Provenance, diagenesis, tectonic setting and geochemistry of Tawil Sandstone (Lower Devonian) in Central Saudi Arabia

The Tawil Sandstone (Lower Devonian) in Central Saudi Arabia overlies the Sharwara Member of the Tayyarat Formation (Silurian) and succeeded conformly by the Shaiba Member of the Jauf Formation. Petrographical data reveal that the Tawil Sandstone comprises 96% quartz, 3% feldspar, and 1% rock fragments and all samples are classified as quartz arenites. The presence of well sorted, altered to fresh feldspar, and discriminate function analysis suggests that the sediments have been subjected to substartial reworking resulting in a high level of maturity. Modal analysis data (Q–F–L) suggest a stable cratonic provenance for the sediments and accumulation in a passive margin basin is indicated (binary plot of SiO₂ vs K₂O/Na₂O). Diagenetic features include dissolution of feldspar and rock fragments, compaction, reduction of the existing pore space through rearrangements, and rotation and fragmentation of grains resulting in dissolution of quartz grains and cementation.     

Quantifying deformation in North Borneo with GPS

The existence of intra-plate deformation of the Sundaland platelet along its eastern edge in North Borneo, South-East Asia, makes it an interesting area that still is relatively understudied. In addition, the motion of the coastal area of North-West Borneo is directed toward a frontal fold-and-thrust belt and has been fueling a long debate on the possible geophysical sources behind it. At present this fold-and-thrust belt is not generating significant seismic activity and may also not be entirely active due to a decreasing shelfal extension from south to north. Two sets of Global Positioning System (GPS) data have been used in this study; the first covering a time period from 1999 until 2004 (ending just before the Giant Sumatra–Andaman earthquake) to determine the continuous Sundaland tectonic plate motion, and the second from 2009 until 2011 to investigate the current deformations of North Borneo. Both absolute and relative positioning methods were carried out to investigate horizontal and vertical displacements. Analysis of the GPS results indicates a clear trend of extension along coastal regions of Sarawak and Brunei in North Borneo. On the contrary strain rate tensors in Sabah reveal that only insignificant and inconsistent extension and compression occurs throughout North-West Borneo. Moreover, station velocities and rotation rate tensors on the northern part of North Borneo suggest a clockwise (micro-block) rotation. The first analysis of vertical displacements recorded by GPS in North-West Borneo points to low subsidence rates along the western coastal regions of Sabah and inconsistent trends between the Crocker and Trusmadi mountain ranges. These results have not been able to either confirm or reject the hypothesis that gravity sliding is the main driving force behind the local motions in North Borneo. The ongoing Sundaland–Philippine Sea plate convergence may also still play an active role in the present-day deformation (crustal shortening) in North Borneo and the possible clockwise rotation of the northern part of North Borneo as a micro-block. However, more observations need to be collected to determine if the northern part of North Borneo indeed is (slowly) moving independently.     

Characterization of carbon monoxide,methane and nonmethane hydrocarbons in emerging cities of Saudi Arabia and Pakistan and in Singapore

We investigate the composition of 63 C₂-C₁₀ nonmethane hydrocarbons (NMHCs), methane (CH₄) and carbon monoxide (CO), in Jeddah, Mecca, and Madina (Saudi Arabia), in Lahore, (Pakistan), and in Singapore. We established a database with which to compare and contrast NMHCs in regions where ambient levels and emissions are poorly characterized, but where conditions are favorable to the formation of tropospheric ozone, and where measurements are essential for improving emission inventories and modeling. This dataset will also serve as a base for further analysis of air pollution in Western Saudi Arabia including, but not limited to, the estimation of urban emissions and long range pollution transport from these regions. The measured species showed enhanced levels in all Saudi Arabian cities compared to the local background but were generally much lower than in Lahore. In Madina, vehicle exhaust was the dominant NMHC source, as indicated by enhanced levels of combustion products and by the good correlation between NMHCs and CO, while in Jeddah and Mecca a combination of sources needs to be considered. Very high NMHC levels were measured in Lahore, and elevated levels of CH₄ in Lahore were attributed to natural gas. When we compared our results with 2010 emissions from the MACCity global inventory, we found discrepancies in the relative contribution of NMHCs between the measurements and the inventory. In all cities, alkenes (especially ethene and propene) dominated the hydroxyl radical (OH) reactivity (k _OH) because of their great abundance and their relatively fast reaction rates with OH.     

Anatexis and fluid regime of the deep continental crust: New clues from melt and fluid inclusions in metapelitic migmatites from Ivrea Zone (NW Italy)

