Enhancement of aquifer vulnerability indexing using the analytic-element method

Indexing methods are used for the evaluation of aquifer vulnerability and establishing guidelines for the protection of ground-water resources. The principle of the indexing method is to rank influences on groundwater to determine overall vulnerability of an aquifer to contamination. The analytic element method (AEM) of ground-water flow modeling is used to enhance indexing methods by rapidly calculating a potentiometric surface based primarily on surface-water features. This potentiometric map is combined with a digital-elevation model to produce a map of water-table depth. This is an improvement over simple water-table interpolation methods. It is physically based, properly representing surface-water features, hydraulic boundaries, and changes in hydraulic conductivity. The AEM software, SPLIT, is used to improve an aquifer vulnerability assessment for a valley-fill aquifer in western New York State. A GIS-based graphical user interface allows automated conversion of hydrography vector data into analytic elements.     

Determination of HBCD, PBDEs and MeO-BDEs in California sea lions (Zalophus californianus) stranded between 1993 and 2003

Blubber samples from male California sea lions (Zalphophus californianus) stranded between 1993 and 2003 were analyzed for 27 polybrominated diphenyl ether (PBDE) congeners, three isomers of hexabromocyclododecane (HBCD) and 14 methoxylated polybrominated diphenyl ether (MeO-BDE) congeners. Total PBDEs ranged from 450 ng/g to 4740 ng/g wet mass and total HBCD ranged from < 0.3 ng/g to 12 ng/g wet mass. The concentration of HBCD increased from 0.7 ng/g to12.0 ng/g wet mass in sea lion blubber between 1993 and 2003. However, no significant temporal trend was observed for any of the other brominated compounds over this 10 year period. Only one of the 14 MeO-BDE congeners was detected in the blubber samples, 6-methoxy-2,2',4,4'-tetrabromodiphenyl ether (6-MeO-BDE 47), and concentrations ranged from < 0.2 ng/g to 12 ng/g wet mass. A bromo-, chloro-heterocyclic compound, 1,1'-dimethyl-tetrabromo-dichloro-2,2'-bipyrrole (DBP-Br4Cl2), previously reported in marine species along the Pacific coast, was also identified in the sea lion blubber. DBP-Br4Cl2 ranged from 44 ng/g wet mass to 660 ng/g wet mass and was present at concentrations rivaling the dominant PBDE congener, BDE 47 (2,2',4,4'-tetrabromodiphenyl ether). Concentrations of DBP-Br4Cl2 were positively correlated with 6-MeO-BDE 47 (r = 0.7; p < 0.05). Both of these compounds have been identified in marine algae and sponges, and studies suggest they are both produced from natural sources. This study demonstrates that brominated compounds from both anthropogenic and biogenic sources can accumulate to similar levels in marine mammals. In addition, HBCD concentrations appear to be increasing in California sea lion populations, whereas PBDE concentrations, between 1993 and 2003, were highly variable.     

Reconstruction of past methane availability in an Arctic Alaska wetland indicates climate influenced methane release during the past ~12,000?years

Atmospheric contributions of methane from Arctic wetlands during the Holocene are dynamic and linked to climate oscillations. However, long-term records linking climate variability to methane availability in Arctic wetlands are lacking. We present a multi-proxy ~12,000?year paleoecological reconstruction of intermittent methane availability from a radiocarbon-dated sediment core (LQ-West) taken from a shallow tundra lake (Qalluuraq Lake) in Arctic Alaska. Specifically, stable carbon isotopic values of photosynthetic biomarkers and methane are utilized to estimate the proportional contribution of methane-derived carbon to lake-sediment-preserved benthic (chironomids) and pelagic (cladocerans) components over the last ~12,000?years. These results were compared to temperature, hydrologic, and habitat reconstructions from the same site using chironomid assemblage data, oxygen isotopes of chironomid head capsules, and radiocarbon ages of plant macrofossils. Cladoceran ephippia from ~4,000?cal?year BP sediments have ??¹³C values that range from ~?39 to ?31??, suggesting peak methane carbon assimilation at that time. These low ??¹³C values coincide with an apparent decrease in effective moisture and development of a wetland that included Sphagnum subsecundum. Incorporation of methane-derived carbon by chironomids and cladocerans decreased from ~2,500 to 1,500?cal?year BP, coinciding with a temperature decrease. Live-collected chironomids with a radiocarbon age of 1,640?cal?year BP, and fossil chironomids from 1,500?cal?year BP in the core illustrate that ??old?? carbon has also contributed to the development of the aquatic ecosystem since ~1,500?cal?year BP. The relatively low ??¹³C values of aquatic invertebrates (as low as ?40.5??) provide evidence of methane incorporation by lake invertebrates, and suggest intermittent climate-linked methane release from the lake throughout the Holocene.     

