19802000北京市农业土地生产性的变动分析

根据1980、1990、2000年的统计资料和实地走访观察,本文分析了北京市乡镇一级的粮食作物、蔬菜作物和果品作物的分布格局及农业土地生产性近20年的变化。研究认为:1980年北京农业生产分布格局与土地生产性为比较典型的杜能模式;随着农业经营的多样化,1990年和2000年北京农业土地生产性呈现出多样的分布格局;北京粮食作物、蔬菜作物、果品作物的分布格局及农业土地生产性近20年的变化与此阶段的农业生产政策、农业以外的社会经济活动变化有较强的关联性;对北京以上问题的研究为验证杜能、辛克利亚、布莱昂特城市周边农业地域研究经典理论的演变提供了实证案例。     

Restructuring of polygalacturonate on alumina upon hydration—Effect on phosphate sorption kinetics

Hydration of organic coatings in soils is expected to affect the sorption of oxyanions onto hydrous Fe and Al oxides. We hypothesized that the hydration of polygalacturonate (PGA) coatings on alumina (Al₂O₃) increases their permeability for phosphate. Pure and PGA-coated alumina were equilibrated in deionized water for 2 and 170 h at pH 5 and 20 °C before studying (i) their porosity with N₂ gas adsorption and ¹H NMR relaxometry, (ii) structural changes of PGA-coatings with differential scanning calorimetry (DSC), and (iii) the kinetics of phosphate sorption and PGA desorption in batch experiments. Scanning electron micrographs revealed that PGA molecules formed three-dimensional networks with pores ranging in size from <10 to several hundred nanometers. Our NMR results showed that the water content of intraparticle alumina pores decreased upon PGA sorption, indicating a displacement of pore water by PGA. The amount of water in interparticle alumina pores increased strongly after PGA addition, however, and was attributed to water in pores of PGA and/or in pores at the PGA-alumina interface. The flexibility of PGA molecules and the fraction of a PGA gel phase increased within one week of hydration, implying restructuring of PGA. Hydration of PGA coatings increased the amount of phosphate defined as instantaneously sorbed by 84%, showing that restructuring of PGA enhanced the accessibility of phosphate to external alumina surfaces. Despite the fact that the efficacy of phosphate to displace PGA was higher after 170 h than after 2 h, a higher phosphate surface loading was required after 170 h to set off PGA desorption. Our findings imply that the number of PGA chain segments directly attached to the alumina surface decreased with time. We conclude that hydration/dehydration of polymeric surface coatings affects the sorption kinetics of oxyanions, and may thus control the sorption and transport of solutes in soils.     

Uniaxial compression and tension tests of anthracite and loading rate dependence of peak strength

The mechanical characteristics of coal under uniaxial compressive stress and uniaxial tensile stress are key factors in investigations of the stability of galleries and coal faces, and are vital considerations for the efficient design of coalmines, disaster prevention, and environmental preservation. These mechanical characteristics have long been a topic of research, but remain insufficiently understood. In this study we performed uniaxial compression tests and uniaxial tension tests on coal, with particular attention to two concerns. The first was to measure the loading rate dependence of the peak strength of coal. Coal shows high sample-to-sample scatter in strength; test methods that are successful in comparatively homogeneous rock types cannot be used for coal. We therefore used an alternative test method that was recently developed by the authors. Anthracite samples were subjected to alternating slow and fast strain rates. Measured variations in stress during this process were used to estimate the loading rate dependence of peak strength. The second objective was to obtain complete stress–strain curves for coal under uniaxial tensile stress. It is difficult to hold samples secure during a tensile test; consequently, such curves have yet to be obtained. This study presents a successful application of the authors' method to the analysis of coal samples, yielding a complete stress–strain curve under tensile stress. The two methods presented here hold promise for application not only to anthracite but also to a wide variety of coals. It is possible to derive the values of the constants used in constitutive equations from the obtained experimental results. Once these equations are determined, they can be incorporated into finite-element software to investigate various time-dependent behaviors of coal and aid in the efficient design of coalmines and the prevention of subsidence and mine disasters.     

Exploiting the dual functions of polymer depressants in fine particle flotation

Fine hydrophilic particles are known to be entrained with water in flotation of many ores. Flocculation of the hydrophilic particles by polymer depressants could potentially reduce the mechanical entrainment of these particles. This paper reports testwork completed on fine particles of several solids, iron oxide, hydroxyapatite and sphalerite, as well as on a relatively coarse quartz sample (− 75 + 38 μm). Dodecylamine was used as a collector for quartz, and several dispersants and polymer depressants, including sodium silicate, sodium metaphosphate, zinc sulfate, cornstarch, corn dextrin and carboxymethyl celluloses (with molecular weights of both 700,000 and 80,000) were used as flotation modifiers. The major part of the testwork involved flotation tests in a 200 mL flotation column. It was observed that flocculation of the fine hydrophilic particles significantly reduced their mechanical entrainment, while dispersion severely aggravated it. Thus, in the flotation separation of synthetic mixtures of the − 75 + 38 μm quartz and fine (reagent grade) iron oxide or hydroxyapatite, polymer depressants that caused flocculation performed better than those that did not cause flocculation.     

