一个三维水动力学模型及其在水环境中的适用性试验

发展了一个三维水动力学模型.该模型在水底磨擦项计算中,采用了流速的平方根法;在湍流扩散系数的估算中,采用了带稳定度函数的参数化方案;对垂直方向上的坐标进行了压缩,引入σ坐标;对时间变量则采用了分离模式技术,即外部模式(快过程)与内部模式(慢过程);而求解外部模式时,采用了显式一隐式格式交错法(ADI),从而使模型不仅计算时间缩短,且可应用于水很深而水平空间尺度很小,又有热力分层的水域中.最后作为该模型的一个实用性试验,选择了美国犹他州East Canyon水库,利用该模型探讨了温跃层对风、人流及出流变化的响应情况.     

Distribution functions of spring discharges according to their lithologies and the influence of lower limit to flow: an example from Spain

Specific functions of distribution of the number of springs and of their contributions according to flow for each of nine lithological groups are established. These functions confirm the suitability of a general type of distribution (Sanz 1996), which is a borderline case of the lognormal distribution. The statistical methods proposed for the lithological types presented can be applied to any region if data on flow and lithology of the aquifers drained by springs are available. These methods have been applied to Spain, a representative region with varied geology, climate and topography; 71.2% of spring flow is supplied by limestones, 19.17% by alluvial sediments and marls, 6.7% by conglomerates and sandstones, and 3% by slates, plutonic rocks, quartzites, and other groups. Springs with discharge rates exceeding 2000 L/s exist only in limestones. The majority of springs with low flow occur in marls. If we consider springs with flow greater than 0.5 L/s, alluvial sediments, sandstones, marls, and limestones have the greatest density of springs per surface area, although the average flow varies greatly from one lithology to the next. The cumulative estimated discharge and the estimated number of springs depend upon the definition of the lower limit of flow. For example, total discharge is reduced by 30% if we eliminate all springs with flow lower than 0.5 L/min.     

苏皖地区大陆岩石圈地幔的长时性--地幔橄榄岩捕虏体的锇同位素模式年龄

中国(USTC)和法国(CRPG)两个实验室测定了苏皖地区地幔橄榄岩捕虏体全岩的锇同位素组成,结果187Os/188Os=0.119～0.129(USTC,n=25,n为样品数,下同)和0.117～0.131(CRPG,n=17).大部分样品的Os同位素组成(<0.1290)呈亏损特征,Os同位素组成与主量成分之间有线性相关性.用187Os/188Os-Al2O3代用等时线法获得的模式年龄为(2.5±0.1)Ga(USTC)和(1.9±0.1)Ga(CRPG),为晚太古代-早元古代.样品组中最低的187Os/188Os比值为0.119(USTC)和0.117(CRPG),相应的Re亏损模式年龄为1.1Ga(USTC)和1.4Ga(CRPG),为中元古代.锇同位素模式年龄表明苏皖地区新生代玄武岩中包含的地幔橄榄岩捕虏体具有古老的形成年龄(早元古-中元古代),它们是经过显生宙岩石圈地幔减薄作用后的残余地幔的碎片,而不是显生宙"置换作用"中产生的新生地幔.     

藏高原雪冰电导率与降水碱度以及大气粉尘载荷变化的关系

对青藏高原小冬克玛底冰川和古里雅冰帽上的数个雪坑和浅冰芯的观测,得出其碱度(OH-)剖面、雪坑和冰芯的液态电导率(EC)变化与OH-之间呈良好线性相关(r≥0.8).分析表明,无论在季节、年际或百年际时间尺度上,EC与OH-间的相关性以及EC与可溶离子总量(TDS)间的相关程度是大致相当的.EC的波动主要取决于粉尘来源的碱性盐类(尤其Ca2+)的变化.因此,EC参量运用到深冰芯研究中,可反映历史时期大气粉尘载荷的变化,对反演沙漠演化、大气环流有重要意义.古里雅冰芯记录表明,大气粉尘的中、长期变化可能取决于气候参量的组合特征"冷-干"气候阶段粉尘量上升,EC和OH-值高;"暖-湿"阶段粉尘量下降,EC和OH-值低.20世纪初以来,随着藏北高原气候呈现暖湿化趋势,大气粉尘载荷明显下降.因此,EC可作为显示大气尘埃载荷变化的宏观标尺,是气候波动的"指示器".     