Identification of mid-latitudinal regional and urban temperature variabilities based on regional reanalysis data

The objective of the study is to detect geographical and temporal variations of near surface air temperatures over Minnesota and Wisconsin, USA derived from the North American Regional Reanalysis (NARR) dataset. In addition, the study serves to assess the usefulness of NARR temperature data to analyze regional and local temperature variations. Particular emphasis was placed on the analyses on the temperature-modifying effects of the Great Lakes and large urban environments. We analyzed annual mean, daily maximum and minimum, and January minimum and July maximum temperatures for the period 1979–2006 by using methods such as ordinary kriging, principal component analysis, and the Mann–Kendall test. On a regional scale, we found significant effects of the latitude and the Great Lakes on the spatial variability of the data. Furthermore, we found clearly identifiable effects of large urban areas in the study region (Minneapolis—Saint Paul and Milwaukee), which are more evident in the principal component scores than in the temperature data themselves. While we failed to detect significant July maximum temperature trends, we detected significantly increasing trends in January minimum and mean annual temperature datasets in the eastern part of the region. Overall, the present study has demonstrated the potential of using NARR data for urban climate research.     

Microstructure modifications of silicates induced by the collection in aerogel: Experimental approach and comparison with Stardust results

Abstract– Particles from comet 81P/Wild 2 were captured with silica aerogel during the flyby Stardust mission. A significant part of the collection was damaged during the impact at hypervelocity in the aerogel. In this study, we conducted impact experiments into aerogel of olivine and pyroxene powder using a light‐gas gun in similar conditions as that of the comet Wild 2 particles collection. The shot samples were investigated using transmission electron microscopy to characterize their microstructure. Both olivine and pyroxene samples show evidence of thermal alteration due to friction with the aerogel. All the grains have rounded edges after collection, whereas their shape was angular in the initial shot powder set. This is probably associated with mass loss of particles. The rims of the grains are clearly melted and mixed with aerogel. The core of olivine grains is fairly well preserved, but some grains contain dislocations in glide configuration. We interpret these dislocations as generated by the thermal stresses that have emerged due to the high temperature gradients between the core and the rim of the grains. Most of the pyroxene grains have been fully melted. Their high silica concentration reflects a strong impregnation with melted aerogel. The preferential melting of pyroxene compared with olivine is due to a difference in melting temperatures of 300°. This melting point difference probably induces a bias in the measurements of the ratio olivine/pyroxene in the Wild 2 comet. The proportion of pyroxene was probably higher on Wild 2 than expected from the samples collected into aerogel.     

Sediment cascades and the entangled relationship between human impact and natural dynamics at the pre-pottery Neolithic site of Göbekli Tepe,Anatolia

This study presents a meta-analysis of radiocarbon ages for the environs of Göbekli Tepe – one of the oldest monumental structures worldwide – using cumulative probability functions to diachronically assess phases of geomorphodynamic activity as controlled by natural or anthropogenic drivers. We employ sediment cascades as a heuristic framework to study the complex responses of the geomorphological system to various triggers at local to supra-regional scales. Possible triggers include climatic variability as documented by supra-regional hydroclimatic proxy data, regional demographic trends, and local to regional socioeconomic developments such as the emergence of sedentism or the introduction and dispersal of livestock herding. Our results show that phases of intensified geomorphodynamic activity occurred between ca. 7.4–7.0 and 5.8–3.3 ka BP. These phases roughly coincide with phases of population growth in southern Turkey and climatic variations in Turkey and the Levant. The phase between ca. 5.8–3.3 ka BP also corresponds to the time when organized agriculture and the seeder plough were introduced. Also, the identified phases are in agreement with the general trend of varying geomorphodynamic activity in the Eastern Mediterranean as driven by human impact and climatic change. However, neither the Younger Dryas–Holocene transition nor the development of herding during the Pre-Pottery Neolithic left a clear signature. We demonstrate how the different depositional environments in the studied landscape compartments vary with respect to their spatiotemporal coverage and discuss challenges when trying to understand processes that once shaped landscapes of past societies. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd     

Correction to: Projection of Iron Ore Production

Natural Resources Research - The original version of this article unfortunately contained an error in Equation&nbsp;3.     

High Resolution Köppen‐Geiger Classifications of Paleoclimate Simulations

The development and application of an algorithm to compute Köppen‐Geiger climate classifications from the Coupled Model Intercomparison Project (CMIP) and Paleo Model Intercomparison Project (PMIP) climate model simulation data is described in this study. The classification algorithm was applied to data from the PMIP III paleoclimate experiments for the Last Glacial Maximum, 21k years before present (yBP), Mid‐Holocene (6k yBP) and the Pre‐Industrial (0k yBP, control run) time slices. To infer detailed classification maps, the simulation datasets were interpolated to a higher resolution. The classification method presented is based on the application of Open Source Software, and the implementation is described with attention to detail. The source code and the exact input data sets as well as the resulting data sets are provided to enable the application of the presented approach.