Focused ion beam technique and transmission electron microscope studies of microdiamonds from the Saxonian Erzgebirge, Germany

A focused ion beam of Ga ions is a relatively new technique that has been developed for microelectronic industries. Now researchers of the Earth sciences find it to be a promising tool for studying various geological materials. Using the FIB technique and an FEI Strata DB 235 dual beam system, we have successfully prepared several electron-transparent foils, which crossed μm-sized diamonds included in host minerals such as zircon and garnet from quartzofeldspathic rocks of the Saxonian Erzgebirge, Germany. Scanning and transmission electron microscopy applied to these foils revealed that the diamonds contain crystalline nanometric inclusions. These inclusions consist of minerals of known stoichiometries such as SiO₂ and Al₂SiO₅, whereas others are characterized by different combinations of Si, K, P, Ti, and Fe in the presence of oxygen (stoichiometries are not clear at this stage of research). One suite of inclusions is assumed to be represented by archerite, KH₂PO₄, which is known to be stable at pressures of 4–22 GPa, and one nanocrystal containing Pb, oxygen and carbon is interpreted to be Pb_xO_y or PbCO₃. Along with solid crystalline inclusions, the diamonds contain cavities filled by liquid/gas that escaped during sample preparation. These are associated with dislocations of diamond growth. Our data are consistent with the concept of diamond crystallization from a COH-rich multicomponent supercritical fluid and suggest that the composition of such a fluid is more consistent with a local crustal source rather than that of a mantle origin.     

A comparison of the evolution of diamondiferous quartz-rich rocks from the Saxonian Erzgebirge and the Kokchetav Massif: are so-called diamondiferous gneisses magmatic rocks?

The petrography and chemical composition of minerals of quartz-rich diamondiferous rocks from the Kokchetav Massif, especially the zonation of garnet, were studied and compared with diamondiferous quartzofeldspathic rocks from the Saxonian Erzgebirge. Many compositional and textural features were found to be similar. For instance, microdiamonds are enclosed systematically in a specific intermediate growth zone of garnet in these rocks. On the basis of experimental data, a magmatic scenario was constructed to check if the quartz-rich diamondiferous rocks are of magmatic origin. By this, the P-T paths, derived here for the Kokchetav rocks, and the textural observations it is concluded that the minerals of the diamondiferous rocks have crystallized from silicate melts. These melts originated by anatexis of deeply submerged metasediments (Erzgebirge: at T as high as 1200°C, Kokchetav Massif: at 50-100°C lower T) and ascended from at least 200 km depth. Relics of the pre-anatectic evolution are still present, for instance, as garnet cores. After ascent and emplacement of the magma in deep portions of thickened continental crust (Kokchetav Massif: 45-50 km close to 800°C, Erzgebirge: 55-60 km at 30-50°C lower T) considerable quantities of (white and/or dark) micas formed by peritectic reactions from melt. For instance, garnets could be resorbed at this stage and biotite grew instead. After the magmatic stage, retrogression took place much stronger in the Kokchetav Massif. This was accompanied by deformation transforming broadly the magmatic texture of quartz-rich diamondiferous rocks from the Kokchetav Massif to a gneissic texture.     

High-P (P = 1.5–1.8 GPa) blueschist from Elba: Implications for underthrusting and exhumation of continental units in the Northern Apennines

The Acquadolce Subunit on the Island of Elba, Italy, records blueschist facies metamorphism related to the Oligocene–early Miocene stages of continental collision in the Northern Apennines. The blueschist facies metamorphism is represented by glaucophane- and lawsonite-bearing metabasite associated with marble and calcschist. These rock types occur as lenses in a schistose complex representing foredeep deposits of early Oligocene age. Detailed petrological analyses on metabasic and metapelitic protoliths, involving mineral and bulk-rock chemistry coupled with P–T and P–T–X(Fe₂O₃) pseudosection modelling using PERPLE_X, show that the Acquadolce Subunit recorded nearly isothermal exhumation from peak pressure–temperature conditions of 1.5–1.8 GPa and 320–370°C. During exhumation, peak lawsonite- and possibly carpholite- or stilpnomelane-bearing assemblages were overprinted and partially obliterated by epidote-blueschist and, subsequently, albite-greenschist facies metamorphic assemblages. This study sheds new light on the tectonic evolution of Adria-derived metamorphic units in the Northern Apennines, by showing (a) the deep underthrusting of continental crust during continental collision and (b) rapid exhumation along ‘cold’ and nearly isothermal paths, compatible with syn-orogenic extrusion.     