Impact of polychaetes (Nereis spp. and Arenicola marina) on carbon biogeochemistry in coastal marine sediments

Known effects of bioturbation by common polychaetes (Nereis spp. and Arenicola marina) in Northern European coastal waters on sediment carbon diagenesis is summarized and assessed. The physical impact of irrigation and reworking activity of the involved polychaete species is evaluated and related to their basic biology. Based on past and present experimental work, it is concluded that effects of bioturbation on carbon diagenesis from manipulated laboratory experiments cannot be directly extrapolated to in situ conditions. The 45–260% flux (e.g., CO₂ release) enhancement found in the laboratory is much higher than usually observed in the field (10–25%). Thus, the faunal induced enhancement of microbial carbon oxidation in natural sediments instead causes a reduction of the organic matter inventory rather than an increased release of CO₂ across the sediment/water interface. The relative decrease in organic inventory (G _b /G _u) is inversely related to the relative increase in microbial capacity for organic matter decay (k _b /k _u). The equilibrium is controlled by the balance between organic input (deposition of organic matter at the sediment surface) and the intensity of bioturbation. Introduction of oxygen to subsurface sediment and removal of metabolites are considered the two most important underlying mechanisms for the stimulation of carbon oxidation by burrowing fauna. Introduction of oxygen to deep sediment layers of low microbial activity, either by downward irrigation transport of overlying oxic water or by upward reworking transport of sediment to the oxic water column will increase carbon oxidation of anaerobically refractory organic matter. It appears that the irrigation effect is larger than and to a higher degree dependent on animal density than the reworking effect. Enhancement of anaerobic carbon oxidation by removal of metabolites (reduced diffusion scale) may cause a significant increase in total sediment metabolism. This is caused by three possible mechanisms: (i) combined mineralization and biological uptake; (ii) combined mineralization and abiogenic precipitation; and (iii) alleviation of metabolite inhibition. Finally, some suggestions for future work on bioturbation effects are presented, including: (i) experimental verification of metabolite inhibition in bioturbated sediments; (ii) mapping and quantification of the role of metals as electron acceptors in bioturbated sediments; and (iii) identification of microbial community composition by the use of new molecular biological techniques. These three topics are not intended to cover all unresolved aspects of bioturbation, but should rather be considered a list of obvious gaps in our knowledge and present new and appealing approaches.     

ENCORE: the effect of nutrient enrichment on coral reefs. Synthesis of results and conclusions

