南海卡氏豆荚软珊瑚化学成分研究Ⅱ

运用光谱分析和GC－MS方法首次从卡氏豆荚软珊瑚Lobophytumcatelai中分离和鉴定出8个化合物：l，十六碳酸；2,异丁基十六碳酸酯；3，鲨肝醇；4十六酸丙酯；5，2，3一二羟基丙基十八酸酯；6，2β，3β-环氧基-5α-雄甾烷-17-醇；7，14-甲基-5α-胆甾-8-稀-3-酮；8，2α，3α一环氧基-5α-雄甾烷-17-醇。     

基于GIS的县域土壤重金属生态风险评价

为研究经济快速发展区农田土壤中重金属的含量及污染状况,本文以浙江省慈溪市为研究对象,研究土壤中铜、汞、镉、铅、砷、铬、锌七种重金属含量特征,并采用潜在生态危害指数法对其进行评价,并绘制生态风险危害指数分级图。结果表明:土壤中除汞元素含量较高外,其他各元素含量仅稍高于当地土壤背景值。七种元素的单因子污染指数Cfi值均属于中等的污染参数,综合污染指数Cd上限值已处于高污染指数的范围,但平均值为属于中等污染水平。从潜在生态风险评价结果来看,七种元素的单项潜在生态风险参数Eri的值也只有汞达到了强生态危害,七种元素综合潜在生态危害指数RI刚刚达到中等生态危害水平,说明该区农田土壤尚处于较低的生态风险状态。生态危害指数插值结果表明,慈溪市重金属元素的高风险区分布在中南部人类活动较为活跃、城乡工业较发达的区域,在今后的土地利用中,应高度重视人类活动对土壤重金属污染的影响。     

IODP 311航次底栖有孔虫碳稳定同位素对天然气水合物地质系统的指示

为了探索海洋天然气水合物背景下有孔虫特征的响应,对综合大洋钻探计划(IODP) 311航次岩芯沉积物中底栖有孔虫Uvigerina peregrina和Bulimina mexicana进行了初步研究。通过对冷泉站位U1328和毗邻的非冷泉站位U1327沉积物中底栖有孔虫Uvigerina peregrina和Bulimina mexicana的显微形貌特征和碳、氧稳定同位素测试等,证实有孔虫壳体未受到后期成岩作用的改造和自生碳酸盐岩的交代影响,有孔虫壳体的碳稳定同位素呈现明显的负偏。其中U1327站位中U.peregrina δ¹³C为-0.67‰～-2.75‰（PDB）,B.mexicana δ¹³C为-0.51‰～-1.52‰（PDB）;U1328站位中U.peregrina δ¹³C为 -0.72‰～-2.71‰（PDB）,B.mexicanaδ¹³C为 -0.58‰～-1.45‰（PDB）。底栖有孔虫壳体的碳稳定同位素负偏成因可能与水合物不稳定分解释放的甲烷厌氧氧化作用和食物源有关,因而可较好地指示海底天然气水合物系统地质背景。     

矿集区预测中的探索式空间分析方法及应用——以中亚铜矿集区预测为例

随着地理信息科学和计算机技术的发展,计算环境下矿集区预测方法的研究热潮也初现端倪.依据矿集区所包含的理论内涵(矿床密集区、潜力密集区的聚集内涵),提出了应用探索式空间分析法进行矿集区预测的设想,并以北至科克舍套,南至帕米尔高原,西至乌拉尔山,东至新疆边境的中亚区域为研究区,利用探索式空间分析方法从含矿潜力的确定及其空间分布模式的探索入手,对研究区铜矿集区进行了预测,初步圈定了乌拉尔、矿区阿尔泰、北滨巴尔喀什、斋桑、塔尔巴合台等17处铜矿集区.研究成果除包含了研究区已知矿集区外,还有7处新区,反映了探索式空间分析法在矿集区预测中的应用潜力.     

