Structural Evolvement of Heating Treatment of Mg/Al-LDH and Preparation of Mineral Mesoporous Materials

Although hydrotalcite, or layered double hydroxides (LDHs), is not a common mineral, it is an important material that can be easily synthesized in laboratory. In this study, structural evolvement and BET surface area changes of heat treated Mg/Al-LDH is evaluated by XRD, TEM and N2-BET analyses. The results indicate that the magnesium-aluminum LDH with carbonate as interlayer anion, periclase-like oxides was formed at temperatures of 400-800℃. Meanwhile, 2-3 nanometer mesoporous were formed during decomposition of LDH. However, the heat treated samples still preserve the morphology of the original LDH plates. Periclase-like formed from LDH heat treatment may re-hydrolyze and recover the structure of LDH. However, crystallinity of the recovered LDH is lower than that of the original LDH. This heat treatment will result in formation of (Mg, Al)-oxide nano-crystals and nanopores among the nano-crystals. When heating temperature exceeds 1000, the periclase-like (Mg, Al)-oxide is transformed into a composite with periclase (MgO) and spinel phases. The periclase can be re-hydrolyzed and dissolved in HCl solution. After acid treatment, the sample with a high surface area is composed of spinel nano-crystals and nanopores among them. Our results will provide a new and economic way to synthesize mesoporous materials through pathways of phase transformation of precursor materials with different composition.     

Hydrogen Isotopic Compositions of Pyroxenes in Nushan Peridotite Xenoliths,SE China

Hydrogen isotopic compositions of pyroxenes in peridotite xenohths from the Nushan volcano, Anhui Province, SE China have been obtained using an ion probe (Cameca 1270). D/H ratios are constant within a single grain and among the different grains from the same sample. The lack of correlation between the D/H ratios and the hydrogen contents indicates that the hydrogen isotopic compositions are inherited from their mantle source. Combining with the δD values of coexisting amphiboles, it is inferred that the Nushan mantle experienced at least a two-stage metasomatic event.One was responsible for formation of amphiboles with extremely variable δD values, and the other was probably responsible for the high δD values (up to -20‰) of some clinopyroxenes from peridotites, clinopyroxene and mica megacrysts. High δD values point to a subduction-related fluid being involved in one metasomatic event. The primary δD values (-90‰ to -140‰) of the Nushan pyroxenes, together with data gleaned from the literature, suggest that the D/H ratios of the nominally anhydrous mineral reservoir might have differed from that of the other mantle hydrogen in being relatively depleted in D.     

安徽省人工影响天气信息管理与作业指挥系统设计与开发

为了提高人工影响天气信息管理和作业指挥能力,设计开发了针对省级人工影响天气信息管理与作业指挥的业务系统。系统应用数据库和网络技术,设计开发了人工影响大气信息数据库,并采用角色和极限双重管理模式,对人工影响天气信息数据库进行管理。系统针对安徽实际设计了合理的地面作业指挥流程,开发了地面作业指挥平台,提供了省级人工影响天气指导产品,并对作业流程中关键环节进行技术控制,为安徽全省人工影响天气地面作业安全提供了保障平台,在实际业务中发挥了重要的作用。     

镇扬大桥桥基区优势断裂显微构造特征及分段研究

基于SEM和矿物组分分析研究了镇扬大桥桥基优势断裂断层泥的显微结构、显微构造和物质组成等特征 ,并进一步应用优势面理论进行分段研究 ,取得了较好的效果 ,其对大桥桥基断裂活动性和稳定性的评价具有重要意义 ,为建在断裂带上的特大型大桥工程的选址、设计以及确保安全运行提供了地质依据     

