneissic fragments. The ore is composed of pyrite, marcasite, sphalerite, galena, barite, celestite, siderite, calcite, and iron oxide-hydroxides. The abandoned wastes in Sidi Driss-Tamra district contain marcasite, galena, goethite, jarosite, anglesite, anhydrite, bassanite, and gypsum. It is very important to assess the hazards and risks that this material type poses to public health and the environment. However, evaluation of a part of toxic elements always poses problems since the associated matrix, the close relationships between some minerals, the grain sizes and their forms (oolites, compact collomorphes aggregate), the oxidation degree of metals, the chemical composition, and trace elements make it difficult to extract mobile metals from complex Sidi Driss tailings and minerals found in these acidic wastes. Nevertheless, there is no universal method that can systematically evaluate metal bioavailability. And the use of proposed sequential extraction procedures for sediments with simple mineralogical composition did not yield any reproducible results for this type of acid mine drainage sediments. Consequently, the methods of controlling and mitigating the risks of hazardous materials should be considered. Many extraction procedures have been applied to better evaluate the mobility of hazardous materials (metals), the characterization of their degree of toxicity, and their chemical behavior in these complex mine tailings. Reproducible results were obtained with lab-scale washing of sediments using distilled water, CaCl₂ and Na₂-EDTA solutions, and BCR sequential extraction. The results showed that the BCR extraction approach was the most efficient procedure for these types of wastes. The extraction with distilled water is recommended for identification of the total quantity of mobile Cr and Fe.     

Contourites in the Gulf of Cadiz: a cautionary note on potentially ambiguous indicators of bottom current velocity

Facies associations in cores collected in the deep part of the Gulf of Cadiz, which is under the influence of the lower branch of the Mediterranean Outflow Water, are investigated in terms of the classical contourite model using grain-size analyses and thin sections of indurated sediment. Cores include both low-energy (contourite drift) and high-energy (channel) environments. The thin sections and grain-size distributions show that clayey fine silts and sandy coarse silts are the most common facies associations in the studied contourite sequences, while coarse-grained, gravelly contourites are less common. Grain-size distributions are unimodal in the fine-grained and bi- or trimodal in the coarser-grained contourites. This change in grain-size composition is related both to the partial removal of the fine-grained fraction and to the replenishment of the coarser-grained one. In addition, most of the contacts between individual facies are sharp rather than transitional. This suggests that the contourite sequence is only in part related to changes in bottom current velocity and flow competency, but may also be related to the supply of a coarser terrigeneous particle stock, provided by either increased erosion of indurated mud along the flanks of confined contourite channels (mud clasts), or by increased sediment supply by rivers (quartz grains) and downslope mass transport on the continental shelf and upper slope. The classical contourite facies association may therefore not be solely controlled by current velocity, but may be the product of a variety of depositional histories. The classical contourite depositional sequence should therefore be interpreted with greater care and in the light of the regional sedimentological background. In addition, the wisdom of exclusively using mean or modal particle size for the interpretation of depositional contourite processes is questioned. Instead, it is proposed that the vertical evolution of grain-size populations in the facies successions forming contourite sequences be assessed.     

Quantifying regional groundwater flow between Continental Intercalaire and Djeffara aquifers in southern Tunisia using isotope methods

Large-scale interaction between the Continental Intercalaire and the Djeffara aquifer systems in the southeast of Tunisia has been investigated with the aid of chemical and isotopic tracers. Two distinct groundwater types have been identified: (1) the Continental Intercalaire groundwater characterized by elevated temperatures (50–61.4°C), low δ¹⁸O (−8.4 to−7.87) and δ²H (−67.2 to−59) values and negligible radiocarbon content, both testifying its great age dating from the late Pleistocene period, and (2) the Djeffara groundwater with distinctly heavier isotopic composition (δ¹⁸O = −8.31 to −5.80, δ²H = −65.9 to −31.9). The Djeffara groundwaters reveal a distinct changes of physico-chemical and isotopic parameters near El Hamma Faults in the northwestern part of the Djeffara basin. These changes could possibly be explained by a vertical leakage from the Continental Intercalaire aquifer through El Hamma Faults. The mixing proportions inferred from stable isotope mass balance prove that the contribution of the Continental Intercalaire to the recharge of Djeffara aquifer is very significant and may reach 100% in the El Hamma region and in the northern part of Gabes. Isotope tracers strongly suggest that recent recharge to the Djeffara aquifer system is very limited. Its current yield, particularly in its central and northern parts can be maintained only thanks to large-scale underground inflow from the Continental Intercalaire aquifer system, which carries late Pleistocene palaeowater. Consequently, current exploitation of groundwater resources of the Djeffara aquifer has non-sustainable character.     

