Metal Complexation with Different types of Soluble and Adsorbed Freshwater Ligands Followed by DPASV

In order to understand metal speciation in a polluted river (Este River, Northern Portugal) filtrate, freeze dried particles and organics desorbed from surfaces were titrated with Cd(II) and Zn(II), followed by differential pulse anodic stripping voltammetry (DPASV). The obtained results are compared with those previously published for Pb(II) and Cu(II). Due to the heterogeneity of the system, a continuous and a discrete ligand model were used to interpret the titration data. Two types of ligands could be detected and quantified by the discrete ligand model: small molecules with high affinities for cations such as Cd(II), Cu(I), and Zn(II) and macromolecules with higher affinities for Pb(II) and Cu(II). Small ligands were strongly adsorbed onto the particles, as inferred from the desorption of Zn(II) during titration with Pb(II) and Cd(II). The total concentrations of the different ligands and the complex formation constants with the different metals are reported.     

Fault–valve action and vein development during strike–slip faulting: An example from the Ribeira Shear Zone, Southeastern Brazil

Fluid inclusion microthermometry and structural data are presented for quartz vein systems of a major dextral transcurrent shear zone of Neoproterozoic–Cambrian age in the Ribeira River Valley area, southeastern Brazil. Geometric and microstructural constraints indicate that foliation–parallel and extensional veins were formed during dextral strike–slip faulting. Both vein systems are formed essentially by quartz and lesser contents of sulfides and carbonates, and were crystallized in the presence of CO₂–CH₄ and H₂O–CO₂–CH₄–NaCl immiscible fluids following unmixing from a homogeneous parental fluid. Contrasting fluid entrapment conditions indicate that the two vein systems were formed in different structural levels. Foliation–parallel veins were precipitated beneath the seismogenic zone under pressure fluctuating from moderately sublithostatic to moderately subhydrostatic values (319–397 °C and 47–215 MPa), which is compatible with predicted fluid pressure cycle curves derived from fault–valve action. Growth of extensional veins occurred in shallower structural levels, under pressure fluctuating from near hydrostatic to moderately subhydrostatic values (207–218 °C and 18–74 MPa), which indicate that precipitation occurred within the near surface hydrostatically pressured seismogenic zone. Fluid immiscibility and precipitation of quartz in foliation–parallel veins resulted from fluid pressure drop immediately after earthquake rupture. Fluid immiscibility following a local pressure drop during extensional veining occurred in pre-seismic stages in response to the development of fracture porosity in the dilatant zone. Late stages of fluid circulation within the fault zone are represented dominantly by low to high salinity (0.2 to 44 wt.% equivalent NaCl) H₂O–NaCl–CaCl₂ fluid inclusions trapped in healed fractures mainly in foliation–parallel veins, which also exhibit subordinate H₂O–NaCl–CaCl₂, CO₂–(CH₄) and H₂O–CO₂–(CH₄)–NaCl fluid inclusions trapped under subsolvus conditions in single healed microcracks. Recurrent circulation of aqueous–carbonic fluids and aqueous fluids of highly contrasting salinities during veining and post-veining stages suggests that fluids of different reservoirs were pumped to the ruptured fault zone during faulting episodes. A fluid evolution trending toward CH₄ depletion for CO₂–CH₄–bearing fluids and salinity depletion and dilution (approximation of the system H₂O–NaCl) for aqueous–saline fluids occurred concomitantly with decrease in temperature and pressure related to fluid entrapment in progressively shallower structural levels reflecting the shear zone exhumation history.     

Characterisation of the intra-annual rainfall and its evolution (1837–2010) in the southwest of the Iberian Peninsula

Variability in precipitation affects annual total records and causes instability in rainfall distribution throughout the year. Our aim in this study was to develop a procedure, based on pluviometric centralisation and dispersion parameters, that is able to characterise rainfall distribution throughout a year of precipitation in a unique, condensed and precise manner. This enabled the evolution of intra-annual precipitation from 1837 to 2010 in the southwest of the Iberian Peninsula to be determined. The obtained results showed irregular oscillations of the parameters during the selected period. Specifically, patterns of precipitation in recent decades revealed the following differentiating features: the displacement of the most intense rainy periods in autumn with a consequent decrease in precipitation in spring, and more erratic distribution throughout the year with an increase of the frequency of intra-annual dispersion peaks.     