安徽嘉山坡缕石加热相变的研究

研究样品产于安徽嘉山县的第三系沉积型粘土矿层。样品经分离提纯后分别加热,对不同温度的样品进行X射线衍射和红外光谱分析,结合坡缕石的热分析资料的综合研究,证明坡缕石的热相变过程为:200℃前脱失沸石水,对晶体结构没有影响;200—400℃配位水渐次脱失,晶体发生“折叠作用”,为无水坡缕石阶段;400-500℃时大部分羟基脱失,坡缕石结构随羟基脱失逐渐瓦解;700—800℃出现短暂的玻璃相,接着在800—900℃先后重结晶为顽火辉石和方英石。在高温结晶相中未发现硅线石。     

安徽月山高钾闪长岩岩石学特征及岩石成因探讨

月山高钾闪长岩体是长江中下游夕卡岩型铜铁成矿带与成矿作用密切相关的代表性岩体。该岩体位于长江中下游岩浆岩带的中段,地处安徽省安庆市北北西20km.     

大别山北部镁铁-超镁铁质岩带中榴辉岩的分布与变质温压条件

大别山北部镁铁-超镁铁质岩带中的榴辉岩主要有两种产状,一是产于变形较强(面理化)的橄榄岩中,另一种是产于片麻岩中。其中,绿辉石中硬玉端元组分大多为Jd=20mol％～52mol％。产于橄榄岩和片麻岩中榴辉岩的石榴子石成分分别相当于Coleman的B型和C型榴辉岩。石榴子石成分特征及钠质单斜辉石中石英针状出溶体的出现表明,本区榴辉岩早期可能经历过超高压变质作用,且至少经历了3个变质阶段,即:①榴辉岩相峰期变质阶段,主要矿物共生组合为石榴子石+绿辉石+金红石±蓝晶石+石英(或柯石英假象?),p≥2.5GPa、t=595～874℃;②高压麻粒岩相变质阶段,主要矿物共生组合为石榴子石+透辉石+紫苏辉石+钛铁矿+尖晶石+斜长石等,p=1.1～1.37GPa、t=817～909℃;③角闪岩相变质阶段,主要矿物共生组合为角闪石+斜长石+磁铁矿等,p=0.5～0.6GPa、t=500～600℃。该区榴辉岩独特的麻粒岩相退变质阶段,表明榴辉岩在折返初期并未能上升到中上地壳,而处于下地壳,它与南部超高压变质岩有不同的p-t演化史,即在榴辉岩相峰期变质之后经历了近等温减压(或稍升温减压)和降温减压变质过程。     

大别造山带的流体系统与成矿作用

大别山是大别造山带的主体部分，流体活动贯穿于俯冲－碰撞－折返整个造山过程。印支期俯冲－碰撞阶段的流体，以具高挥发份、高盐度为特点，流体中保留有原岩在地表时的天水－岩石以及超高压变质过程中的地幔流体－岩石同位素交换的信息。燕山期折返隆升阶段的流体是大量天水与深部流体发生混合的产物，流体中盐度降低，但水－岩相互作用增强。大别造山带的流体系统可称为“天水与深部流体混合系统”，并可分为流体富集区、流体贫乏区和流体排泄区三个部分。成矿作用主要发生在流体富集区。     

港口湾水库入库洪水预报模型研究

基于港口湾、胡乐司流域产、汇流分析，提出了分流域、分单元入库洪水预报模型的整体构架，产流计算应用了蓄满产流模型，汇流计算提出了拟线性河网汇流指数模型：Csj=Sso αe^-βA j，实现了汇流系数因入流强度自动调整的目标。     

西藏羌塘地块西北部银利沟早白垩世钾玄质侵入岩的发现——来自地球化学和锆石U—Pb年龄的证据

银利沟二长岩分布于西藏羌塘西北部,岩石具有高碱、低Ti的特征,在SiO2-K2O图解中位于钾玄岩区。二长岩的锆石U-Pb同位素年龄为121.3Ma±0.6Ma,具有富集LIL、LIEE及显著的Ta-Nb-Ti负异常的地球化学特征,表现出与俯冲有关的钾玄岩的地球化学特征,形成于晚造山—后造山构造背景。这种背景很可能与冈底斯和羌塘地块在晚侏罗世—早白垩世发生的碰撞作用有关。