Hydrogeochemical characteristics of spring water in the Harz Mountains,Germany

Spring water samples of the Harz Mountains were taken in several seasons of 2010, 2011, and 2012. The samples have been analysed for main components (Na⁺, K⁺, Ca²⁺, Mg²⁺, SO₄²⁻, Cl⁻, HCO₃⁻ and NO₃⁻), trace elements (Fe, Cu, Pb, Zn, Y and REE), DOC, δ¹⁸O and δ²H of water. Meteoric water is indicated as the main source of the springs sampled. High precipitation rates lead to a dilution of the measured elemental concentrations. Furthermore, regional differences of rock and water interactions were found. REE concentrations and patterns of the spring waters vary between the distinct geological units and reflect the geochemical characteristics of the surrounding rocks. The actual data compared to measured data from the seventies and nineties of the last century indicate a decrease of the sulphate concentrations in the spring waters which is typical of many European mountain catchments.     

Modelling carbon dynamics from urban land conversion: fundamental model of city in relation to a local carbon cycle

Background  

The main task is to estimate the qualitative and quantitative contribution of urban territories and precisely of the process of urbanization to the Global Carbon Cycle (GCC). Note that, on the contrary to many investigations that have considered direct anthropogenic emission of CO₂(urbanized territories produce ca. 96–98% of it), we are interested in more subtle, and up until the present time, weaker processes associated with the conversion of the surrounding natural ecosystems and landscapes into urban lands. Such conversion inevitably takes place when cities are sprawling and additional "natural" lands are becoming "urbanized".     

Chloritoid-Bearing Mineral Assemblages in High-Pressure Metapelites from the Bughea Complex, Leaota Massif (South Carpathians)

High-Mg chloritoid (X_Mg = 0·40–0·47) andrelatively high-Mg staurolite (X_Mg = 0·25–0·28)coexisting with kyanite and garnet were identified in a mica–garnet-richrock associated with very high-pressure eclogites in the BugheaComplex of the Leaota Massif (South Carpathians). Major andtrace element geochemical data for both fresh eclogites andassociated rocks which represent a metasomatic or retrogradealteration rind of the eclogites, indicate a pelitic precursor.Magnesian chloritoid was found as inclusions in garnet as partof a chloritoid–kyanite–garnet assemblage whichis indicative of high-pressure conditions. The host garnet showsa typically prograde chemical zoning pattern. The chloritoid-bearingassemblage is confined to the inner part of the garnet porphyroblasts,whereas the matrix assemblage in equilibrium with Mg-rich garnetrims has exceeded the thermal stability limit of chloritoid.Pressure–temperature pseudosections for simplified compositionsapproaching the rock bulk-chemistry show a high-pressure fieldfor the identified chloritoid-bearing assemblage in good agreementwith pressure–temperature estimates in the CFMASH andKCFMASH chemical subsystems using analysed mineral compositions.The derived pressure–temperature path is clockwise, indicatingoverprinting during exhumation from 1·8 GPa and 580°Cto 1·15 GPa and 620°C, at a water activity approachinga_H2O = 1. These conditions were attained in a subduction mélangeindicating transient thermal perturbations of a subduction channel. KEY WORDS: high-pressure metapelite; Mg-rich chloritoid; P–T path; P–T pseudosection; very high-pressure eclogite     

Evidence for oceanic subduction at the NE Gondwana margin during Permo-Triassic times

Blueschist was recently recognized within the Lhasa terrane, which is one of the NE Gondwana blocks. In this rock, the Mn and Mg contents of garnet enclosing aegirine-rich clinopyroxene, rutile and quartz decrease and increase, respectively, from core to rim. Amphibole changes from glaucophane through Na–Ca amphibole to Ca amphibole. The Si contents of phengite are high in the centre but low along the rim. The P – T path, starting above 2.5 GPa–450 °C and showing subsequently first a temperature increase to 500 °C and then a pressure release via blueschist conditions to 0.6 GPa, was reconstructed using a P – T pseudosection calculated for the P – T range 0.4–2.8 GPa and 250–650 °C. This path points to deep subduction of a cold oceanic crust probably beneath the NE Gondwana margin during Permo-Triassic times. This finding contributes to a better understanding of the pre-Cenozoic history of major terranes of NE Gondwana.     

Evidence for low-temperature ultrapotassic siliceous fluids in subduction zone environments from experiments in the system K2O---MgO---Al2O3---SiO2---H2O (KMASH)

Experiments in the system K₂O---MgO---Al₂O₃---SiO₂---H₂O (KMASH) were undertaken with the piston-cylinder-apparatus to study the reactions:

1. (1) phengite±quartz+K,Mg-rich siliceous fluid=feldspar+phologopite+H₂O

2. (2) phengite+talc+K,Mg-rich siliceous fluid=phlogopite+quartz/coesite+H₂O

at temperatures between 400 and 700°C. The ultrapotassic fluid appearing at pressures above 15 kbar on the low-temperature sides of the corresponding reaction curves, which show positive dP/dT slopes, is probably supercritical. The P-T positions of the reactions are compatible with KMASH mineral reactions studied previously and with melting investigations in the KMASH system undertaken at temperatures higher than 700°C.

It is possible that natural rocks, chiefly K-rich metasediments subducted as minor portions of the oceanic crust, could give rise to low-temperature ultrapotassic fluids, mainly at temperatures between 300° to 600°C and pressures between 15 and 30 kbar. The ascending K-rich fluids would penetrate the overlying mantle to metasomatize it. After termination of the subduction process, heating of this mantle material, previously cooled by the subducted lithosphere, could lead to the formation of high-temperature K-rich magmas.     

