Quantifying hydrogen‐deuterium exchange of meteoritic dicarboxylic acids during aqueous extraction

Abstract— Hydrogen isotope ratios of organic compounds in carbonaceous chondrites provide critical information about their origins and evolutionary history. However, because many of these compounds are obtained by aqueous extraction, the degree of hydrogen‐deuterium (H/D) exchange that occurs during the process needs to be quantitatively evaluated. This study uses compound‐specific hydrogen isotopic analysis to quantify the H/D exchange during aqueous extraction. Three common meteoritic dicarboxylic acids (succinic, glutaric, and 2‐methyl glutaric acids) were refluxed under conditions simulating the extraction process. Changes in δD values of the dicarboxylic acids were measured following the reflux experiments. A pseudo‐first order rate law was used to model the H/D exchange rates which were then used to calculate the isotope exchange resulting from aqueous extraction. The degree of H/D exchange varies as a result of differences in molecular structure, the alkalinity of the extraction solution and presence/absence of meteorite powder. However, our model indicates that succinic, glutaric, and 2‐methyl glutaric acids with a δD of 1800%***_o would experience isotope changes of 38_o, 10_o, and 6_o, respectively during the extraction process. Therefore, the overall change in δD values of the dicarboxylic acids during the aqueous extraction process is negligible. We also demonstrate that H/D exchange occurs on the chiral α‐carbon in 2‐methyl glutaric acid. The results suggest that the racemic mixture of 2‐methyl glutaric acid in the Tagish Lake meteorite could result from post‐synthesis aqueous alteration. The approach employed in this study can also be used to quantify H/D exchange for other important meteoritic compounds such as amino acids.     

板翅式换热器综合性能优化的设计方法

应用给定换热器结构材料而使换热量最大的两侧换热表面的最佳匹配准则和使可用能损失率最小的最佳运行参数准则。利用两个准则间的关系 ,采用迭代的方式完成换热器的优化设计 ,使换热器的设计达到材料省、换热效果好及运行费用低的目的 ,且能在设计阶段实现。     

电离氢区S140,S141和S142的红外发射研究

本文使用红外天文卫星（IRAS）巡天数据的最新版本IRAS天空巡天图（ISSA），经过进一步处理，得到了S140S141和S142SharplessHII区－分子云复合体的红外发射强度、温度及其光深的分布．在此基础上对各HII区的一些物理参量进行了统计分析，得到了分子云复合体的红外发射总光度以及复合体中尘埃的分布情况，对小尺度尘埃（VSG）的丰度进行了分析．并对各恒星形成区中的致密团块进行了研究，揭示出其中一些可能的恒星形成区域．同时，对S140区中的有关红外点源作出了能谱分析，并对S141区的激发星进行了讨论．     

EMERGY ANALYSIS OF GRAIN PRODUCTION SYSTEM IN JIANGSU AND SHAANXI PROVINCE

1INTRODUCTIONGrain production has always been top-priority issue con-cerned by government and people (MA etal., 2002). Af-ter China put household contract responsibility system in force, its domestic issue of grain was basically settled in the mid 1980s (MA and XU, 1999). However, in the days when idea of sustainable development is broadly accepted, efficiency and sustainability of grain produc-tion are now in question, which have prompted interest in reviewing grain production patterns…     

The Latest Research Progress on El Nino

Cold water in the deep Pacific can be drawn up to the surface (or west warm water drifts eastwards ) because strong tide increases the mixing of seawater both in vertical and horizontal. In this way greenhouse effect is decreased or increased by means of absorbing (or releasing) CO2. Therefore, La Nina cold event (or El Nino warm event) may occur,which is caused by wanning - up or cooling - down air above the ocean. Volcanic action at sea bottom is also controlled by strong tide.     

贵州织金煤矿区龙潭组岩石特征及其意义

织金矿区含煤地层为上二叠统龙潭组,含主要可采煤6层.煤系地层以含玄武岩屑、海绿石为特征的5类碎屑岩夹碳酸盐岩,水平、沙纹、波状层理发育,煤系中稳定的灰岩、硅铁质灰岩标志层较多,有利于煤层的划分与对比,并产丰富的动植物化石及碎块.属海、陆交替环境下的标型海陆交互相沉积.     

推算海洋大地水准面

大地水准面是地球重力等势面,它反映地球形状及海面重力场异常特征,对大地测量学及海底探矿意义重大,利用Geosat高度计50个ERM周期共2.3a的数据,对包括东海区域的20°～40°N,120°～140°     

广西森林旅游资源的特色及其开发意义

广西森林旅游资源多达 816 .7万hm2 ,景点 2 80个 ,内容丰富 ,前景广阔 ,加强广西森林旅游资源特色的开发 ,有利于促进广西旅游业可持续发展 ,有利于经济、社会、环境效益的提高及人们的文化素质和生活质量的提高。     

基于可靠度理论的黄土高边坡优化设计

对黄土高边坡进行可靠性分析，应用数学原理和优化原理，建立了黄土高边坡的优化模型，对铜黄一级公路黄土高边坡进行分析验证。结果表明，该方法计算的结果与实际较接近．应用中易操作。     

一种基于Ohta-Okamoto签名的门限群签名方案

在修改的Ohta_Okamoto数字签名方案基础上,设计出了一个新的(t,n)门限签名方案。该方案具有可验证性和防止内部成员合谋攻击;而且验证者在验证群签名的有效性计算的复杂性与一般个人签名方案一样。该方案的安全性是基于大整数的因式分解,因此在计算上是安全的。