Alpine metamorphism of low-grade schists from the Slavonian Mountains (Croatia): new P-T and geochronological constraints

Low-grade schists from the Slavonian Mountains (Tisia Mega-Unit, Mt Papuk, Croatia), previously assigned to Precambrian to Lower Palaeozoic metamorphism, have been subjected to geochemical investigations, P-T modelling, and in situ age dating of monazite. The studied fine-grained metasediments consist of chlorite (5–15 vol.%), K white-mica (40–55 vol.%), quartz (20–35 vol.%), feldspar (albite 15–20 vol.%), opaques (<2 vol.%), and accessory minerals. According to their whole-rock geochemistry, the detritus of the former sediments came from upper crustal felsic rocks as they occur, for instance, at Mt Papuk. The schists show a complex microtectonic fabric, including well-developed schistosity systems. P-T pseudosections in the system MnNCKFMASHTO, constructed for typical schists of the study area, resulted in peak P-T conditions of 445–465 °C and 4.6–6.0 kbar for a sample from Kutjevo (eastern part of the study area) and 450–460 °C and 5.2–6.0 for a Vranovo sample (western part). Electron microprobe (EMP) dating of monazite in the schists gave a weighted average age of 109.0 ± 13.1 Ma (2σ) eventually with three subgroups of ages at 225 ± 63 (two analyses), 114 ± 24 and 83 ± 22 Ma. We conclude that the metamorphism of the studied schists at depths of c. 20 km is due to an Alpine collisional event.     

Korrelation der Sporenzonen der Oberen Trias und des Jura im Mittleren Orient und in Süddeutschland

Zusammenfassung Bei der sporenstratigraphischen Gliederung des mittleren Mesozoikums im Mittleren Orient konnten vom Nor bis zur Unteren Kreide 6 Sporenzonen unterschieden werden: Unterkreide:Ischyosporites variegatus — Rouseisporites laciniatus — Cicatricosisporites-Zone Malm:Ischyosporites variegatus — Rouseisporites laciniatus-Zone Dogger:Ischyosporites variegatus — Duplexisporites problematicus-Zone Lias:Concavisporites — Duplexisporites problematicus-Zone Rät:Concavisporites — Duplexisporites problematicus — Lophotriletes sangburensis — Ricciisporites tuberculatus-Zone Nor:Concavisporites — Duplexisporites problematicus — Lophotriletes sangburensis — Cyclotriletes oligogranifer-ZoneVergleichende Untersuchungen ergaben, daß diese Sporenzonen auch auf Süddeutschland übertragbar sind und den faunistischen Grenzen entsprechen. Nur die sporenstratigraphische Festlegung der Nor/Rätsowie der Dogger/Malm- und der Malm/Unterkreide-Grenze bedürfen noch der Verifizierung.

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In the middle Mesozoic of the Middle East 6 spore-assoziations could be distinguished from the Norian to the Lower Cretaceous: Lower Cretaceous:Ischyosporites variegatus — Rouseisporites laciniatus — Cicatricosisporites zone Upper Jurassic:Ischyosporites variegatus — Rouseisporites laciniatus zone Middle Jurassic:Ischyosporites variegatus — Duplexisporites problematicus zone Lower Jurassic:Concavisporites — Duplexisporites problematicus zone Rhaetian:Concavisporites — Duplexisporites problematicus — Lophotriletes sangburensis — Ricciisporites tuberculatus zone Norian:Concavisporites — Duplexisporites problematicus — Lophotriletes sangburensis — Cyclotriletes oligogranifer zone.The interregional validity and the correspondance of these spore zones with the faunistic boundaries could be substantiated in equivalent sequences in Southern Germany. However, the palynological definition of the Norian/Rhaetian, Middle/Upper Jurassic and Jurassic/Cretaceous boundaries have still to be confirmed in other regions since suitable sections have not been available in Southern Germany.

