石榴石辉石岩的单斜辉石中韭闪石和钛铁矿出溶结构及地质意义

本文首次报道了在苏鲁超高压变质带胡家岭地区石榴石辉石岩中发现的韭闪石出溶结构。该石榴石辉石岩是由石榴子石、单斜辉石以及镁铝尖晶石、钛铁矿和磁铁矿组成。在石榴子石巨斑晶中有单斜辉石包体，单斜辉石包体中又有石榴子石包体以及大量韭闪石出溶片晶和钛铁矿( 磁铁矿)出溶棒。单斜辉石中韭闪石出溶片晶呈平行条带状，其宽度在1～10μm之间。透射电子显微镜(TEM)观察韭闪石的(010)面平行于主晶透辉石的(010)面，且两者的界面在纳米尺度上是连续过渡的，证明韭闪石是出溶形成的。大量钛铁矿出溶棒的定向排列也显示出它们是自然出溶形成的。从单斜辉石出溶的矿物组合推测其原始单斜辉石成分中应富含H2O、Na和Ti，属高压型单斜辉石。该石榴石辉石岩经历了超高压变质作用后，在抬升减压过程中形成这些出溶结构。大量钛铁矿出溶棒均斜切韭闪石出溶片晶，表明该超高压岩石在减压过程中至少经历了两期以上导致温压明显变化的地质事件。     

MODEL STUDY OF THE EFFECT OF SOIL NO EMISSIONS ON SURFACE OZONE

The effect of soil NO emissions on surface ozone in autumn in East China has been studied byusing TCTM(Troposphere Chemical Transport Model)with the input of meteorological variablesfrom RAMS.The chemical mechanism for ozone variation caused by soil emissions has also beeninvestigated.The model results reveal that soil NO emissions are important to regional ozoneformation and distribution and the effect of soil NO emissions shows spatial inhomogeneity.Ozoneover most areas in northern China decreases with maximum average decrement reaching 5 ppbwhile it increases over most areas of central and southern China with maximum average incrementreaching 7 ppb caused by soil NO emissions.This situation of ozone variation is mainly determinedby nonlinear photochemical mechanism.For the low NOx areas(≤3 ppb),ozone increases as NOxincreases;for the high NOx areas(>3 ppb),ozone decreases as NOx increases.The effect of soilNO emissions on ozone depends on the transition value and NOx concentrations.     

冀西北石榴角闪二辉麻粒岩早期高压变质矿物组合的确定及其形成的温压条件——来自锆石中矿物包裹体的信息

采用激光拉曼、阴极发光和电子探针技术,确认冀西北石榴角闪二辉麻粒岩锆石中保存早期高压变质包体矿物组合:石榴石(Grt)+单斜辉石(Cpx)+斜长石(Pl)+石英(Qtz)+金红石(Rt)、单斜辉石(Cpx)+斜长石(Pl)+石英(Qtz)和石榴石(Grt)+单斜辉石(Cpx)+斜长石(Pl)+石英(Qtz)。其中少量锆石具有继承性锆石的核,而多数锆石则形成于高压麻粒岩相变质阶段。利用TWQ方法限定石榴角闪二辉麻粒岩锆石中所保存的高压包体矿物组合的变质温度条件为750～820℃,压力为1.07～1.40 GPa。该项研究成果对于如何识别高压麻粒岩以及深入研究其成因机制均具有重要的科学意义。     

北极斯瓦尔巴德地区近地层大气观测研究 I.平均场特征

利用“中国科学探险协会2002年北极科学探险考察”期间, 在斯瓦尔巴德地区政府所在地朗伊尔宾城架设的两个自动气象站记录的气象资料, 分析了该地区气象要素平均值的日变化, 给出了这一极端环境区夏季近地层气象要素的基本物理图像: 太阳辐射、大气温度、地表温度和大气湿度等气象要素的日变化都呈单峰分布; 地气温差因地而异, 不同下垫面类型大气能量的源汇不同; 局地环流多种多样, 冰川风、海陆风、山谷风相互叠加, 主导风向各地不一。     

Interdecadal Variations of Phase Delays Between Two Nino Indices at Different Time Scales

Phase delays between two Nino indices-sea surface temperatures in Nino regions 1 2 and 3.4 (1950-2001)-at different time scales are detected by wavelet analysis. Analysis results show that there are two types of period bifurcations in the Nifio indices and that period bifurcation points exist only in the region where the wavelet power is small. Interdecadal variation features of phase delays between the two indices vary with different time scales. In the periods of 40-72 months, the phase delay changes its sign in 1977: Nino 1 2 indices are 2-4 months earlier than Nino 3.4 indices before 1977, but 3-6 months later afterwards. In the periods of 20-40 months, however, the phase delay changes its sign in another way:Nino 1 2 indices are 1-4 months earlier before 1980 and during 1986-90, but 1-4 months later during 1980-83 and 1993-2001.     