Coral reef degradation resulting from nutrient enrichment of coastal waters is of increasing global concern. Although effects of nutrients on coral reef organisms have been demonstrated in the laboratory, there is little direct evidence of nutrient effects on coral reef biota in situ. The ENCORE experiment investigated responses of coral reef organisms and processes to controlled additions of dissolved inorganic nitrogen (N) and/or phosphorus (P) on an offshore reef (One Tree Island) at the southern end of the Great Barrier Reef, Australia. A multi-disciplinary team assessed a variety of factors focusing on nutrient dynamics and biotic responses. A controlled and replicated experiment was conducted over two years using twelve small patch reefs ponded at low tide by a coral rim. Treatments included three control reefs (no nutrient addition) and three + N reefs (NH4Cl added), three + P reefs (KH2PO4 added), and three + N + P reefs. Nutrients were added as pulses at each low tide (ca twice per day) by remotely operated units. There were two phases of nutrient additions. During the initial, low-loading phase of the experiment nutrient pulses (mean dose = 11.5 microM NH4+; 2.3 microM PO4(-3)) rapidly declined, reaching near-background levels (mean = 0.9 microM NH4+; 0.5 microM PO4(-3)) within 2-3 h. A variety of biotic processes, assessed over a year during this initial nutrient loading phase, were not significantly affected, with the exception of coral reproduction, which was affected in all nutrient treatments. In Acropora longicyathus and A. aspera, fewer successfully developed embryos were formed, and in A. longicyathus fertilization rates and lipid levels decreased. In the second, high-loading, phase of ENCORE an increased nutrient dosage (mean dose = 36.2 microM NH4+; 5.1 microM PO4(-3)) declining to means of 11.3 microM NH4+ and 2.4 microM PO4(-3) at the end of low tide) was used for a further year, and a variety of significant biotic responses occurred. Encrusting algae incorporated virtually none of the added nutrients. Organisms containing endosymbiotic zooxanthellae (corals and giant clams) assimilated dissolved nutrients rapidly and were responsive to added nutrients. Coral mortality, not detected during the initial low-loading phase, became evident with increased nutrient dosage, particularly in Pocillopora damicornis. Nitrogen additions stunted coral growth, and phosphorus additions had a variable effect. Coral calcification rate and linear extension increased in the presence of added phosphorus but skeletal density was reduced, making corals more susceptible to breakage. Settlement of all coral larvae was reduced in nitrogen treatments, yet settlement of larvae from brooded species was enhanced in phosphorus treatments. Recruitment of stomatopods, benthic crustaceans living in coral rubble, was reduced in nitrogen and nitrogen plus phosphorus treatments. Grazing rates and reproductive effort of various fish species were not affected by the nutrient treatments. Microbial nitrogen transformations in sediments were responsive to nutrient loading with nitrogen fixation significantly increased in phosphorus treatments and denitrification increased in all treatments to which nitrogen had been added. Rates of bioerosion and grazing showed no significant effects of added nutrients. ENCORE has shown that reef organisms and processes investigated in situ were impacted by elevated nutrients. Impacts were dependent on dose level, whether nitrogen and/or phosphorus were elevated and were often species-specific. The impacts were generally sub-lethal and subtle and the treated reefs at the end of the experiment were visually similar to control reefs. Rapid nutrient uptake indicates that nutrient concentrations alone are not adequate to assess nutrient condition of reefs. Sensitive and quantifiable biological indicators need to be developed for coral reef ecosystems. The potential bioindicators identified in ENCORE should be tested in future research on coral reef/nutrient interactions. Synergistic and cumulative effects of elevated nutrients and other environmental parameters, comparative studies of intact vs. disturbed reefs, offshore vs. inshore reefs, or the ability of a nutrient-stressed reef to respond to natural disturbances require elucidation. An expanded understanding of coral reef responses to anthropogenic impacts is necessary, particularly regarding the subtle, sub-lethal effects detected in the ENCORE studies.     

Holistic environmental assessment and offshore oil field exploration and production

According to UK Government surveys, concern for the environment is growing. Environmental regulation of the industry is becoming wider in its scope and tougher in its implementation. Various techniques are available to assess how the industry can drive down its environmental impact and comply with environmental regulation. Environmental Assessments (EA) required by European law do not cover the whole life cycle of the project that they are analysing. Life Cycle Analysis (LCA) was developed to assess the environmental loadings of a product, process or activity over its entire life cycle. It was the first technique used in environmental analysis that adopted what was described as a holistic approach. It fails this approach by not assessing accidental emissions or environmental impacts other than those that are direct. Cost Benefit Analysis (CBA) offers the opportunity to value environmental effects and appraise a project on the basis of costs and benefits. Not all environmental effects can be valued and of those that can there is considerable uncertainty in their valuation and occurrence. CBA cannot satisfactorily measure the total environmental risk of a project. Consequently there is a need for a technique that overcomes the failures of project-level EA, LCA and CBA, and assesses total environmental risk. Many organizations such as, the British Medical Association, the European Oilfield Speciality Chemicals Association, the Royal Ministry of Petroleum and Energy (Norway) and Shell Expro now recognize that a holistic approach is an integral part of assessing total risk. The Brent SPAR case study highlights the interdisciplinary nature required of any environmental analysis. Holistic Environmental Assessment is recommended as such an environmental analysis.     