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Résumé Dans le Mésozoïque moyen du Moyen Orient, six zones de spores peuvent être distinguées du Norien au Crétacé inférieur: Crétacé inférieur: Zone àIschyosporites variegatus — Rouseisporites laciniatus — Cicatricosisporites Jurassique supérieur: Zone àIschyosporites variegatus — Rouseisporites laciniatus Jurassique moyen: Zone àIschyosporites variegatus — Duplexisporites problematicus Jurassique inférieur: Zone àConcavisporites — Duplexisporites problematicus Réthien: Zone àConcavisporites — Duplexisporites problematicus — Lophotriletes sangburensis — Ricciisporites tuberculatus Norien: Zone àConcavisporites — Duplexisporites problematicus — Lophotriletes sangburensis — Cyclotriletes oligogranifer Une étude comparative montre que les mêmes zones de spores existent en Allemagne du sud et qu'elles correspondent aux limites faunistiques. Toutefois, les limites Norien/ Rhétien, Dogger/Malm et Malm/Crétacé inférieur demandent à être vérifiées.

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- : : Ischyosporites variegatus —Rouseisporites laciniatus — Cicatricosisporites : Ischyosporites variegatus — Rouseisporites laciniatus : Ischyosporites variegatus — Duplexisporites problematicus : Concavisporites — Duplexisporites problematicus : Concavisporites — Duplexisporites problematicus — Lophotriletes sangburensis — Ricciisporites tuberculatus : Concavisporites — Duplexisporites problematicus — Lophotriletes sangburensis — Cyclotriletes oligogranifer. , , . , /, / / .

     

Antagonistic structures in border areas: Local milieux and local politics in the Polish-German twin city Gubin/Guben

Cross-border communication and co-operation at the Eastern fringe of the European Union seems so far to have been a matter of political initiative and a lot of good will at the levels of national, regional and local governance. This article maintains that everyday culture must be given more notice when cross-border activities are regarded at the local level, especially in twin cities. The case of the German-Polish twin city Guben/Gubin reveals a strong tendency towards a new divergence of thought and action between formal and informal levels of action, namely the level of local politics and governance and the level of local everyday milieux. While the politics of Euroregions, local administrations and local governments is very often directed towards establishing symbolic gestures of border-crossing and mutual understanding, social milieux at the ‘base’ of local societies are rather driven by a paradoxical mixture of hope, anxiety, resentments and prejudice, thus producing contradictions and even conflict with official political initiative. This revised version was published online in July 2006 with corrections to the Cover Date.     

Search for strange attractors in magnetic field data: An example from a tertiary volcanic area near Bonn, Germany

Spatial variations of the magnetic field, measured at the Earth's surface, are mainly due to geological inhomogeneities within the crust. The present state of the crust, in turn, reflects its past dynamical processes and evolution. We analyzed the magnetic field intensity along a few but densely sampled profiles in a Tertiary volcanic province near Bonn, Germany. The aim was to find out whether the variation of the magnetic intensity can be related to a deterministic, although chaotic, generating system or to a stochastic one. In the former case, the geodynamical history would depend on a few degrees of freedom, whereas in the latter case, the parameters to take into account were so many that a statistic approach appears to be more suitable. Since strange attractors do not emerge from the analyzed data, we exclude the presence of a chaos generating system. Autocorrelation functions and a rescaled-range analysis, on the other hand, reveal and quantify a certain degree of correlation among successive data points and allow calculation of a range of spectral exponents in log-log diagrams, which are clearly distinct from those of white noise and Brownian motion. Only one of the profiles exhibits similarity to uncorrelated or white noise. In this case, the signal variations do not result from the local geology but from a buried gas pipe-line, aligned subparallel to that profile. If self-organized crustal evolution generally produces signatures that can be described as correlated noise, within a limited bandwidth of spectral exponents, erraneous or disturbed data could eventually be discriminated from records containing purely natural data by applying analysis tools of the dynamic system theory together with autocorrelation tests.     

From Kyoto via Moscow to nowhere?

Abstract

Since the World Climate Change Conference held in the autumn of 2003 in Moscow, Russian Federation, the fate of international climate policy architecture designed around the Kyoto Protocol hangs in the balance. After the withdrawal of the USA from the Kyoto Protocol, the condition of its ratification cannot be met without the Russian Federation. There has been a considerable uncertainty as to Russia's intentions regarding ratification of Kyoto. In this contribution, an attempt is made to identify the Russian motives and concerns, and explain their attitudes regarding the Kyoto Protocol. Pressures against and for ratification are discussed. Finally, a few comments are made about the future of the efforts to solve the global environmental problem of protecting the Earth's climate.