We investigate the inclusions hosted in peritectic garnet from metapelitic migmatites of the Kinzigite Formation (Ivrea Zone, NW Italy) to evaluate the starting composition of the anatectic melt and fluid regime during anatexis throughout the upper amphibolite facies, transition, and granulite facies zones. Inclusions have negative crystal shapes, sizes from 2 to 10 μm and are regularly distributed in the core of the garnet. Microstructural and micro‐Raman investigations indicate the presence of two types of inclusions: crystallized silicate melt inclusions (i.e., nanogranitoids, NI), and fluid inclusions (FI). Microstructural evidence suggests that FI and NI coexist in the same cluster and are primary (i.e., were trapped simultaneously during garnet growth). FI have similar compositions in the three zones and comprise variable proportions of CO₂, CH₄, and N₂, commonly with siderite, pyrophyllite, and kaolinite, suggesting a COHN composition of the trapped fluid. The mineral assemblage in the NI contains K‐feldspar, plagioclase, quartz, biotite, muscovite, chlorite, graphite and, rarely, calcite. Polymorphs such as kumdykolite, cristobalite, tridymite, and less commonly kokchetavite, were also found. Rehomogenized NI from the different zones show that all the melts are leucogranitic but have slightly different compositions. In samples from the upper amphibolite facies, melts are less mafic (FeO + MgO = 2.0–3.4 wt%), contain 860–1700 ppm CO₂ and reach the highest H₂O contents (6.5–10 wt%). In the transition zone melts have intermediate H₂O (4.8–8.5 wt%), CO₂ (457–1534 ppm) and maficity (FeO + MgO = 2.3–3.9 wt%). In contrast, melts at granulite facies reach highest CaO, FeO + MgO (3.2–4.7 wt%), and CO₂ (up to 2,400 ppm), with H₂O contents comparable (5.4–8.3 wt%) to the other two zones. Our results represent the first clear evidence for carbonic fluid‐present melting in the Ivrea Zone. Anatexis of metapelites occurred through muscovite and biotite breakdown melting in the presence of a COH fluid, in a situation of fluid–melt immiscibility. The fluid is assumed to have been internally derived, produced initially by devolatilization of hydrous silicates in the graphitic protolith, then as a result of oxidation of carbon by consumption of Fe³⁺‐bearing biotite during melting. Variations in the compositions of the melts are interpreted to result from higher T of melting. The H₂O contents of the melts throughout the three zones are higher than usually assumed for initial H₂O contents of anatectic melts. The CO₂ contents are highest at granulite facies, and show that carbon‐contents of crustal magmas are not negligible at high T. The activity of H₂O of the fluid dissolved in granitic melts decreases with increasing metamorphic grade. Carbonic fluid‐present melting of the deep continental crust represents, together with hydrate‐breakdown melting reactions, an important process in the origin of crustal anatectic granitoids.     

The Tully-Fisher relations of the Eridanus group of galaxies

The Tully-Fisher (TF) or the luminosity-linewidth relations of the galaxies in the Eridanus group are constructed using the HI rotation curves and the luminosities in the optical and in the near-infrared bands. The slopes of the TF relations (absolute magnitudevs log2V _flat) are −8.6 ± 1.1, −10.0 ±1.5, −10.7 ±2.1, and −9.7 ±1.3 in the R, J, H, and K bands respectively for galaxies having flat HI rotation curves. These values of the slopes are consistent with those obtained from studies of other groups and clusters. The scatter in the TF relations is in the range 0.5-1.1 mag in different bands. This scatter is considerably larger compared to those observed in other groups and clusters. It is suggested that the larger scatter in the TF relations for the Eridanus group is related to the loose structure of the group. If the TF relations are constructed using the baryonic mass (stellar +HI + Helium mass) instead of the stellar luminosity, nearly identical slopes are obtained in the R and in the near-infrared bands. The baryonic TF (baryonic massvs log2V _flat) slope is in the range 3.5–4.1.     

Radio continuum and far-infrared emission from the galaxies in the Eridanus group

The Eridanus galaxies follow the well-known radio—FIR correlation. The majority (70%) of these galaxies have their star formation rates below that of the Milky Way. The galaxies that have a significant excess of radio emission are identified as low luminosity AGNs based on their radio morphologies obtained from the GMRT observations. There are no powerful AGNs (L _20cm > 10²³ W Hz⁻¹) in the group. The two most far-infrared and radio luminous galaxies in the group have optical and HI morphologies suggestive of recent tidal interactions. The Eridanus group also has two far-infrared luminous but radio-deficient galaxies. It is believed that these galaxies are observed within a few Myr of the onset of an intense star formation episode after being quiescent for at least a 100 Myr. The upper end of the radio luminosity distribution of the Eridanus galaxies (L _20cm ∼ 10²² W Hz⁻¹) is consistent with that of the field galaxies, other groups, and late-type galaxies in nearby clusters.     

Air pollution hazard assessment using decision tree algorithms and bivariate probability cluster polar function: evaluating inter-correlation clusters of PM10 and other air pollutants

ABSTRACT

The automated classification of ambient air pollutants is an important task in air pollution hazard assessment and life quality research. In the current study, machine learning (ML) algorithms are used to identify the inter-correlation between dominant air pollution index (API) for PM10 percentile values and other major air pollutants in order to detect the vital pollutants’ clusters in ambient monitoring data around the study area. Two air quality stations, CA0016 and CA0054, were selected for this research due to their strategic locations. Non-linear RPart and Tree model of Decision Tree (DT) algorithm within the R programming environment were adopted for classification analysis. The pollutants’ respective significance to PM10 occurrence was evaluated using Random forest (RF) of DT algorithms and K means polar cluster function identified and grouped similar features, and also detected vital clusters in ambient monitoring data around the industrial areas. Results show increase in the number of clusters did not significantly alter results. PM10 generally shows a reduction in trend, especially in SW direction and an overall minimal reduction in the pollutants’ concentration in all directions is observed (less than 1). Fluctuations were observed in the behaviors of CO and NO_x during the day while NOx displayed relative stability. Results also show that a direct and positive linear relationship exists between the PM10 (target pollutant) and CO, SO₂, which suggests that these pollutants originate from the same sources. A semi-linear relationship is observed between the PM10 and others (O₃ and NO_x) while humidity shows a negative linearity with PM10. We conclude that most of the major pollutants show a positive trend toward the industrial areas in both stations while tra?c emissions dominate this site (CA0016) for CO and NOx. Potential applications of nuggets of information derived from these results in reducing air pollution and ensuring sustainability within the city are also discussed. Results from this study are expected to provide valuable information to decision makers to implement viable strategies capable of mitigating air pollution effects.