黄河内蒙古段上覆水、悬浮物和底泥重金属特征及生态风险研究

系统地采集黄河内蒙古段上覆水、悬浮物和底泥样品,分析其中重金属元素的含量。采用地质累积指数法和潜在生态危害系数法,研究了黄河干流内蒙古段的上覆水、悬浮物和底泥的重金属沿程分布特征、污染程度和生态风险。分析结果显示:除了As元素,悬浮物中重金属元素含量总体上高于底泥中的含量。地质累积指数法评价结果表明:悬浮物和底泥属于无污染—中度污染,悬浮物总体上比底泥污染严重;潜在生态危害系数法评价结果表明:底泥和悬浮物中重金属的生态危害总体上属轻微状态;因此,生态风险指数法和地质累积指数评价结果基本一致。     

Chronology and cooling history of the Tianmenshan pluton in South Jiangxi Province and their geological significance

Geochronological studies on the crust-derived Tianmenshan pluton were undertaken by SHRIMP zircon U-Pb dating and Ar-Ar dating of biotite, muscovite and K-feldspar, giving a petrogenetic age of 167 Ma. Owing to the closure systems in different minerals, the cooling history of the pluton can be determined with an age-temperature diagram. The late hydrothermal event has been recognized, which is related probably with mineralization. In terms of the comparative geochronological and petrologic records, it is concluded that there are some constrains on tectonic evolution and that the formation of the Tianmenshan pluton proceeded in a transition period from Indosinian post-orogeny extension to strong compressive tectonics. And the timing of the hydrothermal event matches the compressive climax of the Yanshanian orogeny. The temporal gap between granite emplacement and wolframite mineralization could last 10-20 Ma owing to the low cooling rate of the pluton.     

Formation Dynamics and Quantitative Prediction of Hydrocarbons of the Superpressure System in the Dongying Sag

Based on the theory of formation dynamics of oil/gas pools, the Dongying sag can be divided into three dynamic systems regarding the accumulation of oil and gas： the superpressure closed system, the semi-closed system and the normal pressure open system. Based on the analysis of genesis of superpressure in the superpressure closed system and the rule of hydrocarbon expulsion, it is found that hydrocarbon generation is related to superpressure, which is the main driving factor of hydrocarbon migration. Micro fractures formed by superpressure are the main channels for hydrocarbon migration. There are three dynamic patterns for hydrocarbon expulsion： free water drainage, hydrocarbon accumulation and drainage through micro fissures. In the superpressure closed system, the oil-driving-water process and oil/gas accumulation were completed in lithologic traps by way of such two dynamic patterns as episodic evolution of superpressure systems and episodic pressure release of faults. The oil-bearing capacity of lithologic traps is intimately related to reservoir-forming dynamic force. Quantitative evaluation of dynamic conditions for pool formation can effectively predict the oil-bearing capability of traps.     

RBF网络在地质样品非线性基体效应校正中的应用

基于RBF(Radial Basis Function)网络的正交最小平方算法,对攀枝花地质样品进行动态非线性基体效应校正.首先采用EDXRF仪器对样品进行测量,并对样品的荧光计数进行归一化,设计出自动分类模型和动态非线性数据基体效应校正模型的二级串联结构,用自组织神经网络(SOFM)进行分类,然后用RBF网络预测了未知样品元素Ti的百分含量.结果表明:对所预测样本的Ti的百分含量与化学分析相比的误差均小于0.5%.由此可见,用RBF方法可以有效地对地质样品进行非线性基体效应校正,能够达到工矿生产的要求.     

安徽池州铜山铜矿深部找矿实践与启示

铜山铜矿资源储量日益枯竭。危机矿山接替资源勘查中,采用地质、物探综合手段圈定异常区,经深部钻探验证,取得突破。     

郯庐断裂带张八岭隆起北段的左旋走滑挤压变形及其~(40)Ar/~(39)Ar定年

郯庐断裂带张八岭隆起北段,自西向东分别出露北北东向的韧性滑脱变形带、脆-韧性过渡带和脆性的前陆褶断带。韧性滑脱变形带内的张八岭群片岩,广泛发生了低绿片相背景下的糜棱岩化。其中呈现为平缓的糜棱面理和近南北向的矿物拉伸线理。显微构造及石英C轴组构分析显示,该韧性滑脱带一致为上盘向南的运动。该带以东依次变为上盘向南南东→南东的逆冲活动,总体上为左旋走滑挤压变形带。张八岭群所在的韧性变形带为深部陡立走滑构造与浅部脆性构造之间的滑脱变形带,其间的差异走滑变形,造成了该滑脱层在总体向北运动中出现上盘向南的剪切变形。对6处张八岭群片岩中15个不同粒级白云母的40Ar/39Ar定年指示,变形发生在(236.2±0.5)~(238.0±0.4)Ma的中三叠世晚期。这表明郯庐断裂带的左行平移发生在华北与华南板块碰撞的深俯冲阶段,起源于陆内转换断层。