P -T-t history of the Lower Austroalpine Nappe Complex in the “Tarntaler Berge” NW of the Tauern Window: implications for the geotectonic evolution of the central Eastern Alps

New petrologic and ⁴⁰Ar/³⁹Ar geochronologic data constrain conditions of Alpine metamorphism along the northwestern border of the Tauern Window. The P-T estimations based on phengite barometry were determined for samples from units of the Lower Austroalpine nappe complex exposed above the Southpenninic interior of the Tauern Window, and from upper parts of the Southpenninic “Bündner Schiefer” sequence. Results suggest that both Mesozoic metasedimentary nappe units (Reckner and Hippold Nappes) and an ophiolitic nappe (Reckner Complex) of the Lower Austroalpine nappe complex have been metamorphosed at pressures between 8 and 10.5 kbar and temperatures around 350 °C. The structurally highest Lower Austroalpine unit (Quartzphyllite Nappe) was not affected by high-pressure metamorphism and records maximum P-T conditions of approximately 4 kbar and 400 °C. Highest parts of the structurally underlying Southpenninic Bündner Schiefer sequence were metamorphosed at intermediate pressures (6–7 kbar). Temperatures increased in all structural units during decompression. Whole-rock ⁴⁰Ar/³⁹Ar plateau ages of silicic phyllites and cherts with abundant high-Si phengites record ages around 50 Ma in the Reckner Nappe, and 44–37 Ma in the Hippold Nappe and Southpenninic Bündner Schiefer sequence. These ages are interpreted to date closely the high-pressure metamorphism. The Lower Austroalpine-Southpenninic border area in the NW Tauern Window appears to have evolved along an indented, fragmented active continental margin where the Reckner Complex represents one of the oldest sections of the Southpenninic (Piemontais) Oceanic tract that was originally situated close to, or even within, the Lower Austroalpine continent. During closure of the Piemontais Ocean, the resultant subduction zone did not entrain components of the Reckner Complex or its cover sequences (Reckner and Hippold Nappes): therefore “Eoalpine” high-pressure metamorphism did not occur. Sequences exposed within the study area were subducted to relatively shallow depths during the last stage of consumption of oceanic crust and immediately prior to final continental collision. Received: 30 July 1996 / Accepted: 7 April 1997     

Statistical analysis of strong-motion accelerograms and its application to earthquake early-warning systems

In view of increasing damage due to earthquakes, and the current problems of earthquake prediction, real-time warning of strong ground motion is attracting more interest. In principle, it allows short-term warning of earthquakes while they are occurring. With warning times of up to tens of seconds it is possible to send alerts to potential areas of strong shaking before the arrival of the seismic waves and to mitigate the damage, but only if the seismic source parameters are determined rapidly. The major problem of an early-warning system is the real-time estimation of the earthquake's size.
We investigated digitized strong-motion accelerograms from 244 earthquakes that occurred in North and Central America between 1940 and 1986 to find out whether their initial portions reflected the size of the ongoing earthquake. Applying conventional methods of time-series analyses we calculate appropriate signal parameters and describe their uncertainties in relation to the magnitude and epicentral distance. The study reveals that the magnitude of an earthquake can be predicted from the first second of a single accelerogram within ±1.36 magnitude units. The uncertainty can be reduced to about ±0.5 magnitude units if a larger number (≥8) of accelerograms are available, which requires a dense network of seismic stations in areas of high seismic risk.     

Eclogites from the Chinese continental scientific drilling borehole, their petrology and different P-T evolutions

Abstract Four phengite‐bearing eclogites, taken from different depths of the Chinese continental scientific drilling (CCSD) borehole in the Sulu ultrahigh pressure terrane, eastern China, were studied with the electron microprobe. The compositional zonations of garnet and omphacite are moderate, whereas phengite compositions generally vary significantly in a single sample from core to rim by decrease of the Si content. Various geothermobarometric methods were applied to constrain the P‐T conditions of these eclogites on the basis of the compositional variability of the above minerals. The constrained P‐T path for sample B218 is characterized by pressure decrease from ca 3.0 GPa (ca 600°C) to 1.3 GPa (ca 550°C). Eclogite B310 yielded P‐T conditions of 3.0 GPa and 750°C. The path for eclogite B1008 starts at about 650°C and 3.6–3.9 GPa (stage I) followed by a pressure decrease to 2.8–3.0 GPa and a significant temperature rise (stages II and IIIa, 750–810°C). Afterwards, this rock cooled down to 620–660°C at still high pressures (2.5–2.7 GPa, stage IIIb). Retrograde conditions were about 670°C and 1.3 GPa (stage IV). Eclogite B1039 yielded a P‐T path starting at ca 600°C and 3.3–3.9 GPa (stage I). A pressure decrease to about 3.0 GPa (stage II, 590–610°C) and then a moderate isobaric temperature increase to ca 630°C (stage III) followed. Stage IV is characterized by temperatures of 650°C at pressures close to 1.3 GPa. During and after this stage (hydrous) fluids partially rich in potassium penetrated the rocks causing minor changes. Relatively high oxygen fugacities led to andradite and magnetite among the newly formed minerals. We think that the above findings can be best explained by mass flow in a subduction channel. Thus, we conclude that the assembly of UHP rocks of the CCSD site, eclogites, quartzofeldspathic rocks, and peridotites, cannot represent a crustal section that was already coherent at UHP conditions as it is the common belief currently. The coherency was attained after significant exhumation of these UHP rocks.