Application of geochemical tracers for the investigations of groundwater resources in semi-arid region (Central-East Tunisia)

Groundwater resources in Mahdia-Ksour Essef region, located in the central-eastern part of Tunisia, suffer from intensive exploitation and degradation of water quality. The assessment of groundwater vulnerability, the well-understanding of geochemical processes and the investigation of groundwater quality variations are of particular importance for water resources management in this semi-arid region. The results of this multi-disciplinary investigation show that groundwaters of Mahdia-Ksour Essef region are flowing from El Jem and Boumerdes regions in the South, towards the Mediterranean Sea and the sebkha of Moknine in the North. The groundwaters are classified as either Na-Cl or Ca-SO₄. Stable oxygen and hydrogen isotope compositions (δ¹⁸O and δ²H) confirm a recharge by rapid water infiltration, evaporate surface water and water-rock interaction processes in the salinity increase. The rock-water interaction processes of the mineralization of groundwaters include the cation-exchange reactions and the dissolution of carbonates and evaporate. The high values of the water quality index (WQI) and of the total dissolved solids (TDS) (3.7–11 g/L) of these groundwaters indicate their unsuitability for drinking purpose. Moreover, the combination of the WQI, TDS and nitrate results prove the vulnerability of the studied groundwater to the anthropogenic pollution linked to agriculture and domestic activities and to the salt water contamination.     

Optical remote sensing of turbidity and total suspended matter in the Gulf of Gabes

Optical remote sensing was used to provide scientific information to support environmental management in the Gulf of Gabes that is located in the southeastern coast of Tunisia. This region is characterized by shallow continental shelf subjected to semi-diurnal tides. Industrial activities in this area since the early 1970s may have contributed to the degradation of the biodiversity of the ecosystem with eutrophication problems and disappearance of benthic and planktonic species. To assess the long-term effect of anthropogenic and natural discharges on the Gulf of Gabes, the optical environment of the coastal waters is assessed from in situ measurements of total suspended matter concentration (TSM), Secchi depth and turbidity (TU). This monitoring requires regular seaborne measurements (monthly), which is very expensive and difficult to obtain. The objective of the present study is the evaluation of the Moderate Resolution Imaging Spectrometer (MODIS) AQUA data compared with two sampling campaigns realized at the study area. To map turbidity data from MODIS images, a semi-empirical algorithm was applied at band 667 nm. This bio-optical algorithm has already been calibrated and validated on the Belgian coast. The validation of this algorithm on the Gulf of Gabes using in situ measurements of turbidity and remotely sensed turbidity obtained from MODIS imagery shows a correlation coefficient of 68.9%. Seasonal and annual average maps for TSM and TU were then computed over the Gulf of Gabes using MODIS imagery. The obtained results of TSM and TU from remotely sensed data are conformable with those obtained through the analysis of in situ measurements. Therefore, remote sensing techniques offer a better and efficient tool for mapping and monitoring turbidity over the whole region.     

Modeling GPS satellite attitude variation for precise orbit determination

High precision geodetic applications of the Global Positioning System (GPS) require highly precise ephemerides of the GPS satellites. An accurate model for the non-gravitational forces on the GPS satellites is a key to high quality GPS orbit determination, especially in long arcs. In this paper the effect of the satellite solar panel orientation error is investigated. These effects are approximated by empirical functions to model the satellite attitude variation in long arc orbit fit. Experiments show that major part of the long arc GPS orbit errors can be accommodated by introducing a periodic variation of the satellite solar panel orientation with respect to the satellite-Sun direction, the desired direction for solar panel normal vector, with an amplitude of about 1 degree and with a frequency of once per orbit revolution.