贵州南部“半边街式”铅锌矿床地质特征及其成因探讨

贵州省南部地区是全国重要的汞、锑资源分布区。2000年由于产于上泥盆统中铅锌矿的陆续发现,贵州省地矿局启动了以铅锌资源评价和成矿规律研究为主的地质工作,目标是总结铅锌矿产出的地质特征和成矿规律。通过三年的研究认为,该区处扬子准地台、华南褶皱带和右江造山带交汇部位,受晚古生代初期发生的陆内裂谷活动影响,产生了一个与桂中台陷相连的大型沉积凹陷区—黔南台陷沉积区,形成了巨厚碳酸盐和碎屑岩沉积,产生了与裂陷盆地边缘同沉积断层活动有关的低温成矿作用,造成了在晚泥盆纪以前的地层中汞、锑、砷、金、铅锌等矿床沿同沉积断层密集分布。本文通过矿床特征总结和矿床成因探讨,建立了准同生沉积成矿作用模式,旨在为该区寻找这类矿床提供参考和借鉴作用。     

Adsorption of aluminium by a latosol as affected by phosphate and glutamic acid

The effect of phosphate and glutamic acid on adsorption of aluminium onto a latosol was investigated as a function of pH and ligand concentrations through batch equilibrium experiments. The results showed that adsorption of aluminium by the soil was enhanced after addition of phosphate at low pH, and this promotive effect was gradually eliminated with the increase in pH. The positive effect of phosphate on aluminium adsorption onto latosol was attributed to phosphate-induced surface negative charge and formation of ternary surface complexes involving aluminium and phosphate. While using silica as adsorbent, the inactive surfaces for phosphate, promotion of adsorption of aluminium by phosphate was also found. Then it was proposed that additional aluminium might bind to the phosphate adsorbed onto the silica in the form of surface complexes silica–aluminium–phosphate again, and the mechanism might operate in the soil systems as well. Glutamic acid exhibited no influence on the adsorption of aluminium by the soil at low pH. After increasing the pH, adsorption of aluminium was inhibited especially with the highest addition of glutamic acid, probably owing to weak affinity of complexes between glutamic acid and aluminium to the soil.     

西北地区泥石流沟形态因素的非线性分析——以兰州市为例

以兰州市区96条主要的泥石流沟为例,利用分形理论的统计自相似性对泥石流沟数的累计分布随沟谷形态要素沟道比降、汇水面积和沟道长度的变化进行了分析;并与不同流域形态要素的分维进行了比较,探讨了分维不同的原因。兰州市区泥石流沟三个形态要素均具有统计意义上的自相似性,其中以汇水面积显示出分维最小(0.46),沟道长度次之(0.71),沟道比降最大(1.09)。分维的大小描述了作为系统的沟谷及其泥石流的形成的空间结构,即分形结构,同时也反映了不同形态要素对系统所起作用的差异,分维越小,所起作用越显著。其结果对西北干旱半干旱地区石流灾害的进一步研究与防治提供了新的思路。     

Towards models of strategic spatial choice behaviour: theory and application issues

Models of spatial choice behaviour have been around in geography urban planning for decades to assess the feasibility of planning actions or to predict external (competition) effects on existing destinations. Although these models differ in terms of complexity and key concepts, they all have in common that spatial choice behaviour is predicted as a function of the attributes of the choice alternatives and distance or travel time separation only. None of these models do take into account that the attributes of choice alternatives and travel time may be highly non-stationary and that often the utility that people derive from visiting a particular location also depends on the choice behaviour of other individuals. Under these circumstances, individuals may exhibit strategic choice behaviour. That is, they will choose particular choice options taking into account their expected behaviour of others such as to maximize their own utility. The purpose of the proposed paper is to discuss possible models of strategic choice behaviour for these urban planning problems. Theory will be outlined and some critical issues in the application of such models to problems of spatial choice will be discussed.     

青海气候条件对牧草再生性影响的研究

选取1994～2001年河南、甘德两站牧草再生草资料及同期气象资料，通过分析同一地区不同时期及同一时期不同地区气候条件对牧草再生性的影响，建立了牧草再生草产量气候模式，讨论了再生草增、减产的气候条件。研究得出：同一地区不同时期和同一时期不同地区因气候条件不同，割草不一定能增产。     

云南省冰雹的时空分布特征

利用近40年的云南省冰雹资料，统计分析了云南省冰雹的时空分布特征，进一步揭示了其活动规律及主要影响因素。研究结果表明：冰雹的季节分布比较复杂，呈现出春季和夏季两个峰值的特点；冰雹的季节分布还与海拔高度有关，低海拔地区为春季多雹型，高海拔地区为夏季多雹型；滇西地区冰雹日数的年际变化特征较滇东地区显著而年代际变化特征没有东部地区站点明显；滇东地区表现出了明显的年代际变化特征，目前处于冰雹相对较少时期。从区域来看，年冰雹日数山区较坝区高，高海拔地区较低海拔地区高。