Sorption of radioactive contaminants by sediment from the Kara Sea

The purpose of this study is to quantify some of the parameters needed to perform near-field modelling of sites in the Kara Sea that were impacted by the disposal of radioactive waste. The parameters of interest are: the distribution coefficients (Kd) for several important radionuclides, the mineralogy of the sediment, and the relationship of Kd to liquid-to-solid ratio. Sediment from the Kara Sea (location: 73 degrees 00'N, 58 degrees 00'E) was sampled from a depth of 287 m on August 23/24, 1992. Analysis of the material included mineralogy, grain size and total organic carbon (TOC). Uptake kinetics were determined for 85Sr, 137Cs, 241Am, 99Tc, 1251, 232U and 210Pb and distribution coefficients (Kd) were determined for these radionuclides using batch type experiments. Sorption isotherms, developed for 137Cs, 85Sr and 99Tc, were linear in each case. Increasing the liquid-to-solid ratio strongly increased uptake of 137Cs and moderately increased uptake of 99Tc. Analysis for anthropogenic radionuclides indicated the presence only of 239/240Pu in the sediment with the highest activity (at the top section of the core) being 0.420 Bq kg(-1). Other anthropogenic radionuclides were below detection limits.     

Spatial differences in persistent organochlorine pollutant concentrations between the Bering and Chukchi Seas (1993)

During August-September 1993, a joint Russian-United States expedition to the Bering and Chukchi Seas took place. Surface water samples were collected from 21 sites and separated into dissolved (duplicates) and suspended solids; 19 sediment and 6 air samples were also collected. These samples were analysed for 19 organochlorine pesticides, 11 chlorobenzenes and 113 PCB congeners. The report provides data on selected compounds which occured in > or = 75% of the water samples. Highest water concentrations were observed for HCH in open waters north and south of the Bering Strait, both regions being similar (alpha-HCH; 2.2 ng/L and lindane: 0.35 ng/L). Air levels observed were also constant (alpha-HCH; 0.041 ng/m3, lindane: 0.0093 ng/m3). Suspended solids and air particulares contributed little to the concentrations in their respective media, an observation common to all analytes except for the PCBs and the DDT residues. The sum of PCB concentrations in water were higher in the Bering Sea area compared to the Chukchi Sea (1.0 vrs 0.67 ng/L) and lower for air (0.46 vrs 0.23 ng/m3). Sum of DDT in water was higher in the Bering Sea than in the Chukchi Sea (0.23 vrs 0.15 ng/L) while in sediments and air, the Bering Sea concentrations were lower (0.95 vrs 1.6 ng/g and 36 vrs 56 pg/m3, respectively). Other organochlorine compounds for which data are presented include: pp'-DDE, pp'-DDT, dieldrin, HCB, 3 chlorobenzenes and 3 PCB congeners. Fluxes of all these chemicals through the Berin Strait are estimated; they ranged from 57 t/a (alpha-HCH) through 26 t/a (for sum of PCBs) to 0.2 t/a (pp'-DDE, dieldrin and 1,2,3-trichlorobenzene). Fugacity ratios for the HCHs and PCBs indicate the alpha-HCH is degassing in both the Bering and Chukchi Seas and that the gamma-isomer is degassing in the Bering Sea and is close to equilibrium (weakly absorbing) in the Chuchi Sea; the sum of PCBs are strongly absorbing in both areas.     

Can a pollution event be detected using a single biological effects monitoring method?

The trends of malformation prevalence in embryos of dab, Limanda limanda, in the southern North Sea after the year 1990 mirrored the drop in major pollutants in the rivers draining into the German Bight. Despite this general decline, we detected a pollution event in the southern North Sea in winter 1995/1996 employing the prevalence of malformations in pelagic dab embryos as an indicator. An abrupt rise in malformation prevalence in the embryos of dab, corresponded to a dramatic increase in DDT levels in parent fish from the same area, indicating a hitherto unnoticed introduction of considerable quantities of DDT into the system.