Gaussian Processes for history-matching: application to an unconventional gas reservoir

The process of reservoir history-matching is a costly task. Many available history-matching algorithms either fail to perform such a task or they require a large number of simulation runs. To overcome such struggles, we apply the Gaussian Process (GP) modeling technique to approximate the costly objective functions and to expedite finding the global optima. A GP model is a proxy, which is employed to model the input-output relationships by assuming a multi-Gaussian distribution on the output values. An infill criterion is used in conjunction with a GP model to help sequentially add the samples with potentially lower outputs. The IC fault model is used to compare the efficiency of GP-based optimization method with other typical optimization methods for minimizing the objective function. In this paper, we present the applicability of using a GP modeling approach for reservoir history-matching problems, which is exemplified by numerical analysis of production data from a horizontal multi-stage fractured tight gas condensate well. The results for the case that is studied here show a quick convergence to the lowest objective values in less than 100 simulations for this 20-dimensional problem. This amounts to an almost 10 times faster performance compared to the Differential Evolution (DE) algorithm that is also known to be a powerful optimization technique. The sensitivities are conducted to explain the performance of the GP-based optimization technique with various correlation functions.     

Spatial distribution and estimation of rainfall trends and erosivity in the Epitácio Pessoa reservoir catchment,Paraíba,Brazil

Natural Hazards - The main goals of this study are to better understand the spatial and temporal variabilities in rainfall and to identify rainfall trends and erosivity for the period from 1963 to...     

Entropy theory for analysing water resources in northeastern region of Brazil

Using the Shannon entropy, the space–time variability of rainfall and streamflow was assessed for daily rainfall and streamflow data for a 10-year period from 189 stations in the northeastern region of Brazil. Mean values of marginal entropy were computed for all observation stations and entropy maps were then constructed for delineating annual and seasonal characteristics of rainfall and streamflow. The Mann-Kendall test was used to evaluate the long-term trend in marginal entropy as well as relative entropy for two sample stations. The marginal entropy values of rainfall and streamflow were higher for locations and periods with the highest amounts of rainfall. The entropy values were higher where rainfall was higher. This was because the probability distributions of rainfall and the resulting streamflow were more uniform and less skewed. The Shannon entropy produced spatial patterns which led to a better understanding of rainfall and streamflow characteristics throughout the northeastern region of Brazil. The total relative entropy indicated that rainfall and streamflow carried the same information content at annual and rainy season time scales.     

The role of fault reactivation in the development of tropical montane lakes

This work details the role of fault reactivation in the development of tropical montane lakes by using basin morpho-structural analysis and seismostratigraphic studies. The upland lakes are severely faulted sinkholes, whose faults penetrate the Quaternary sedimentary units. Four main stages are related to the lake formation: (i) an Early Proterozoic tectonic deformation of the rocks along the southern border of the Carajás Structure, where the lake is placed; (ii) differential erosion by – and building of – the formation of the South Carajás Hill; (iii) Fe-rich crust formation by weathering and gravitational collapse faults following the E–W plateau border and the start of Violão Lake formation during the Pliocene–Pleistocene; and (iv) episodic fault-fracture reactivation by gravitational collapse causing pulses of subsidence in the lake and outlining its faulted borders. Dissolution of the lateritic crust and erosion by runoff drainage under wet climate conditions were coeval with fault activities, which allowed the deposition of relatively thick clastic deposits organized in three main seismostratigraphic units associated with major lake-level fluctuations. Initial fault reactivation under low-level water started lacustrine basin development with deposition of prograding fan deltas related to the main drainage. A second fault reactivation by gravitational collapse increased the lake accommodation space and resulted in the deposition of fine-grained sediments from dilute interflows or overflows until 36 000 cal year BP. At about 31 000 cal year BP, rapid decreases in the lake water level under redox conditions at the sediment/water interface allowed widespread siderite formation. A third gravitational collapse episode was responsible for the increase in the lake area and depth and the returning of clastic/organic deposition up to the present. This tropical montane lake can be seen as a representative example for understanding the formation of other upland lakes controlled by fault reactivation. © 2020 John Wiley & Sons, Ltd.     

AsteroFLAG: First results from hare‐and‐hounds Exercise #1

We report on initial results from the first phase of Exercise #1 of the asteroFLAG hare and hounds. The asteroFLAG group is helping to prepare for the asteroseismology component of NASA's Kepler mission, and the first phase of Exercise #1 is concerned with testing extraction of estimates of the large and small frequency spacings of the low‐degree p modes from Kepler‐like artificial data. These seismic frequency spacings will provide key input for complementing the exoplanet search data. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)