四川三台膨润土的基本物化性能及其对铅、钴的吸附性研究

对四川三台钙基膨润土的基本物化性能和对Pb^2 ，Co^2 离子的吸附性能作了初步的研究。基本物化性能主要包括化学成分、阳离子交换容量、密度、比表面积、孔径、渗透系数及热稳定性。通过实验得出：1)经过钠化改型并酸化处理后的膨润土的阳离子交换容量(CEC)明显高于未经处理的原土；2)膨润土的最佳酸活化条件为在96℃左右以15％的硫酸活化4小时的性能最佳；3)膨润土土的密度为2．11g／cm^3，颗粒密度钠化土为1．996g／cm^3，原土为2．079g／cm^3；渗透系数为0．013cm／s(20C)；体积平均粒径为30．950μm；比表面积为329．7482m^2／g，平均孔径为33．238nm；4)膨润土对对重金属离子的吸附实验，得出膨润土对重金属离子Pb^2 的吸附性能优于Co^2 ，Pb^2 和Co^2 的吸附比(Rd)分别为167．8ml／g及53．3ml／g；Pb^2 和Co^2 去除率(r)分别为45．87%和21．20％。     

Ion Probe Study of Silicate Inclusions from Colomera (ⅡE) Iron Meteorite: the Rare Earth Element Perspective

Coupled with a petrographical study, I carried out an ion probe study of rare earth element microdistributions in mineral phases of silicate inclusions from the Colomera ⅡE iron meteorite. Most mineral grains have homogeneous REEs, but show considerable inter-grain variations by a factor of 2 to 100. The whole rock REE abundances for Colomera, estimated by combining REE data with modal abundances, are relatively LREE-enriched with REEs of -10'CI, which suggest that Colomera silicates were highly differentiated and might represent a low degree partial melt (-10%) of a chondritic source. REE geochemistry of Colomera silicate inclusions points to an origin that involves differentiation, dynamic mixing, remelting, reduction, recrystallization, and subsequent rapid cooling near the surface of a planetary body.     

LONG VALID TIME ENERGY PERFECT CONSERVATIVE FIDELITY SPECTRAL SCHEMES OF BAROTROPIC PRIMITIVE EQUATIONS

In accordance with a new compensation principle of discrete computations,the traditional meteo-rological global (pseudo-) spectral schemes of barotropic primitive equation (s) are transformed intoperfect energy conservative fidelity schemes,thus resolving the problems of both nonlinear computa-tional instability and incomplete energy conservation,and raising the computational efficiency of thetraditional schemes.As the numerical tests of the new schemes demonstrate,in solving the problem of energy conser-vation in operational computations,the new schemes can eliminate the (nonlinear) computational in-stability and,to some extent even the (nonlinear) computational diverging as found in the traditionalschemes,Further contrasts between new and traditional schemes also indicate that,in discrete opera-tional computations,the new scheme in the case of nondivergence is capable of prolonging the valid in-tegral time of the corresponding traditional scheme,and eliminating certain kind of systematical com-putational“climate drift”,meanwhile increasing its computational accuracy and reducing its amount ofcomputation.The working principle of this paper is also applicable to the problem concerning baroclin-ic primitive equations.     

IMPROVEMENT OF A GLOBAL SPECTRAL MODEL BY INTRODUCING THE SECONDLAW OF THERMODYNAMICS

The second law of thermodynamics has never been taken into account in the traditional hydrodynamics and numer-ical weather prediction models,which is a serious oversight in the history of mechanics.Introducing the thermodynamicirreversibility into the hydrodynamic systems,the theory and method proposed in this study would not only lead theoutputs of a numerical weather prediction model to noticeable improvement,but lead the structure of hydrodynamics todeepgoing transformation.     

On the Nonlinear Response of Lower Stratospheric Ozone to NO_x and ClO_x Perturbations for Different CH_4 Sources

The impact of sulfate aerosol, ClO2 and NOx perturbations for two different magnitudes of CH4 sources on lower stratospheric ozone is studied by using a heterogeneous chemical system that consists of 19 species belonging to 5 chemical families (oxygen, hydrogen, nitrogen, chlorine and carbon). The results show that the present modeled photochemical system can present several different solutions, for instance, periodic states and multi-equilibrium states appearing in turn under certain parameter domains, through chlorine chemistry and nitrogen chemistry together with sulfate aerosol as well as the increasing magnitude of CH4 sources. The existence of catastrophic transitions could produce a dramatic reduction in the ozone concentration with the increase of external sources.